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A Case Study of the Mechanism of Alcohol-Mediated Morita Baylis–Hillman Reactions. The Importance of Experimental Observations

Journal of the American Chemical Society, 2015-03, Vol.137 (11), p.3811-3826

2015

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Dynamics and the Regiochemistry of Nitration of Toluene

Journal of the American Chemical Society, 2016-11, Vol.138 (46), p.15167-15176

2016

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Energy Read-out as a Probe of Kinetically Hidden Transition States

Organic letters, 2021-03, Vol.23 (6), p.2174-2177

2021

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Ir-Catalyzed ortho-Borylation of Phenols Directed by Substrate–Ligand Electrostatic Interactions: A Combined Experimental/in Silico Strategy for Optimizing Weak Interactions

Journal of the American Chemical Society, 2017-06, Vol.139 (23), p.7864-7871

2017

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Dynamics and the Failure of Transition State Theory in Alkene Hydroboration

Journal of the American Chemical Society, 2009-03, Vol.131 (9), p.3130-3131

2009

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Dynamically Complex [6+4] and [4+2] Cycloadditions in the Biosynthesis of Spinosyn A

Journal of the American Chemical Society, 2016-03, Vol.138 (11), p.3631-3634

2016

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Dynamics and a Unified Understanding of Competitive [2,3]- and [1,2]-Sigmatropic Rearrangements Based on a Study of Ammonium Ylides

Journal of the American Chemical Society, 2014-03, Vol.136 (10), p.3740-3743

2014

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Recrossing and Dynamic Matching Effects on Selectivity in a Diels-Alder Reaction

Angewandte Chemie (International ed.), 2009-01, Vol.48 (48), p.9156-9159

2009

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Outer-Sphere Direction in Iridium C–H Borylation

Journal of the American Chemical Society, 2012-07, Vol.134 (28), p.11350-11353

2012

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Dynamic Origin of the Stereoselectivity of a Nucleophilic Substitution Reaction

Organic letters, 2012-05, Vol.14 (10), p.2528-2531

2012

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Entropic Intermediates and Hidden Rate-Limiting Steps in Seemingly Concerted Cycloadditions. Observation, Prediction, and Origin of an Isotope Effect on Recrossing

Journal of the American Chemical Society, 2012-02, Vol.134 (4), p.1914-1917

2012

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Controlling Selectivity by Controlling Energy Partitioning in a Thermal Reaction in Solution

Journal of the American Chemical Society, 2016-11, Vol.138 (44), p.14534-14537

2016

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Control Elements in Dynamically Determined Selectivity on a Bifurcating Surface

Journal of the American Chemical Society, 2008-11, Vol.130 (44), p.14544-14555

2008

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Mechanistic Studies of Formal Thioboration Reactions of Alkynes

Journal of organic chemistry, 2017-08, Vol.82 (15), p.8165-8178

2017

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Isotope Effects and Heavy-Atom Tunneling in the Roush Allylboration of Aldehydes

Organic letters, 2012-05, Vol.14 (9), p.2370-2373

2012

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Competition between Reaction and Intramolecular Energy Redistribution in Solution: Observation and Nature of Nonstatistical Dynamics in the Ozonolysis of Vinyl Ethers

Journal of the American Chemical Society, 2011-09, Vol.133 (35), p.13824-13827

2011

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Newtonian Kinetic Isotope Effects. Observation, Prediction, and Origin of Heavy-Atom Dynamic Isotope Effects

Journal of the American Chemical Society, 2009-06, Vol.131 (24), p.8382-8383

2009

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Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

Chemical communications (Cambridge, England), 2010-01, Vol.46 (41), p.7724-7726

2010

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Controlling Selectivity by Controlling the Path of Trajectories

Journal of the American Chemical Society, 2015-11, Vol.137 (45), p.14244-14247

2015

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Solvation Dynamics and the Nature of Reaction Barriers and Ion-Pair Intermediates in Carbocation Reactions

Journal of the American Chemical Society, 2020-07, Vol.142 (29), p.12865-12877

2020

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Labelling and determination of the energy in reactive intermediates in solution enabled by energy-dependent reaction selectivity

Nature chemistry, 2018-02, Vol.10 (2), p.237-241

2018

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A Few Molecules Can Control the Enantiomeric Outcome. Evidence Supporting Absolute Asymmetric Synthesis Using the Soai Asymmetric Autocatalysis

Organic letters, 2003-11, Vol.5 (23), p.4337-4339

2003

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Isotope Effects and the Nature of Selectivity in Rhodium-Catalyzed Cyclopropanations

Journal of the American Chemical Society, 2003-12, Vol.125 (51), p.15902-15911

2003

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Failure and Redemption of Statistical and Nonstatistical Rate Theories in the Hydroboration of Alkenes

Journal of the American Chemical Society, 2017-11, Vol.139 (44), p.15710-15723

2017

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Nuclear Quantum Effects on the Nature of Hydroboration Selectivity: Experimental Effects of First-Collision Tunneling

Journal of the American Chemical Society, 2024-09, Vol.146 (38), p.25907-25911

2024

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A Case Study of the Mechanism of Alcohol-Mediated Morita Baylis–Hillman Reactions. The Importance of Experimental Observations

Dynamics and the Regiochemistry of Nitration of Toluene

Energy Read-out as a Probe of Kinetically Hidden Transition States

Ir-Catalyzed ortho-Borylation of Phenols Directed by Substrate–Ligand Electrostatic Interactions: A Combined Experimental/in Silico Strategy for Optimizing Weak Interactions

Dynamics and the Failure of Transition State Theory in Alkene Hydroboration

Dynamically Complex [6+4] and [4+2] Cycloadditions in the Biosynthesis of Spinosyn A

Dynamics and a Unified Understanding of Competitive [2,3]- and [1,2]-Sigmatropic Rearrangements Based on a Study of Ammonium Ylides

Recrossing and Dynamic Matching Effects on Selectivity in a Diels-Alder Reaction

Outer-Sphere Direction in Iridium C–H Borylation

Dynamic Origin of the Stereoselectivity of a Nucleophilic Substitution Reaction

Entropic Intermediates and Hidden Rate-Limiting Steps in Seemingly Concerted Cycloadditions. Observation, Prediction, and Origin of an Isotope Effect on Recrossing

Controlling Selectivity by Controlling Energy Partitioning in a Thermal Reaction in Solution

Control Elements in Dynamically Determined Selectivity on a Bifurcating Surface

Mechanistic Studies of Formal Thioboration Reactions of Alkynes

Isotope Effects and Heavy-Atom Tunneling in the Roush Allylboration of Aldehydes

Competition between Reaction and Intramolecular Energy Redistribution in Solution: Observation and Nature of Nonstatistical Dynamics in the Ozonolysis of Vinyl Ethers

Newtonian Kinetic Isotope Effects. Observation, Prediction, and Origin of Heavy-Atom Dynamic Isotope Effects

Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

Controlling Selectivity by Controlling the Path of Trajectories

Solvation Dynamics and the Nature of Reaction Barriers and Ion-Pair Intermediates in Carbocation Reactions

Labelling and determination of the energy in reactive intermediates in solution enabled by energy-dependent reaction selectivity

A Few Molecules Can Control the Enantiomeric Outcome. Evidence Supporting Absolute Asymmetric Synthesis Using the Soai Asymmetric Autocatalysis

Isotope Effects and the Nature of Selectivity in Rhodium-Catalyzed Cyclopropanations

Failure and Redemption of Statistical and Nonstatistical Rate Theories in the Hydroboration of Alkenes

Nuclear Quantum Effects on the Nature of Hydroboration Selectivity: Experimental Effects of First-Collision Tunneling

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