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Highly active, stable, catalysts for the Heck reaction; further suggestions on the mechanism

Chemical communications (Cambridge, England), 1998-07 (13), p.1361-1362

Shaw, Bernard L.

1998

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Speculations on new mechanisms for Heck reactions

New journal of chemistry, 1998, Vol.22 (2), p.77-79

Shaw, Bernard L.

1998

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Aryl halide coordination to Ru(II): crystal structure of mer, trans-[RuCl 2(PPh 3){PPh 2CH 2C(Bu t)NNCH(C 6H 3F 2-2,6)}]

Inorganica Chimica Acta, 2001-12, Vol.325 (1), p.151-154

2001

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Activation of C–X (X=Cl or Br) bonds in 2-halobenzaldehydes as their 2-pyridylhydrazone derivatives: oxidative addition to tungsten(0) to give aryl–tungsten(II) complexes

Inorganica Chimica Acta, 2001-12, Vol.325 (1), p.175-178

2001

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Diphosphinoazines (Z,Z)-R2PCH2C(But)NNC(But)CH2PR2 with R groups of various sizes and complexes {[(Z,Z)-R2PCH2C(But)NNC(But)CH2PR2]-[η3-CH2C(CH3)CH2PdCl]2}

Inorganica Chimica Acta, 2001-02, Vol.313 (1-2), p.77-86

2001

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Cationic nickel(II) complexes with azine diphosphines—structural and electrochemical study

Inorganica Chimica Acta, 2002-10, Vol.338, p.201-209

2002

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Large-ring and cyclometalated rhodium complexes from some medium-chain .alpha.,.omega.-diphosphines

Journal of the American Chemical Society, 1980-06, Vol.102 (13), p.4373-4379

1980

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Chelating diphosphine–palladium(ii) dihalides; outstandingly good catalysts for Heck reactions of aryl halides

Chemical communications (Cambridge, England), 1998-09 (17), p.1863-1864

Shaw, Bernard L.

1998

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Formation of large rings, internal metalation reactions, and internal entropy effects

Journal of the American Chemical Society, 1975-06, Vol.97 (13), p.3856-3857

Shaw, Bernard L

1975

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Heterobimetallic iridium or rhodium .mu.-bis(diphenylphosphino)methane complexes with copper(I), silver(I), or gold(I). A silver hydride complex and the crystal structure of [(PhC.tplbond.C)(OC)Ir(.mu.-Ph2PCH2PPh2)2CuCl]

Organometallics, 1983-12, Vol.2 (12), p.1889-1891

1983

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Formation of a heterobimetallic cyclohexa-1,4-dienyl-hydrido-complex from an acetylide and buta-1,3-diene: crystal structure of [(p-MeC6H4C≡C)Pt(υ-dppm)2-(υ-H)Ir(CO){C = C(C6H3Me)CH2CH = CHCH2}][BF4] (dppm = Ph2PCH2PPh2)

Journal of the Chemical Society. Chemical communications, 1987 (13), p.1005-1007

1987

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Palladation of dimethylhydrazones, oximes, and oxime O-allyl ethers: crystal structure of [Pd3(ON = CPriPh)6]

Journal of the Chemical Society. Chemical communications, 1978 (23), p.1061

1978

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Rapid reversible fission of a C–H bond in a metal complex: X-ray crystal structure of [RhHCl(Bu t 2 PCH 2 CH 2 CHCH 2 CH 2 PBu t 2 )]

Journal of the Chemical Society. Chemical communications, 1979 (11), p.498-499

1979

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Synthesis and X-ray structure of an unusual iridium ylide or carbene complex

Journal of the Chemical Society. Chemical communications, 1977 (17), p.589

1977

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Novel iridium complexes of an azine diphosphine: very reactive iridium(I) species formed by a unique isomerisation of an iridium(III) hydride. A new method of creating coordinative unsaturation

Journal of the Chemical Society. Chemical communications, 1995 (8), p.865

1995

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Alkylation and acylation of co-ordinated tertiary phosphines: the nucleophilic substitution of the carbanions derived from [M(CO)4(Ph2PCH2PPh2)](M = Cr, Mo, or W)

Journal of the Chemical Society. Chemical communications, 1982 (5), p.286

1982

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Diphosphinoazines ( Z, Z)-R 2PCH 2C(Bu t)NNC(Bu t)CH 2PR 2 with R groups of various sizes and complexes {[( Z, Z)-R 2PCH 2C(Bu t)NNC(Bu t)CH 2PR 2]-[η 3-CH 2C(CH 3)CH 2PdCl] 2}

Inorganica Chimica Acta, 2001, Vol.313 (1), p.77-86

2001

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A general method of promoting agostic interactions (Ru-Ha-C) using azine phosphines

Journal of the Chemical Society. Chemical communications, 1994 (10), p.1201-1202

1994

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A general method of promoting oxidative addition of C-H bonds to iridium(I) using azine phosphines

Journal of the Chemical Society. Chemical communications, 1994 (10), p.1203-1204

1994

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Photoelectron spectra and tertiary phosphine–metal complexes

Journal of the Chemical Society. Chemical communications, 1979 (3), p.104-105

Shaw, Bernard L.

1979

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A systematic method of promoting an aryl fluoride to coordinate to ruthenium(11)

Inorganica Chimica Acta, 1995-01, Vol.228 (2), p.127-131

1995

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Chemistry of the azine phosphine ligand Z,E-PPh2CH2C(But)=N-N=CMe(C6H4NO2-4): crystal structure of [Mo(CO)4{PPh2CH2C(But)=N-N=CMe(C6H4NO2-4)}]

Inorganica Chimica Acta, 1998-04, Vol.270 (1-2), p.312-325

1998

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Some chlorocarbonylruthenium(II) complexes of P,N-donor ligands: crystal structures of [RuCl(CO) {PPh 2CH 2C(Bu t)NNH 2} 2]Cl and fac, cis-[RuCj 2(CO) {PPh 2CH 2C(Bu t)NNC(Bu t)CH 2PPh 2}]

Inorganica Chimica Acta, 1998-09, Vol.279 (1), p.95-103

1998

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Diphenylphosphinomethyl t-butyl ketone N-diphenylphosphino- N-phenylhydrazone PPh 2CH 2C(Bu t)NN(Ph)PPh 2 and its complexes with chromium(0), molybdenum(0), tungsten(0), palladium(II) and platinum(II)

Inorganica Chimica Acta, 1993, Vol.204 (1), p.39-43

1993

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Some steric, conformational and entropy effects of tertiary phosphine ligands

Journal of organometallic chemistry, 1980-01, Vol.200 (1), p.307-318

Shaw, Bernard L.

1980

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Highly active, stable, catalysts for the Heck reaction; further suggestions on the mechanism

Speculations on new mechanisms for Heck reactions

Aryl halide coordination to Ru(II): crystal structure of mer, trans-[RuCl 2(PPh 3){PPh 2CH 2C(Bu t)NNCH(C 6H 3F 2-2,6)}]

Activation of C–X (X=Cl or Br) bonds in 2-halobenzaldehydes as their 2-pyridylhydrazone derivatives: oxidative addition to tungsten(0) to give aryl–tungsten(II) complexes

Diphosphinoazines (Z,Z)-R2PCH2C(But)NNC(But)CH2PR2 with R groups of various sizes and complexes {[(Z,Z)-R2PCH2C(But)NNC(But)CH2PR2]-[η3-CH2C(CH3)CH2PdCl]2}

Cationic nickel(II) complexes with azine diphosphines—structural and electrochemical study

Large-ring and cyclometalated rhodium complexes from some medium-chain .alpha.,.omega.-diphosphines

Chelating diphosphine–palladium(ii) dihalides; outstandingly good catalysts for Heck reactions of aryl halides

Formation of large rings, internal metalation reactions, and internal entropy effects

Heterobimetallic iridium or rhodium .mu.-bis(diphenylphosphino)methane complexes with copper(I), silver(I), or gold(I). A silver hydride complex and the crystal structure of [(PhC.tplbond.C)(OC)Ir(.mu.-Ph2PCH2PPh2)2CuCl]

Formation of a heterobimetallic cyclohexa-1,4-dienyl-hydrido-complex from an acetylide and buta-1,3-diene: crystal structure of [(p-MeC6H4C≡C)Pt(υ-dppm)2-(υ-H)Ir(CO){C = C(C6H3Me)CH2CH = CHCH2}][BF4] (dppm = Ph2PCH2PPh2)

Palladation of dimethylhydrazones, oximes, and oxime O-allyl ethers: crystal structure of [Pd3(ON = CPriPh)6]

Rapid reversible fission of a C–H bond in a metal complex: X-ray crystal structure of [RhHCl(Bu t 2 PCH 2 CH 2 CHCH 2 CH 2 PBu t 2 )]

Synthesis and X-ray structure of an unusual iridium ylide or carbene complex

Novel iridium complexes of an azine diphosphine: very reactive iridium(I) species formed by a unique isomerisation of an iridium(III) hydride. A new method of creating coordinative unsaturation

Alkylation and acylation of co-ordinated tertiary phosphines: the nucleophilic substitution of the carbanions derived from [M(CO)4(Ph2PCH2PPh2)](M = Cr, Mo, or W)

Diphosphinoazines ( Z, Z)-R 2PCH 2C(Bu t)NNC(Bu t)CH 2PR 2 with R groups of various sizes and complexes {[( Z, Z)-R 2PCH 2C(Bu t)NNC(Bu t)CH 2PR 2]-[η 3-CH 2C(CH 3)CH 2PdCl] 2}

A general method of promoting agostic interactions (Ru-Ha-C) using azine phosphines

A general method of promoting oxidative addition of C-H bonds to iridium(I) using azine phosphines

Photoelectron spectra and tertiary phosphine–metal complexes

A systematic method of promoting an aryl fluoride to coordinate to ruthenium(11)

Chemistry of the azine phosphine ligand Z,E-PPh2CH2C(But)=N-N=CMe(C6H4NO2-4): crystal structure of [Mo(CO)4{PPh2CH2C(But)=N-N=CMe(C6H4NO2-4)}]

Some chlorocarbonylruthenium(II) complexes of P,N-donor ligands: crystal structures of [RuCl(CO) {PPh 2CH 2C(Bu t)NNH 2} 2]Cl and fac, cis-[RuCj 2(CO) {PPh 2CH 2C(Bu t)NNC(Bu t)CH 2PPh 2}]

Diphenylphosphinomethyl t-butyl ketone N-diphenylphosphino- N-phenylhydrazone PPh 2CH 2C(Bu t)NN(Ph)PPh 2 and its complexes with chromium(0), molybdenum(0), tungsten(0), palladium(II) and platinum(II)

Some steric, conformational and entropy effects of tertiary phosphine ligands

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