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Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis

Nature communications, 2021-09, Vol.12 (1), p.5649-5649, Article 5649

2021

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Evidence for ligand- and solvent-induced disproportionation of uranium(IV)

Nature communications, 2021-08, Vol.12 (1), p.4832-4832, Article 4832

2021

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A crystalline tri-thorium cluster with σ-aromatic metal-metal bonding

Nature (London), 2021-10, Vol.598 (7879), p.72-75

2021

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Thorium(iv)–antimony complexes exhibiting single, double, and triple polar covalent metal–metal bonds

Nature chemistry, 2024-05, Vol.16 (5), p.780-790

2024

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Arene‑, Chlorido‑, and Imido-Uranium Bis- and Tris(boryloxide) Complexes

Inorganic chemistry, 2024-05, Vol.63 (21), p.9588-9601

2024

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f-Element Zintl Chemistry: Actinide-Mediated Dehydrocoupling of H2Sb1- Affords the Trithorium and Triuranium Undeca-Antimontriide Zintl Clusters [{An(TrenTIPS)}3(μ3-Sb11)] (An = Th, U; TrenTIPS = {N(CH2CH2NSiiPr3)3}3-)

Inorganic chemistry, 2024-05

2024

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f-Element Zintl Chemistry: Actinide-Mediated Dehydrocoupling of H 2 Sb 1- Affords the Trithorium and Triuranium Undeca-Antimontriide Zintl Clusters [{An(Tren TIPS )} 3 (μ 3 -Sb 11 )] (An = Th, U; Tren TIPS = {N(CH 2 CH 2 NSi i Pr 3 ) 3 } 3- )

Inorganic chemistry, 2024-05

2024

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13Ccarbene nuclear magnetic resonance chemical shift analysis confirms CeIV=C double bonding in cerium(iv)–diphosphonioalkylidene complexes

Chemical science (Cambridge), 2023-12, Vol.15 (1), p.238-249

2023

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31P Nuclear Magnetic Resonance Spectroscopy as a Probe of Thorium–Phosphorus Bond Covalency: Correlating Phosphorus Chemical Shift to Metal–Phosphorus Bond Order

Journal of the American Chemical Society, 2023-10, Vol.145 (40), p.21766-21784

2023

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Nature of the Arsonium‐Ylide Ph3As=CH2 and a Uranium(IV) Arsonium–Carbene Complex

Angewandte Chemie International Edition, 2020-09, Vol.59 (37), p.15870-15874

International ed. in English, 2020

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13 C carbene nuclear magnetic resonance chemical shift analysis confirms Ce IV [double bond, length as m-dash]C double bonding in cerium(iv)-diphosphonioalkylidene complexes

Chemical science (Cambridge), 2023-12, Vol.15 (1), p.238-249

2023

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Actinide Pnictinidene Chemistry: A Terminal Thorium Parent‐Arsinidene Complex Stabilised by a Super‐Bulky Triamidoamine Ligand

Angewandte Chemie International Edition, 2022-12, Vol.61 (50), p.e202211627-n/a

International ed. in English, 2022

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Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)

Organometallics, 2022-06, Vol.41 (11), p.1353-1363

2022

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Dipnictogen f‑Element Chemistry: A Diphosphorus Uranium Complex

Journal of the American Chemical Society, 2021-04, Vol.143 (14), p.5343-5348

2021

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Fragmentation, catenation, and direct functionalisation of white phosphorus by a uranium()-silyl-phosphino-carbene complex

Chemical communications (Cambridge, England), 2021-05, Vol.57 (41), p.59-593

2021

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f‐Element Half‐Sandwich Complexes: A Tetrasilylcyclobutadienyl–Uranium(IV)–Tris(tetrahydroborate) Anion Pianostool Complex

Angewandte Chemie International Edition, 2020-01, Vol.59 (1), p.295-299

International ed. in English, 2020

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Carbene Complexes of Plutonium: Structure, Bonding, and Divergent Reactivity to Lanthanide Analogs

Journal of the American Chemical Society, 2024-02, Vol.146 (6), p.4098-4111

2024

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Reactivity of a triamidoamine terminal uranium(VI)-nitride with 3d-transition metal metallocenes

Chemical communications (Cambridge, England), 2024-09, Vol.60 (73), p.9990-9993

2024

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Determination of Uranium Central-Field Covalency with 3d4f Resonant Inelastic X‑ray Scattering

Journal of the American Chemical Society, 2024-08, Vol.146 (32), p.22570-22582

2024

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Determination of Uranium Central-Field Covalency with 3 d 4 f Resonant Inelastic X-ray Scattering

Journal of the American Chemical Society, 2024-08, Vol.146 (32), p.22570-22582

2024

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Uranium-nitride chemistry: uranium-uranium electronic communication mediated by nitride bridges

Dalton transactions : an international journal of inorganic chemistry, 2022-06, Vol.51 (22), p.8855-8864

2022

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A Series of Rare‐Earth Mesoionic Carbene Complexes

Chemistry : a European journal, 2022-07, Vol.28 (37), p.e202200761-n/a

2022

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N‑Heterocyclic Carbene to Actinide d‑Based π‑bonding Correlates with Observed Metal–Carbene Bond Length Shortening Versus Lanthanide Congeners

Journal of the American Chemical Society, 2024-04, Vol.146 (15), p.10367-10380

2024

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δ-Bonding modulates the electronic structure of formally divalent nd 1 rare earth arene complexes

Chemical science (Cambridge), 2024-09, Vol.15 (37), p.15160-15169

2024

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δ-Bonding modulates the electronic structure of formally divalent nd1 rare earth arene complexes

Chemical science (Cambridge), 2024-08, Vol.15 (37), p.15160-15169

2024

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Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis

Evidence for ligand- and solvent-induced disproportionation of uranium(IV)

A crystalline tri-thorium cluster with σ-aromatic metal-metal bonding

Thorium(iv)–antimony complexes exhibiting single, double, and triple polar covalent metal–metal bonds

Arene‑, Chlorido‑, and Imido-Uranium Bis- and Tris(boryloxide) Complexes

f-Element Zintl Chemistry: Actinide-Mediated Dehydrocoupling of H2Sb1- Affords the Trithorium and Triuranium Undeca-Antimontriide Zintl Clusters [{An(TrenTIPS)}3(μ3-Sb11)] (An = Th, U; TrenTIPS = {N(CH2CH2NSiiPr3)3}3-)

f-Element Zintl Chemistry: Actinide-Mediated Dehydrocoupling of H 2 Sb 1- Affords the Trithorium and Triuranium Undeca-Antimontriide Zintl Clusters [{An(Tren TIPS )} 3 (μ 3 -Sb 11 )] (An = Th, U; Tren TIPS = {N(CH 2 CH 2 NSi i Pr 3 ) 3 } 3- )

13Ccarbene nuclear magnetic resonance chemical shift analysis confirms CeIV=C double bonding in cerium(iv)–diphosphonioalkylidene complexes

31P Nuclear Magnetic Resonance Spectroscopy as a Probe of Thorium–Phosphorus Bond Covalency: Correlating Phosphorus Chemical Shift to Metal–Phosphorus Bond Order

Nature of the Arsonium‐Ylide Ph3As=CH2 and a Uranium(IV) Arsonium–Carbene Complex

13 C carbene nuclear magnetic resonance chemical shift analysis confirms Ce IV [double bond, length as m-dash]C double bonding in cerium(iv)-diphosphonioalkylidene complexes

Actinide Pnictinidene Chemistry: A Terminal Thorium Parent‐Arsinidene Complex Stabilised by a Super‐Bulky Triamidoamine Ligand

Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)

Dipnictogen f‑Element Chemistry: A Diphosphorus Uranium Complex

Fragmentation, catenation, and direct functionalisation of white phosphorus by a uranium()-silyl-phosphino-carbene complex

f‐Element Half‐Sandwich Complexes: A Tetrasilylcyclobutadienyl–Uranium(IV)–Tris(tetrahydroborate) Anion Pianostool Complex

Carbene Complexes of Plutonium: Structure, Bonding, and Divergent Reactivity to Lanthanide Analogs

Reactivity of a triamidoamine terminal uranium(VI)-nitride with 3d-transition metal metallocenes

Determination of Uranium Central-Field Covalency with 3d4f Resonant Inelastic X‑ray Scattering

Determination of Uranium Central-Field Covalency with 3 d 4 f Resonant Inelastic X-ray Scattering

Uranium-nitride chemistry: uranium-uranium electronic communication mediated by nitride bridges

A Series of Rare‐Earth Mesoionic Carbene Complexes

N‑Heterocyclic Carbene to Actinide d‑Based π‑bonding Correlates with Observed Metal–Carbene Bond Length Shortening Versus Lanthanide Congeners

δ-Bonding modulates the electronic structure of formally divalent nd 1 rare earth arene complexes

δ-Bonding modulates the electronic structure of formally divalent nd1 rare earth arene complexes

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