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Chasing C,C‐Palladacycles

European journal of inorganic chemistry, 2021-09, Vol.2021 (36), p.3655-3683

2021

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Synthesis and Reactivity of Model Intermediates Proposed for the Pd-Catalyzed Remote C–H Functionalization of N‑(2-Haloaryl)acrylamides

Organometallics, 2017-11, Vol.36 (22), p.4465-4476

2017

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Benzyne-benzyne-RNC or CO triple sequential insertion into the Pd-C bond: synthesis of ten-membered N-heterocycles through stable ten- and eleven-membered palladacycles

Chemical communications (Cambridge, England), 2013-09, Vol.49 (73), p.7997-7999

2013

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The First Acetimine Gold(I) and Gold(III) Complexes and the First Acetonine Complexes

Chemistry : a European journal, 2001-02, Vol.7 (3), p.638-646

2001

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Regiospecific Functionalization of Pharmaceuticals and Other Biologically Active Molecules through Cyclopalladated Compounds. 2-Iodination of Phentermine and l-Tryptophan Methyl Ester

Organometallics, 2005-11, Vol.24 (24), p.6001-6004

2005

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Sequential Insertion of Alkynes, Alkenes, and CO into the Pd-C Bond of ortho -Palladated Primary Phenethylamines: from η 3 -Allyl Complexes and Enlarged Palladacycles to Functionalized Arylalkylamines

Organometallics, 2021-02, Vol.40 (4), p.539-556

2021

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Pd-Catalyzed Ring-Opening Polymerization of Cyclobutanols through C(sp3)–C(sp3) Bond Cleavage

Macromolecules, 2024-07, Vol.57 (14), p.6577-6582

2024

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Synthesis of Benzofused O- and N‑Heterocycles through Cascade Carbopalladation/Cross-Alkylation of Alkynes Involving the C–C Cleavage of Cyclobutanols

Organometallics, 2022-03, Vol.41 (5), p.649-658

2022

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Sequential Insertion of Alkynes, Alkenes, and CO into the Pd–C Bond of ortho-Palladated Primary Phenethylamines: from η3‑Allyl Complexes and Enlarged Palladacycles to Functionalized Arylalkylamines

Organometallics, 2021-02, Vol.40 (4), p.539-556

2021

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Ortho-Metalated Primary Amines. 6. The First Synthesis of Six-Membered Palladacycles from Primary Amines Containing Electron-Withdrawing Substituents: End of the Limiting Rules of Cope and Friedrich on Cyclopalladation of Benzyl- and Phenethylamines

Organometallics, 2003-12, Vol.22 (26), p.5513-5517

2003

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ORTHO-PALLADATION OF PRIMARY AMINES: THE MYTH DISPELLED

Comments on modern chemistry. Part A, Comments on inorganic chemistry, 2007-05, Vol.28 (1-2), p.39-72

2007

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Palladium-Assisted Formation of Carbon−Carbon Bonds. Part 10. Insertion Reactions of Isocyanides into the Pd−C Bond of Orthopalladated Primary Amines. Synthesis of 2-R-Aminoisoindolinium Salts (R = tBu, 2,6-Xylyl)

Organometallics, 2002-08, Vol.21 (17), p.3587-3595

2002

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Epimerization of secondary alcohols by new homogeneous, low oxidation-state metal catalysts: carbon-hydrogen bond activation in rhenium alkoxide complexes (.eta.5-C5R5)Re(NO)(PPh3)(OCHRR')

Journal of the American Chemical Society, 1992-03, Vol.114 (6), p.2136-2144

1992

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Insertion of Isocyanides, Isothiocyanates, and Carbon Monoxide into the Pd−C Bond of Cyclopalladated Complexes Containing Primary Arylalkylamines of Biological and Pharmaceutical Significance. Synthesis of Lactams and Cyclic Amidinium Salts Related to the Isoquinoline, Benzo[g]isoquinoline, and β-Carboline Nuclei

Organometallics, 2009-01, Vol.28 (2), p.448-464

2009

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Insertion reactions of isocyanides into the Metal-C(sp3) bonds of ylide complexes

Journal of organometallic chemistry, 2019-08, Vol.894, p.61-66

2019

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Palladium-Mediated Functionalization of Benzofuran and Benzothiophene Cores

Organometallics, 2018-12, Vol.37 (24), p.4648-4663

2018

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Reactivity of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C bond of Ortho-Palladated Phenethylamines toward Unsaturated Molecules. Synthesis of Dihydro-3-Benzazocinones, N7‑amino Acids, N7‑amino Esters, and 3‑Benzazepines

Organometallics, 2014-01, Vol.33 (1), p.19-32

2014

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C–H Activation in Primary 3‑Phenylpropylamines: Synthesis of Seven-Membered Palladacycles through Orthometalation. Stoichiometric Preparation of Benzazepinones and Catalytic Synthesis of Ureas

Inorganic chemistry, 2016-06, Vol.55 (11), p.5520-5533

2016

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Norbornadiene as a Building Block for the Synthesis of Linked Benzazocinones and Benzazocinium Salts through Tetranuclear Carbopalladated Intermediates

Organometallics, 2017-01, Vol.36 (2), p.372-383

2017

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Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines

Organometallics, 2010-10, Vol.29 (19), p.4320-4338

2010

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Insertion Reactions on Carbopalladated Benzyne: From Eight- to Nine- and Ten-Membered Palladacycles. Applications to the Synthesis of N‑Heterocycles

Organometallics, 2014-11, Vol.33 (22), p.6420-6430

2014

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Reactivity toward Neutral N- and P‑Donor Ligands of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C Bond of Orthopalladated Homoveratrylamine and Phentermine. A New Example of the Transphobia Effect

Organometallics, 2014-01, Vol.33 (1), p.33-39

2014

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Reactivity of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C bond of Ortho-Palladated Phenethylamines toward Unsaturated Molecules. Synthesis of Dihydro-3-Benzazocinones, N 7 -amino Acids, N 7 -amino Esters, and 3-Benzazepines

Organometallics, 2014-01, Vol.33 (1), p.19-32

2014

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Benzyne-benzyne-RNC or CO triple sequential insertion into the Pd-C bond: synthesis of ten-membered N-heterocycles through stable ten- and eleven-membered palladacyclesDedicated to Prof. Antonio Laguna (Zaragoza University, Spain) on the occasion of his 65th birthday.Electronic supplementary information (ESI) available: Experimental details, spectroscopic data, NMR spectra, relevant crystallographic data and details of the refinements for the structures of compounds 2a and 4·CH2Cl2, hydrogen bon

2013-08

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Ortho Palladation and Functionalization of l-Phenylalanine Methyl Ester

Organometallics, 2007-05, Vol.26 (10), p.2768-2776

2007

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Chasing C,C‐Palladacycles

Synthesis and Reactivity of Model Intermediates Proposed for the Pd-Catalyzed Remote C–H Functionalization of N‑(2-Haloaryl)acrylamides

Benzyne-benzyne-RNC or CO triple sequential insertion into the Pd-C bond: synthesis of ten-membered N-heterocycles through stable ten- and eleven-membered palladacycles

The First Acetimine Gold(I) and Gold(III) Complexes and the First Acetonine Complexes

Regiospecific Functionalization of Pharmaceuticals and Other Biologically Active Molecules through Cyclopalladated Compounds. 2-Iodination of Phentermine and l-Tryptophan Methyl Ester

Sequential Insertion of Alkynes, Alkenes, and CO into the Pd-C Bond of ortho -Palladated Primary Phenethylamines: from η 3 -Allyl Complexes and Enlarged Palladacycles to Functionalized Arylalkylamines

Pd-Catalyzed Ring-Opening Polymerization of Cyclobutanols through C(sp3)–C(sp3) Bond Cleavage

Synthesis of Benzofused O- and N‑Heterocycles through Cascade Carbopalladation/Cross-Alkylation of Alkynes Involving the C–C Cleavage of Cyclobutanols

Sequential Insertion of Alkynes, Alkenes, and CO into the Pd–C Bond of ortho-Palladated Primary Phenethylamines: from η3‑Allyl Complexes and Enlarged Palladacycles to Functionalized Arylalkylamines

Ortho-Metalated Primary Amines. 6. The First Synthesis of Six-Membered Palladacycles from Primary Amines Containing Electron-Withdrawing Substituents: End of the Limiting Rules of Cope and Friedrich on Cyclopalladation of Benzyl- and Phenethylamines

ORTHO-PALLADATION OF PRIMARY AMINES: THE MYTH DISPELLED

Palladium-Assisted Formation of Carbon−Carbon Bonds. Part 10. Insertion Reactions of Isocyanides into the Pd−C Bond of Orthopalladated Primary Amines. Synthesis of 2-R-Aminoisoindolinium Salts (R = tBu, 2,6-Xylyl)

Epimerization of secondary alcohols by new homogeneous, low oxidation-state metal catalysts: carbon-hydrogen bond activation in rhenium alkoxide complexes (.eta.5-C5R5)Re(NO)(PPh3)(OCHRR')

Insertion reactions of isocyanides into the Metal-C(sp3) bonds of ylide complexes

Palladium-Mediated Functionalization of Benzofuran and Benzothiophene Cores

Reactivity of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C bond of Ortho-Palladated Phenethylamines toward Unsaturated Molecules. Synthesis of Dihydro-3-Benzazocinones, N7‑amino Acids, N7‑amino Esters, and 3‑Benzazepines

C–H Activation in Primary 3‑Phenylpropylamines: Synthesis of Seven-Membered Palladacycles through Orthometalation. Stoichiometric Preparation of Benzazepinones and Catalytic Synthesis of Ureas

Norbornadiene as a Building Block for the Synthesis of Linked Benzazocinones and Benzazocinium Salts through Tetranuclear Carbopalladated Intermediates

Insertion Reactions on Carbopalladated Benzyne: From Eight- to Nine- and Ten-Membered Palladacycles. Applications to the Synthesis of N‑Heterocycles

Reactivity toward Neutral N- and P‑Donor Ligands of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C Bond of Orthopalladated Homoveratrylamine and Phentermine. A New Example of the Transphobia Effect

Reactivity of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C bond of Ortho-Palladated Phenethylamines toward Unsaturated Molecules. Synthesis of Dihydro-3-Benzazocinones, N 7 -amino Acids, N 7 -amino Esters, and 3-Benzazepines

Ortho Palladation and Functionalization of l-Phenylalanine Methyl Ester

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