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The 3 rd degree of biomimetism: associating the cavity effect, Zn II coordination and internal base assistance for guest binding and activation

Chemical science (Cambridge), 2018, Vol.9 (24), p.5479-5487

2018

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Guest exchange in a biomimetic ZnII cavity-complex: kinetic control by a catalytic water, through pore selection, 2nd sphere assistance, and induced-fit processes

Inorganic chemistry frontiers, 2023-08, Vol.10 (19), p.5772-5781

2023

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Guest exchange in a biomimetic Zn cavity-complex: kinetic control by a catalytic water, through pore selection, 2nd sphere assistance, and induced-fit processes

Inorganic chemistry frontiers, 2023-09, Vol.1 (19), p.5772-5781

2023

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Architecture-Controlled “SMART” Calix[6]Arene Self-Assemblies in Aqueous Solution

Langmuir, 2007-04, Vol.23 (9), p.4849-4855

2007

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Hydrogen bonding and CH/π interactions for the stabilization of biomimetic zinc complexes: first examples of X-ray characterized alcohol and amide adducts to a tetrahedral dicationic Zn center

Chemical communications (Cambridge, England), 2001-01 (11), p.984-985

2001

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Supramolecular Stabilization of a Tris(imidazolyl) Zn−Aqua Complex Evidenced by X-ray Analysis: A Structural Model for Mono-Zinc Active Sites of Enzymes

Journal of the American Chemical Society, 2001-08, Vol.123 (34), p.8442-8443

2001

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Electrochemical Behavior of the Tris(pyridine)−Cu Funnel Complexes: An Overall Induced-Fit Process Involving an Entatic State through a Supramolecular Stress

Journal of the American Chemical Society, 2005-04, Vol.127 (15), p.5280-5281

2005

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First Insights into the Electronic Properties of a Cu(II) Center Embedded in the PN3 Cap of a Calix[6]arene-Based Ligand

Inorganic chemistry, 2007-01, Vol.46 (2), p.375-377

2007

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TREN and TMPA capped calix[6]arene metal complexes as ds-DNA/RNA binders

Acta crystallographica. Section A, Foundations and advances, 2022-08, Vol.78 (a2), p.e364-e364

2022

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The 3rd degree of biomimetism: associating the cavity effect, ZnII coordination and internal base assistance for guest binding and activation

Chemical science (Cambridge), 2018-06, Vol.9 (24), p.5479-5487

2018

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The 3rd degree of biomimetism: associating the cavity effect, ZnII coordination and internal base assistance for guest binding and activationElectronic supplementary information (ESI) available: Full NMR spectra, DOSY, IR, and ITC titrations. See DOI: 10.1039/c8sc01129j

2018-06

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The 3rd degree of biomimetism: associating the cavity effect, ZnII coordination and internal base assistance for guest binding and activation† †Electronic supplementary information (ESI) available: Full NMR spectra, DOSY, IR, and ITC titrations. See DOI: 10.1039/c8sc01129j

Chemical science (Cambridge), 2018-05, Vol.9 (24), p.5479-5487

2018

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Supramolecular control of an organic radical coupled to a metal ion embedded at the entrance of a hydrophobic cavity

Dalton transactions : an international journal of inorganic chemistry, 2003-01 (22), p.4216-4218

2003

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Guest exchange in a biomimetic Zn II cavity-complex: kinetic control by a catalytic water, through pore selection, 2nd sphere assistance, and induced-fit processes

Inorganic chemistry frontiers, 2023-09, Vol.10 (19), p.5772-5781

2023

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Supramolecular Assembly with Calix[6]arene and Copper Ions − Formation of a Novel Tetranuclear Core Exhibiting Unusual Redox Properties and Catecholase Activity

European journal of inorganic chemistry, 2002-08, Vol.2002 (8), p.2007-2014

2002

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Polarizing a Hydrophobic Cavity for the Efficient Binding of Organic Guests: The Case of Calix[6]tren, a Highly Efficient and Versatile Receptor for Neutral or Cationic Species

Journal of the American Chemical Society, 2005-06, Vol.127 (23), p.8517-8525

2005

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Solid‐State Chemistry at an Isolated Copper(I) Center with O2

Angewandte Chemie International Edition, 2009, Vol.48 (40), p.7383-7386

2009

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Mimicking the Protein Access Channel to a Metal Center: Effect of a Funnel Complex on Dissociative versus Associative Copper Redox Chemistry

Journal of the American Chemical Society, 2009-12, Vol.131 (49), p.17800-17807

2009

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Calix[6]tren and Copper(II): A Third Generation of Funnel Complexes on the Way to Redox Calix-Zymes

Proceedings of the National Academy of Sciences - PNAS, 2005-05, Vol.102 (19), p.6831-6836

2005

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Calix[6]arenes and Zinc: Biomimetic Receptors for Neutral Molecules

Journal of the American Chemical Society, 2000-07, Vol.122 (26), p.6183-6189

2000

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The First Water‐Soluble Copper(I) Calix[6]arene Complex Presenting a Hydrophobic Ligand Binding Pocket: A Remarkable Model for Active Sites in Metalloenzymes

Angewandte Chemie International Edition, 2002-03, Vol.41 (6), p.1044-1046

2002

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Calix[6]arene-Based Cuprous “Funnel Complexes”: A Mimic for the Substrate Access Channel to Metalloenzyme Active Sites

Journal of the American Chemical Society, 2002-02, Vol.124 (7), p.1334-1340

2002

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Unprecedented Selective ipso-Nitration of Calixarenes Monitored by the O-Substituents

Journal of organic chemistry, 2003-09, Vol.68 (18), p.7004-7008

2003

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Biomimetic Zinc Funnel Complexes Based on Calix[6]N3ArO Ligands: An Acid−Base Switch for Guest Binding

Journal of the American Chemical Society, 2005-10, Vol.127 (42), p.14833-14840

2005

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Supramolecular Assemblies with Calix[6]arenes and Copper Ions: from Dinuclear to Trinuclear Linear Arrangements of Hydroxo−Cu(II) Complexes

Inorganic chemistry, 2006-02, Vol.45 (3), p.1069-1077

2006

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The 3 rd degree of biomimetism: associating the cavity effect, Zn II coordination and internal base assistance for guest binding and activation

Guest exchange in a biomimetic ZnII cavity-complex: kinetic control by a catalytic water, through pore selection, 2nd sphere assistance, and induced-fit processes

Guest exchange in a biomimetic Zn cavity-complex: kinetic control by a catalytic water, through pore selection, 2nd sphere assistance, and induced-fit processes

Architecture-Controlled “SMART” Calix[6]Arene Self-Assemblies in Aqueous Solution

Hydrogen bonding and CH/π interactions for the stabilization of biomimetic zinc complexes: first examples of X-ray characterized alcohol and amide adducts to a tetrahedral dicationic Zn center

Supramolecular Stabilization of a Tris(imidazolyl) Zn−Aqua Complex Evidenced by X-ray Analysis: A Structural Model for Mono-Zinc Active Sites of Enzymes

Electrochemical Behavior of the Tris(pyridine)−Cu Funnel Complexes: An Overall Induced-Fit Process Involving an Entatic State through a Supramolecular Stress

First Insights into the Electronic Properties of a Cu(II) Center Embedded in the PN3 Cap of a Calix[6]arene-Based Ligand

TREN and TMPA capped calix[6]arene metal complexes as ds-DNA/RNA binders

The 3rd degree of biomimetism: associating the cavity effect, ZnII coordination and internal base assistance for guest binding and activation

The 3rd degree of biomimetism: associating the cavity effect, ZnII coordination and internal base assistance for guest binding and activationElectronic supplementary information (ESI) available: Full NMR spectra, DOSY, IR, and ITC titrations. See DOI: 10.1039/c8sc01129j

The 3rd degree of biomimetism: associating the cavity effect, ZnII coordination and internal base assistance for guest binding and activation† †Electronic supplementary information (ESI) available: Full NMR spectra, DOSY, IR, and ITC titrations. See DOI: 10.1039/c8sc01129j

Supramolecular control of an organic radical coupled to a metal ion embedded at the entrance of a hydrophobic cavity

Guest exchange in a biomimetic Zn II cavity-complex: kinetic control by a catalytic water, through pore selection, 2nd sphere assistance, and induced-fit processes

Supramolecular Assembly with Calix[6]arene and Copper Ions − Formation of a Novel Tetranuclear Core Exhibiting Unusual Redox Properties and Catecholase Activity

Polarizing a Hydrophobic Cavity for the Efficient Binding of Organic Guests: The Case of Calix[6]tren, a Highly Efficient and Versatile Receptor for Neutral or Cationic Species

Solid‐State Chemistry at an Isolated Copper(I) Center with O2

Mimicking the Protein Access Channel to a Metal Center: Effect of a Funnel Complex on Dissociative versus Associative Copper Redox Chemistry

Calix[6]tren and Copper(II): A Third Generation of Funnel Complexes on the Way to Redox Calix-Zymes

Calix[6]arenes and Zinc: Biomimetic Receptors for Neutral Molecules

The First Water‐Soluble Copper(I) Calix[6]arene Complex Presenting a Hydrophobic Ligand Binding Pocket: A Remarkable Model for Active Sites in Metalloenzymes

Calix[6]arene-Based Cuprous “Funnel Complexes”: A Mimic for the Substrate Access Channel to Metalloenzyme Active Sites

Unprecedented Selective ipso-Nitration of Calixarenes Monitored by the O-Substituents

Biomimetic Zinc Funnel Complexes Based on Calix[6]N3ArO Ligands: An Acid−Base Switch for Guest Binding

Supramolecular Assemblies with Calix[6]arenes and Copper Ions: from Dinuclear to Trinuclear Linear Arrangements of Hydroxo−Cu(II) Complexes

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