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Pyridoxal-5′-phosphate as the catalyst for radical isomerization in reactions of PLP-dependent aminomutases

Biochimica et biophysica acta, 2011-11, Vol.1814 (11), p.1548-1557

2011

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Radical reactions of thiamin pyrophosphate in 2-oxoacid oxidoreductases

Biochimica et biophysica acta, 2012-11, Vol.1824 (11), p.1291-1298

2012

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The Ubiquity of Iron

ACS chemical biology, 2012-09, Vol.7 (9), p.1477-1481

2012

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Identification of the Substrate Radical Intermediate Derived from Ethanolamine during Catalysis by Ethanolamine Ammonia-Lyase

Biochemistry (Easton), 2008-10, Vol.47 (43), p.11360-11366

2008

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EPR Spectroscopic and Computational Characterization of the Hydroxyethylidene-Thiamine Pyrophosphate Radical Intermediate of Pyruvate:Ferredoxin Oxidoreductase

Biochemistry (Easton), 2006-06, Vol.45 (23), p.7122-7131

2006

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Radical mechanisms in adenosylcobalamin-dependent enzymes

Current opinion in chemical biology, 2004-10, Vol.8 (5), p.477-483

Reed, George H

2004

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Isotope Effects in the Transient Phases of the Reaction Catalyzed by Ethanolamine Ammonia-Lyase: Determination of the Number of Exchangeable Hydrogens in the Enzyme−Cofactor Complex

Biochemistry (Easton), 2000-10, Vol.39 (39), p.12069-12075

2000

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Free Radical Mechanisms in Enzymology

Chemical reviews, 2006-08, Vol.106 (8), p.3302-3316

2006

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Characterization of a Succinyl-CoA Radical−Cob(II)alamin Spin Triplet Intermediate in the Reaction Catalyzed by Adenosylcobalamin-Dependent Methylmalonyl-CoA Mutase

Biochemistry (Easton), 2005-03, Vol.44 (9), p.3153-3158

2005

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Properties of Intermediates in the Catalytic Cycle of Oxalate Oxidoreductase and Its Suicide Inactivation by Pyruvate

Biochemistry (Easton), 2017-06, Vol.56 (22), p.2824-2835

2017

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Fourier Deconvolution Methods for Resolution Enhancement in Continuous-Wave EPR Spectroscopy

Methods in enzymology, 2015, Vol.563, p.23-36

2015

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Probing Nitrogen-Sensitive Steps in the Free-Radical-Mediated Deamination of Amino Alcohols by Ethanolamine Ammonia-Lyase

Journal of the American Chemical Society, 2006-06, Vol.128 (22), p.7120-7121

2006

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Identification of cis-Ethanesemidione as the Organic Radical Derived from Glycolaldehyde in the Suicide Inactivation of Dioldehydrase and of Ethanolamine Ammonia-Lyase

Biochemistry (Easton), 2000-05, Vol.39 (20), p.6250-6257

2000

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Radical Triplets and Suicide Inhibition in Reactions of 4-Thia-d- and 4-Thia-l-lysine with Lysine 5,6-Aminomutase

Biochemistry (Easton), 2009-09, Vol.48 (34), p.8151-8160

2009

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Analysis of the Electron Paramagnetic Resonance Spectrum of a Radical Intermediate in the Coenzyme B12-Dependent Ethanolamine Ammonia-Lyase Catalyzed Reaction of S-2-Aminopropanol

Biochemistry (Easton), 2002-07, Vol.41 (27), p.8580-8588

2002

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Structural and mechanistic studies of enolase

Current opinion in structural biology, 1996-12, Vol.6 (6), p.736-743

1996

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Suicide Inactivation of Dioldehydrase by 2-Chloroacetaldehyde: Formation of the 'cis-Ethanesemidione' Radical, and the Role of a Monovalent Cation

Helvetica chimica acta, 2003-11, Vol.86 (11), p.3764-3775

2003

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The Catalytic Mn2+ Sites in the Enolase−Inhibitor Complex: Crystallography, Single-Crystal EPR, and DFT Calculations

Journal of the American Chemical Society, 2007-04, Vol.129 (14), p.4240-4252

2007

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Reaction of AdoMet with ThiC Generates a Backbone Free Radical

Biochemistry (Easton), 2009-01, Vol.48 (2), p.217-219

2009

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The Enolase Superfamily: A General Strategy for Enzyme-Catalyzed Abstraction of the α-Protons of Carboxylic Acids

Biochemistry (Easton), 1996-12, Vol.35 (51), p.16489-16501

1996

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Lysine 2,3-Aminomutase: Rapid Mix−Freeze−Quench Electron Paramagnetic Resonance Studies Establishing the Kinetic Competence of a Substrate-Based Radical Intermediate

Biochemistry (Easton), 1996-08, Vol.35 (34), p.11081-11084

1996

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Structure of a substrate radical intermediate in the reaction of lysine 2,3-aminomutase

Biochemistry (Easton), 1992-11, Vol.31 (44), p.10782-10789

1992

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Characterization of an Allylic Analogue of the 5‘-Deoxyadenosyl Radical: An Intermediate in the Reaction of Lysine 2,3-Aminomutase

Biochemistry (Easton), 2001-07, Vol.40 (26), p.7773-7782

2001

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Pulsed Electron Paramagnetic Resonance Experiments Identify the Paramagnetic Intermediates in the Pyruvate Ferredoxin Oxidoreductase Catalytic Cycle

Journal of the American Chemical Society, 2006-03, Vol.128 (12), p.3888-3889

2006

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Structure of the Bis(Mg2+)−ATP−Oxalate Complex of the Rabbit Muscle Pyruvate Kinase at 2.1 Å Resolution: ATP Binding over a Barrel

Biochemistry (Easton), 1998-05, Vol.37 (18), p.6247-6255

1998

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Pyridoxal-5′-phosphate as the catalyst for radical isomerization in reactions of PLP-dependent aminomutases

Radical reactions of thiamin pyrophosphate in 2-oxoacid oxidoreductases

The Ubiquity of Iron

Identification of the Substrate Radical Intermediate Derived from Ethanolamine during Catalysis by Ethanolamine Ammonia-Lyase

EPR Spectroscopic and Computational Characterization of the Hydroxyethylidene-Thiamine Pyrophosphate Radical Intermediate of Pyruvate:Ferredoxin Oxidoreductase

Radical mechanisms in adenosylcobalamin-dependent enzymes

Isotope Effects in the Transient Phases of the Reaction Catalyzed by Ethanolamine Ammonia-Lyase: Determination of the Number of Exchangeable Hydrogens in the Enzyme−Cofactor Complex

Free Radical Mechanisms in Enzymology

Characterization of a Succinyl-CoA Radical−Cob(II)alamin Spin Triplet Intermediate in the Reaction Catalyzed by Adenosylcobalamin-Dependent Methylmalonyl-CoA Mutase

Properties of Intermediates in the Catalytic Cycle of Oxalate Oxidoreductase and Its Suicide Inactivation by Pyruvate

Fourier Deconvolution Methods for Resolution Enhancement in Continuous-Wave EPR Spectroscopy

Probing Nitrogen-Sensitive Steps in the Free-Radical-Mediated Deamination of Amino Alcohols by Ethanolamine Ammonia-Lyase

Identification of cis-Ethanesemidione as the Organic Radical Derived from Glycolaldehyde in the Suicide Inactivation of Dioldehydrase and of Ethanolamine Ammonia-Lyase

Radical Triplets and Suicide Inhibition in Reactions of 4-Thia-d- and 4-Thia-l-lysine with Lysine 5,6-Aminomutase

Analysis of the Electron Paramagnetic Resonance Spectrum of a Radical Intermediate in the Coenzyme B12-Dependent Ethanolamine Ammonia-Lyase Catalyzed Reaction of S-2-Aminopropanol

Structural and mechanistic studies of enolase

Suicide Inactivation of Dioldehydrase by 2-Chloroacetaldehyde: Formation of the 'cis-Ethanesemidione' Radical, and the Role of a Monovalent Cation

The Catalytic Mn2+ Sites in the Enolase−Inhibitor Complex: Crystallography, Single-Crystal EPR, and DFT Calculations

Reaction of AdoMet with ThiC Generates a Backbone Free Radical

The Enolase Superfamily: A General Strategy for Enzyme-Catalyzed Abstraction of the α-Protons of Carboxylic Acids

Lysine 2,3-Aminomutase: Rapid Mix−Freeze−Quench Electron Paramagnetic Resonance Studies Establishing the Kinetic Competence of a Substrate-Based Radical Intermediate

Structure of a substrate radical intermediate in the reaction of lysine 2,3-aminomutase

Characterization of an Allylic Analogue of the 5‘-Deoxyadenosyl Radical: An Intermediate in the Reaction of Lysine 2,3-Aminomutase

Pulsed Electron Paramagnetic Resonance Experiments Identify the Paramagnetic Intermediates in the Pyruvate Ferredoxin Oxidoreductase Catalytic Cycle

Structure of the Bis(Mg2+)−ATP−Oxalate Complex of the Rabbit Muscle Pyruvate Kinase at 2.1 Å Resolution: ATP Binding over a Barrel

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