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Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

Angewandte Chemie (International ed.), 2011-09, Vol.50 (39), p.9120-9123

International ed. in English, 2011

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Catalytic Enantioselective Synthesis of Tetrahydrofurans: A Dynamic Kinetic Asymmetric [3 + 2] Cycloaddition of Racemic Cyclopropanes and Aldehydes

Journal of the American Chemical Society, 2009-03, Vol.131 (9), p.3122-3123

2009

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Room Temperature Aryl Trifluoromethylation via Copper-Mediated Oxidative Cross-Coupling

Journal of organic chemistry, 2011-02, Vol.76 (4), p.1174-1176

2011

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Iron(II)-Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates

Angewandte Chemie (International ed.), 2012-03, Vol.51 (12), p.2947-2950

International ed. in English, 2012

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Dynamic Kinetic Asymmetric Synthesis of Substituted Pyrrolidines from Racemic Cyclopropanes and Aldimines: Reaction Development and Mechanistic Insights

Journal of the American Chemical Society, 2010-07, Vol.132 (28), p.9688-9692

2010

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Formal [4 + 2] Cycloaddition of Donor−Acceptor Cyclobutanes and Aldehydes: Stereoselective Access to Substituted Tetrahydropyrans

Journal of the American Chemical Society, 2009-10, Vol.131 (40), p.14202-14203

2009

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Scope and Mechanism for Lewis Acid-Catalyzed Cycloadditions of Aldehydes and Donor−Acceptor Cyclopropanes: Evidence for a Stereospecific Intimate Ion Pair Pathway

Journal of the American Chemical Society, 2008-07, Vol.130 (27), p.8642-8650

2008

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Diastereoselective Synthesis of Tetrahydrofurans via Palladium(0)-Catalyzed [3 + 2] Cycloaddition of Vinylcyclopropanes and Aldehydes

Organic letters, 2008-06, Vol.10 (12), p.2541-2544

2008

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CMC development of [14C]-labeled sotorasib for the conduct of microtracer human ADME study

AAPS open, 2023-12, Vol.9 (1), p.6-12, Article 6

2023

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Addressing Atropisomerism in the Development of Sotorasib, a Covalent Inhibitor of KRAS G12C: Structural, Analytical, and Synthetic Considerations

Accounts of chemical research, 2022-10, Vol.55 (20), p.2892-2903

2022

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Complexity-Building Annulations of Strained Cycloalkanes and CO π Bonds

Journal of organic chemistry, 2010-10, Vol.75 (19), p.6317-6325

2010

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Synthesis of Substituted Pyridines via Formal (3+3) Cycloaddition of Enamines with Unsaturated Aldehydes and Ketones

Journal of organic chemistry, 2022-07, Vol.87 (13), p.8437-8444

2022

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Characterization of false positive, contaminant-driven mutagenicity in impurities associated with the sotorasib drug substance

Regulatory toxicology and pharmacology, 2022-06, Vol.131, p.105162-105162, Article 105162

2022

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Enantioselective Synthesis of a γ‑Secretase Modulator via Vinylogous Dynamic Kinetic Resolution

Journal of organic chemistry, 2018-09, Vol.83 (18), p.11133-11144

2018

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Continuous Process Improvement in the Manufacture of Carfilzomib, Part 2: An Improved Process for Synthesis of the Epoxyketone Warhead

Organic process research & development, 2020-04, Vol.24 (4), p.490-499

2020

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Organic chemistry: A radical approach to diversity

Nature (London), 2011-12, Vol.480 (7376), p.184-185

2011

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Green Chemistry Articles of Interest to the Pharmaceutical Industry

Organic process research & development, 2020-03, Vol.24 (3), p.334-346

2020

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An Improved Process for the Preparation of a Covalent Kinase Inhibitor through a C–N Bond-Forming SNAr Reaction

Organic process research & development, 2018-07, Vol.22 (7), p.898-902

2018

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Green Chemistry Articles of Interest to the Pharmaceutical Industry

Organic process research & development, 2019-06, Vol.23 (6), p.1118-1133

2019

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Green Chemistry Articles of Interest to the Pharmaceutical Industry

Organic process research & development, 2019-11, Vol.23 (11), p.2287-2301

2019

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A radical approach to diversity

Nature (London), 2011-12, Vol.480 (7376), p.184-185

2011

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Developing and Optimizing a Quench-Crystallization Operation in Drug Substance Manufacturing

Organic process research & development, 2023-08, Vol.27 (8), p.1499-1509

2023

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Axial Chirality in the Sotorasib Drug Substance, Part 1: Development of a Classical Resolution to Prepare an Atropisomerically Pure Sotorasib Intermediate

Organic process research & development, 2022-09, Vol.26 (9), p.2629-2635

2022

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Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

Angewandte Chemie, 2011-09, Vol.123 (39), p.9286-9289

2011

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Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

Catalytic Enantioselective Synthesis of Tetrahydrofurans: A Dynamic Kinetic Asymmetric [3 + 2] Cycloaddition of Racemic Cyclopropanes and Aldehydes

Room Temperature Aryl Trifluoromethylation via Copper-Mediated Oxidative Cross-Coupling

Iron(II)-Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates

Dynamic Kinetic Asymmetric Synthesis of Substituted Pyrrolidines from Racemic Cyclopropanes and Aldimines: Reaction Development and Mechanistic Insights

Formal [4 + 2] Cycloaddition of Donor−Acceptor Cyclobutanes and Aldehydes: Stereoselective Access to Substituted Tetrahydropyrans

Scope and Mechanism for Lewis Acid-Catalyzed Cycloadditions of Aldehydes and Donor−Acceptor Cyclopropanes: Evidence for a Stereospecific Intimate Ion Pair Pathway

Diastereoselective Synthesis of Tetrahydrofurans via Palladium(0)-Catalyzed [3 + 2] Cycloaddition of Vinylcyclopropanes and Aldehydes

CMC development of [14C]-labeled sotorasib for the conduct of microtracer human ADME study

Addressing Atropisomerism in the Development of Sotorasib, a Covalent Inhibitor of KRAS G12C: Structural, Analytical, and Synthetic Considerations

Complexity-Building Annulations of Strained Cycloalkanes and CO π Bonds

Synthesis of Substituted Pyridines via Formal (3+3) Cycloaddition of Enamines with Unsaturated Aldehydes and Ketones

Characterization of false positive, contaminant-driven mutagenicity in impurities associated with the sotorasib drug substance

Enantioselective Synthesis of a γ‑Secretase Modulator via Vinylogous Dynamic Kinetic Resolution

Continuous Process Improvement in the Manufacture of Carfilzomib, Part 2: An Improved Process for Synthesis of the Epoxyketone Warhead

Organic chemistry: A radical approach to diversity

Green Chemistry Articles of Interest to the Pharmaceutical Industry

An Improved Process for the Preparation of a Covalent Kinase Inhibitor through a C–N Bond-Forming SNAr Reaction

Green Chemistry Articles of Interest to the Pharmaceutical Industry

Green Chemistry Articles of Interest to the Pharmaceutical Industry

A radical approach to diversity

Oxopyrido[2,3‑d]pyrimidines as Covalent L858R/T790M Mutant Selective Epidermal Growth Factor Receptor (EGFR) Inhibitors

Developing and Optimizing a Quench-Crystallization Operation in Drug Substance Manufacturing

Axial Chirality in the Sotorasib Drug Substance, Part 1: Development of a Classical Resolution to Prepare an Atropisomerically Pure Sotorasib Intermediate

Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

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