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N2‐to‐NH3 Conversion by a triphos–Iron Catalyst and Enhanced Turnover under Photolysis

Angewandte Chemie International Edition, 2017-06, Vol.56 (24), p.6921-6926

International ed. in English, 2017

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Cp Noninnocence Leads to a Remarkably Weak C–H Bond via Metallocene Protonation

Journal of the American Chemical Society, 2019-03, Vol.141 (11), p.4721-4729

2019

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Characterization of the Earliest Intermediate of Fe‑N2 Protonation: CW and Pulse EPR Detection of an Fe-NNH Species and Its Evolution to Fe-NNH2

Journal of the American Chemical Society, 2019-05, Vol.141 (20), p.8116-8127

2019

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Hydrazine Formation via Coupling of a Nickel(III)–NH2 Radical

Angewandte Chemie International Edition, 2021-02, Vol.60 (8), p.4009-4013

International ed. in English, 2021

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Ammonia Binds to the Dangler Manganese of the Photosystem II Oxygen-Evolving Complex

Journal of the American Chemical Society, 2015-07, Vol.137 (27), p.8829-8837

2015

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Understanding Covalent versus Spin–Orbit Coupling Contributions to Temperature-Dependent Electron Spin Relaxation in Cupric and Vanadyl Phthalocyanines

The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 2020-11, Vol.124 (44), p.9252-9260

2020

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Structural Effects of Ammonia Binding to the Mn4CaO5 Cluster of Photosystem II

The journal of physical chemistry. B, 2018-02, Vol.122 (5), p.1588-1599

2018

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Generating Potent C–H PCET Donors: Ligand-Induced Fe-to-Ring Proton Migration from a CpFeIII–H Complex Demonstrates a Promising Strategy

Journal of the American Chemical Society, 2020-11, Vol.142 (44), p.18963-18970

2020

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Photoinduced, Copper-Catalyzed Enantioconvergent Alkylations of Anilines by Racemic Tertiary Electrophiles: Synthesis and Mechanism

Journal of the American Chemical Society, 2022-03, Vol.144 (10), p.4550-4558

2022

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Electronic Structures of an [Fe(NNR2)]+/0/– Redox Series: Ligand Noninnocence and Implications for Catalytic Nitrogen Fixation

Inorganic chemistry, 2019-03, Vol.58 (5), p.3535-3549

2019

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Mononuclear Fe(I) and Fe(II) Acetylene Adducts and Their Reductive Protonation to Terminal Fe(IV) and Fe(V) Carbynes

Journal of the American Chemical Society, 2019-09, Vol.141 (38), p.15211-15221

2019

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Independent Mutation of Two Bridging Carboxylate Ligands Stabilizes Alternate Conformers of the Photosynthetic O2‑Evolving Mn4CaO5 Cluster in Photosystem II

The journal of physical chemistry. B, 2024-04, Vol.128 (16), p.3870-3884

2024

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Independent Mutation of Two Bridging Carboxylate Ligands Stabilizes Alternate Conformers of the Photosynthetic O 2 -Evolving Mn 4 CaO 5 Cluster in Photosystem II

The journal of physical chemistry. B, 2024-04, Vol.128 (16), p.3870-3884

2024

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Investigation of the C-N Bond-Forming Step in a Photoinduced, Copper-Catalyzed Enantioconvergent N-Alkylation: Characterization and Application of a Stabilized Organic Radical as a Mechanistic Probe

Journal of the American Chemical Society, 2022-03, Vol.144 (9), p.4114-4123

2022

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H 2 Evolution from a Thiolate-Bound Ni(III) Hydride

Journal of the American Chemical Society, 2020-04, Vol.142 (17), p.7827-7835

2020

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H2 Evolution from a Thiolate-Bound Ni(III) Hydride

Journal of the American Chemical Society, 2020-04, Vol.142 (17), p.7827-7835

2020

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17O Electron Nuclear Double Resonance Analysis of Compound I: Inverse Correlation between Oxygen Spin Population and Electron Donation

Journal of the American Chemical Society, 2022-10, Vol.144 (42), p.19272-19283

2022

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Coordination Number in High-Spin-Low-Spin Equilibrium in Cluster Models of the S 2 State of the Oxygen Evolving Complex

Journal of the American Chemical Society, 2023-07, Vol.145 (27), p.14592-14598

2023

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Coordination Number in High-Spin–Low-Spin Equilibrium in Cluster Models of the S2 State of the Oxygen Evolving Complex

Journal of the American Chemical Society, 2023-07, Vol.145 (27), p.14592-14598

2023

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Probing Redox Non‐Innocence in Iron–Carbene Complexes {Fe=C(H)Ar}10–11 by 1,2H and 13C Pulse Electron Paramagnetic Resonance

Angewandte Chemie International Edition, 2021-12, Vol.60 (52), p.27220-27224

International ed. in English, 2021

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Probing Redox Non-Innocence in Iron-Carbene Complexes {Fe=C(H)Ar} 10-11 by 1,2 H and 13 C Pulse Electron Paramagnetic Resonance

Angewandte Chemie International Edition, 2021-12, Vol.60 (52), p.27220-27224

2021

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Terminal Molybdenum Phosphides with d Electrons: Radical Character Promotes Coupling Chemistry

Angewandte Chemie International Edition, 2017-11, Vol.56 (46), p.14502-14506

International ed. in English, 2017

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An S = 1 / 2 Iron Complex Featuring N 2 , Thiolate, and Hydride Ligands: Reductive Elimination of H 2 and Relevant Thermochemical Fe-H Parameters

Journal of the American Chemical Society, 2018-05, Vol.140 (20), p.6374-6382

2018

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Reaction Discovery Using Spectroscopic Insights from an Enzymatic C–H Amination Intermediate

Journal of the American Chemical Society, 2024-07, Vol.146 (30), p.20556-20562

2024

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Terminal, Open-Shell Mo Carbide and Carbyne Complexes: Spin Delocalization and Ligand Noninnocence

Journal of the American Chemical Society, 2021-08, Vol.143 (33), p.13091-13102

2021

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N2‐to‐NH3 Conversion by a triphos–Iron Catalyst and Enhanced Turnover under Photolysis

Cp Noninnocence Leads to a Remarkably Weak C–H Bond via Metallocene Protonation

Characterization of the Earliest Intermediate of Fe‑N2 Protonation: CW and Pulse EPR Detection of an Fe-NNH Species and Its Evolution to Fe-NNH2

Hydrazine Formation via Coupling of a Nickel(III)–NH2 Radical

Ammonia Binds to the Dangler Manganese of the Photosystem II Oxygen-Evolving Complex

Understanding Covalent versus Spin–Orbit Coupling Contributions to Temperature-Dependent Electron Spin Relaxation in Cupric and Vanadyl Phthalocyanines

Structural Effects of Ammonia Binding to the Mn4CaO5 Cluster of Photosystem II

Generating Potent C–H PCET Donors: Ligand-Induced Fe-to-Ring Proton Migration from a CpFeIII–H Complex Demonstrates a Promising Strategy

Photoinduced, Copper-Catalyzed Enantioconvergent Alkylations of Anilines by Racemic Tertiary Electrophiles: Synthesis and Mechanism

Electronic Structures of an [Fe(NNR2)]+/0/– Redox Series: Ligand Noninnocence and Implications for Catalytic Nitrogen Fixation

Mononuclear Fe(I) and Fe(II) Acetylene Adducts and Their Reductive Protonation to Terminal Fe(IV) and Fe(V) Carbynes

Independent Mutation of Two Bridging Carboxylate Ligands Stabilizes Alternate Conformers of the Photosynthetic O2‑Evolving Mn4CaO5 Cluster in Photosystem II

Independent Mutation of Two Bridging Carboxylate Ligands Stabilizes Alternate Conformers of the Photosynthetic O 2 -Evolving Mn 4 CaO 5 Cluster in Photosystem II

Investigation of the C-N Bond-Forming Step in a Photoinduced, Copper-Catalyzed Enantioconvergent N-Alkylation: Characterization and Application of a Stabilized Organic Radical as a Mechanistic Probe

H 2 Evolution from a Thiolate-Bound Ni(III) Hydride

H2 Evolution from a Thiolate-Bound Ni(III) Hydride

17O Electron Nuclear Double Resonance Analysis of Compound I: Inverse Correlation between Oxygen Spin Population and Electron Donation

Coordination Number in High-Spin-Low-Spin Equilibrium in Cluster Models of the S 2 State of the Oxygen Evolving Complex

Coordination Number in High-Spin–Low-Spin Equilibrium in Cluster Models of the S2 State of the Oxygen Evolving Complex

Probing Redox Non‐Innocence in Iron–Carbene Complexes {Fe=C(H)Ar}10–11 by 1,2H and 13C Pulse Electron Paramagnetic Resonance

Probing Redox Non-Innocence in Iron-Carbene Complexes {Fe=C(H)Ar} 10-11 by 1,2 H and 13 C Pulse Electron Paramagnetic Resonance

Terminal Molybdenum Phosphides with d Electrons: Radical Character Promotes Coupling Chemistry

An S = 1 / 2 Iron Complex Featuring N 2 , Thiolate, and Hydride Ligands: Reductive Elimination of H 2 and Relevant Thermochemical Fe-H Parameters

Reaction Discovery Using Spectroscopic Insights from an Enzymatic C–H Amination Intermediate

Terminal, Open-Shell Mo Carbide and Carbyne Complexes: Spin Delocalization and Ligand Noninnocence

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