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Strategic Use of Visible-Light Photoredox Catalysis in Natural Product Synthesis

Chemical reviews, 2022-01, Vol.122 (2), p.1717-1751

2022

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Catalytic enantioselective synthesis of quaternary carbon stereocentres

Nature (London), 2014-12, Vol.516 (7530), p.181-191

2014

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Total Synthesis of Complex Cyclotryptamine Alkaloids: Stereocontrolled Construction of Quaternary Carbon Stereocenters

Angewandte Chemie (International ed.), 2007-01, Vol.46 (29), p.5488-5508

2007

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A Concise Synthesis of (−)-Aplyviolene Facilitated by a Strategic Tertiary Radical Conjugate Addition

Angewandte Chemie (International ed.), 2012-09, Vol.51 (38), p.9576-9580

International ed. in English, 2012

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Constructing Quaternary Carbons from N‑(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis

Journal of organic chemistry, 2015-06, Vol.80 (12), p.6025-6036

2015

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Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms

Angewandte Chemie (International ed.), 2016-03, Vol.55 (13), p.4156-4186

International ed. in English, 2016

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Facile Preparation of Spirolactones by an Alkoxycarbonyl Radical Cyclization–Cross‐Coupling Cascade

Angewandte Chemie International Edition, 2019-06, Vol.58 (25), p.8561-8565

International ed. in English, 2019

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Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling

Journal of the American Chemical Society, 2015-09, Vol.137 (35), p.11270-11273

2015

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Lewis Acid Activation of Fragment-Coupling Reactions of Tertiary Carbon Radicals Promoted by Visible-Light Irradiation of EDA Complexes

Organic letters, 2021-02, Vol.23 (3), p.1103-1106

2021

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Palladium(II)-Catalyzed Enantioselective Reactions Using COP Catalysts

Accounts of chemical research, 2016-10, Vol.49 (10), p.2220-2231

2016

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Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N‑Phthalimidoyl Oxalates By Visible-Light Photocatalysis

Journal of organic chemistry, 2015-06, Vol.80 (12), p.6012-6024

2015

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1,6-Addition of Tertiary Carbon Radicals Generated From Alcohols or Carboxylic Acids by Visible-Light Photoredox Catalysis

Organic letters, 2018-02, Vol.20 (3), p.868-871

2018

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H3K9me3 Inhibition Improves Memory, Promotes Spine Formation, and Increases BDNF Levels in the Aged Hippocampus

The Journal of neuroscience, 2016-03, Vol.36 (12), p.3611-3622

2016

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The Asymmetric Intramolecular Heck Reaction in Natural Product Total Synthesis

Chemical reviews, 2003-08, Vol.103 (8), p.2945-2964

2003

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Total Synthesis of (−)-Chromodorolide B By a Computationally-Guided Radical Addition/Cyclization/Fragmentation Cascade

Journal of the American Chemical Society, 2018-02, Vol.140 (8), p.3091-3102

2018

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Versatile Construction of 6‑Substituted cis-2,8-Dioxabicyclo[3.3.0]octan-3-ones: Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C

Journal of the American Chemical Society, 2017-05, Vol.139 (21), p.7192-7195

2017

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Catalytic Asymmetric Synthesis of All-Carbon Quaternary Stereocenters

Proceedings of the National Academy of Sciences - PNAS, 2004-04, Vol.101 (15), p.5363-5367

2004

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Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C via Convergent Fragment Coupling Using a Tertiary Carbon Radical

Journal of organic chemistry, 2018-07, Vol.83 (13), p.6958-6976

2018

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Constructing Quaternary Stereogenic Centers Using Tertiary Organocuprates and Tertiary Radicals. Total Synthesis of trans-Clerodane Natural Products

Journal of the American Chemical Society, 2015-01, Vol.137 (2), p.660-663

2015

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Total Synthesis of (±)- and (−)-Actinophyllic Acid

Journal of the American Chemical Society, 2010-04, Vol.132 (13), p.4894-4906

2010

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Enantioselective Total Synthesis of (+)-Gliocladine C: Convergent Construction of Cyclotryptamine-Fused Polyoxopiperazines and a General Approach for Preparing Epidithiodioxopiperazines from Trioxopiperazine Precursors

Journal of the American Chemical Society, 2011-05, Vol.133 (17), p.6549-6552

2011

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Total Synthesis of the Strychnos Alkaloid (+)-Minfiensine: Tandem Enantioselective Intramolecular Heck−Iminium Ion Cyclization

Journal of the American Chemical Society, 2008-04, Vol.130 (15), p.5368-5377

2008

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General Approach for Preparing Epidithiodioxopiperazines from Trioxopiperazine Precursors: Enantioselective Total Syntheses of (+)- and (−)-Gliocladine C, (+)-Leptosin D, (+)-T988C, (+)-Bionectin A, and (+)-Gliocladin A

Journal of the American Chemical Society, 2013-03, Vol.135 (10), p.4117-4128

2013

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Contiguous Stereogenic Quaternary Carbons: A Daunting Challenge in Natural Products Synthesis

Proceedings of the National Academy of Sciences - PNAS, 2004-08, Vol.101 (33), p.11943-11948

2004

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Fragment Coupling with Tertiary Radicals Generated by Visible-Light Photocatalysis

Accounts of chemical research, 2016-08, Vol.49 (8), p.1578-1586

2016

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Strategic Use of Visible-Light Photoredox Catalysis in Natural Product Synthesis

Catalytic enantioselective synthesis of quaternary carbon stereocentres

Total Synthesis of Complex Cyclotryptamine Alkaloids: Stereocontrolled Construction of Quaternary Carbon Stereocenters

A Concise Synthesis of (−)-Aplyviolene Facilitated by a Strategic Tertiary Radical Conjugate Addition

Constructing Quaternary Carbons from N‑(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis

Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms

Facile Preparation of Spirolactones by an Alkoxycarbonyl Radical Cyclization–Cross‐Coupling Cascade

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling

Lewis Acid Activation of Fragment-Coupling Reactions of Tertiary Carbon Radicals Promoted by Visible-Light Irradiation of EDA Complexes

Palladium(II)-Catalyzed Enantioselective Reactions Using COP Catalysts

Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N‑Phthalimidoyl Oxalates By Visible-Light Photocatalysis

1,6-Addition of Tertiary Carbon Radicals Generated From Alcohols or Carboxylic Acids by Visible-Light Photoredox Catalysis

H3K9me3 Inhibition Improves Memory, Promotes Spine Formation, and Increases BDNF Levels in the Aged Hippocampus

The Asymmetric Intramolecular Heck Reaction in Natural Product Total Synthesis

Total Synthesis of (−)-Chromodorolide B By a Computationally-Guided Radical Addition/Cyclization/Fragmentation Cascade

Versatile Construction of 6‑Substituted cis-2,8-Dioxabicyclo[3.3.0]octan-3-ones: Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C

Catalytic Asymmetric Synthesis of All-Carbon Quaternary Stereocenters

Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C via Convergent Fragment Coupling Using a Tertiary Carbon Radical

Constructing Quaternary Stereogenic Centers Using Tertiary Organocuprates and Tertiary Radicals. Total Synthesis of trans-Clerodane Natural Products

Total Synthesis of (±)- and (−)-Actinophyllic Acid

Enantioselective Total Synthesis of (+)-Gliocladine C: Convergent Construction of Cyclotryptamine-Fused Polyoxopiperazines and a General Approach for Preparing Epidithiodioxopiperazines from Trioxopiperazine Precursors

Total Synthesis of the Strychnos Alkaloid (+)-Minfiensine: Tandem Enantioselective Intramolecular Heck−Iminium Ion Cyclization

General Approach for Preparing Epidithiodioxopiperazines from Trioxopiperazine Precursors: Enantioselective Total Syntheses of (+)- and (−)-Gliocladine C, (+)-Leptosin D, (+)-T988C, (+)-Bionectin A, and (+)-Gliocladin A

Contiguous Stereogenic Quaternary Carbons: A Daunting Challenge in Natural Products Synthesis

Fragment Coupling with Tertiary Radicals Generated by Visible-Light Photocatalysis

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