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Silylboranes as New Tools in Organic Synthesis

Bulletin of the Chemical Society of Japan, 2009, Vol.82 (1), p.29-49

2009

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Regioselective Synthesis of 1,2-Dihydropyridines by Rhodium-Catalyzed Hydroboration of Pyridines

Journal of the American Chemical Society, 2012-02, Vol.134 (8), p.3699-3702

2012

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Asymmetric Cycloisomerization of o‐Alkenyl‐N‐Methylanilines to Indolines by Iridium‐Catalyzed C(sp3)−H Addition to Carbon–Carbon Double Bonds

Angewandte Chemie International Edition, 2017-11, Vol.56 (45), p.14272-14276

International ed. in English, 2017

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Construction of Silicon-Containing Seven-Membered Rings by Catalytic [4 + 2 + 1] Cycloaddition through Rhodium Silylenoid

Organic letters, 2020-04, Vol.22 (8), p.2961-2966

2020

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Iridium-catalyzed enantioselective intramolecular hydroarylation of allylic aryl ethers devoid of a directing group on the aryl group

Chemical communications (Cambridge, England), 2021-12, Vol.57 (99), p.13542-13545

2021

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Catalytic Generation of Rhodium Silylenoid for Alkene–Alkyne–Silylene [2 + 2 + 1] Cycloaddition

Organic letters, 2019-03, Vol.21 (6), p.1649-1653

2019

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4,4′-Bipyridine-catalyzed Stereoselective trans -Diboration of Acetylenedicarboxylates to 2,3-Diborylfumarates

Chemistry letters, 2017-12, Vol.46 (12), p.1793-1796

2017

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Iridium-catalyzed Enantioselective Intramolecular Cross-dehydrogenative Coupling of Alkyl Aryl Ethers Giving Enantioenriched 2,3-Dihydrobenzofurans

Chemistry letters, 2022-06, Vol.51 (6), p.601-604

2022

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Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes

Journal of the American Chemical Society, 2012-10, Vol.134 (42), p.17416-17419

2012

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Iridium‐Catalyzed C(sp3)−H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3‐Dihydrobenzofurans

Advanced synthesis & catalysis, 2019-10, Vol.361 (19), p.4448-4453

2019

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Intramolecular Addition of a Dimethylamino C(sp3)–H Bond across C–C Triple Bonds Using IrCl(DTBM-SEGPHOS)(ethylene) Catalyst: Synthesis of Indoles from 2-Alkynyl-N-methylanilines

Synthesis (Stuttgart), 2021-09, Vol.53 (17), p.3057-3064

2021

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Tandem C–H Transformations by a Single Iridium Catalyst: Direct Access to Indoles and Indolines from o‑Alkyl‑N‑methylanilines

ACS catalysis, 2020-03, Vol.10 (5), p.3152-3157

2020

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Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines

Journal of the American Chemical Society, 2011-05, Vol.133 (19), p.7324-7327

2011

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Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)–H Borylation at the Methyl Group on Silicon

Journal of organic chemistry, 2017-03, Vol.82 (6), p.2943-2956

2017

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Synthesis of Disilanes, Dihydrosiloles, and 1,4‐Disilacyclohexa‐2,5‐dienes by Transition‐Metal‐Free Transfer of Diphenylsilylene and Dimethylsilylene from Silylboronic Esters

European journal of organic chemistry, 2022-03, Vol.2022 (12), p.n/a

2022

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Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination

Journal of the American Chemical Society, 2010-09, Vol.132 (35), p.12194-12196

2010

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Iridium-Catalyzed Intramolecular Methoxy C−H Addition to Carbon-Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes

Chemistry : a European journal, 2016-07, Vol.22 (30), p.10415-10419

2016

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4,4′-Bipyridyl-Catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron

Organic letters, 2019-12, Vol.21 (24), p.9812-9817

2019

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Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium-Catalyzed C(sp3)–H Borylation

Organometallics, 2013-11, Vol.32 (21), p.6170-6173

2013

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Pyridine‐Based Organocatalysts for Regioselective syn‐1,2‐Silaboration of Terminal Alkynes and Allenes

Asian journal of organic chemistry, 2019-07, Vol.8 (7), p.1092-1096

2019

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Mechanism of 2,6-Dichloro-4,4′-bipyridine-Catalyzed Diboration of Pyrazines Involving a Bipyridine-Stabilized Boryl Radical

Bulletin of the Chemical Society of Japan, 2021-07, Vol.94 (7), p.1894-1902

2021

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A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp3)–H Borylation and Conversion to Functionalized Siloxanes

Organometallics, 2016-06, Vol.35 (11), p.1601-1603

2016

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Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

Chemical communications (Cambridge, England), 2012-01, Vol.48 (68), p.8571-8573

2012

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Regio- and Enantioselective Allylic Amination of Achiral Allylic Esters Catalyzed by an Iridium−Phosphoramidite Complex

Journal of the American Chemical Society, 2002-12, Vol.124 (51), p.15164-15165

2002

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Palladium-Catalyzed Asymmetric Silaborative C−C Cleavage of meso-Methylenecyclopropanes

Journal of the American Chemical Society, 2007-03, Vol.129 (12), p.3518-3519

2007

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Silylboranes as New Tools in Organic Synthesis

Regioselective Synthesis of 1,2-Dihydropyridines by Rhodium-Catalyzed Hydroboration of Pyridines

Asymmetric Cycloisomerization of o‐Alkenyl‐N‐Methylanilines to Indolines by Iridium‐Catalyzed C(sp3)−H Addition to Carbon–Carbon Double Bonds

Construction of Silicon-Containing Seven-Membered Rings by Catalytic [4 + 2 + 1] Cycloaddition through Rhodium Silylenoid

Iridium-catalyzed enantioselective intramolecular hydroarylation of allylic aryl ethers devoid of a directing group on the aryl group

Catalytic Generation of Rhodium Silylenoid for Alkene–Alkyne–Silylene [2 + 2 + 1] Cycloaddition

4,4′-Bipyridine-catalyzed Stereoselective trans -Diboration of Acetylenedicarboxylates to 2,3-Diborylfumarates

Iridium-catalyzed Enantioselective Intramolecular Cross-dehydrogenative Coupling of Alkyl Aryl Ethers Giving Enantioenriched 2,3-Dihydrobenzofurans

Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes

Iridium‐Catalyzed C(sp3)−H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3‐Dihydrobenzofurans

Intramolecular Addition of a Dimethylamino C(sp3)–H Bond across C–C Triple Bonds Using IrCl(DTBM-SEGPHOS)(ethylene) Catalyst: Synthesis of Indoles from 2-Alkynyl-N-methylanilines

Tandem C–H Transformations by a Single Iridium Catalyst: Direct Access to Indoles and Indolines from o‑Alkyl‑N‑methylanilines

Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines

Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)–H Borylation at the Methyl Group on Silicon

Synthesis of Disilanes, Dihydrosiloles, and 1,4‐Disilacyclohexa‐2,5‐dienes by Transition‐Metal‐Free Transfer of Diphenylsilylene and Dimethylsilylene from Silylboronic Esters

Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination

Iridium-Catalyzed Intramolecular Methoxy C−H Addition to Carbon-Carbon Triple Bonds: Direct Synthesis of 3-Substituted Benzofurans from o-Methoxyphenylalkynes

4,4′-Bipyridyl-Catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron

Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium-Catalyzed C(sp3)–H Borylation

Pyridine‐Based Organocatalysts for Regioselective syn‐1,2‐Silaboration of Terminal Alkynes and Allenes

Mechanism of 2,6-Dichloro-4,4′-bipyridine-Catalyzed Diboration of Pyrazines Involving a Bipyridine-Stabilized Boryl Radical

A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp3)–H Borylation and Conversion to Functionalized Siloxanes

Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

Regio- and Enantioselective Allylic Amination of Achiral Allylic Esters Catalyzed by an Iridium−Phosphoramidite Complex

Palladium-Catalyzed Asymmetric Silaborative C−C Cleavage of meso-Methylenecyclopropanes

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