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Alkali‐Metal Mediation: Diversity of Applications in Main‐Group Organometallic Chemistry

Angewandte Chemie International Edition, 2021-04, Vol.60 (17), p.9247-9262

International ed. in English, 2021

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Avant-Garde Metalating Agents: Structural Basis of Alkali-Metal-Mediated Metalation

Accounts of chemical research, 2009-06, Vol.42 (6), p.743-755

Mulvey, Robert E

2009

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Alkali-Metal-Mediated Synergistic Effects in Polar Main Group Organometallic Chemistry

Chemical reviews, 2019-07, Vol.119 (14), p.8332-8405

2019

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Synthetically Important Alkali-Metal Utility Amides: Lithium, Sodium, and Potassium Hexamethyldisilazides, Diisopropylamides, and Tetramethylpiperidides

Angewandte Chemie (International ed.), 2013-10, Vol.52 (44), p.11470-11487

International ed. in English, 2013

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Deprotonative Metalation Using Ate Compounds: Synergy, Synthesis, and Structure Building

Angewandte Chemie (International ed.), 2007-01, Vol.46 (21), p.3802-3824

2007

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An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry

Dalton transactions : an international journal of inorganic chemistry, 2013-01, Vol.42 (19), p.6676-6693

Mulvey, Robert E

2013

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Trans‐Metal‐Trapping: Concealed Crossover Complexes En Route to Transmetallation?

Chemistry : a European journal, 2018-06, Vol.24 (31), p.7786-7793

2018

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Modern Ate Chemistry: Applications of Synergic Mixed Alkali-Metal−Magnesium or −Zinc Reagents in Synthesis and Structure Building

Organometallics, 2006-02, Vol.25 (5), p.1060-1075

Mulvey, Robert E

2006

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Split Personality of Lithium Chloride: Recent Salt Effects in Organometallic Recipes

Angewandte Chemie (International ed.), 2011-07, Vol.50 (29), p.6448-6450

International ed. in English, 2011

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Rubidium and caesium aluminyls: synthesis, structures and reactivity in C-H bond activation of benzene

Chemical communications (Cambridge, England), 2022-01, Vol.58 (9), p.139-1393

2022

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Directed ortho-meta′- and meta-meta′-dimetalations: A template base approach to deprotonation

Science (American Association for the Advancement of Science), 2014-11, Vol.346 (6211), p.834-837

2014

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Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans-Metal-Trapping

Angewandte Chemie (International ed.), 2016-10, Vol.55 (42), p.13147-13150

International ed. in English, 2016

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LiTMP Trans‐Metal‐Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

Angewandte Chemie International Edition, 2017-08, Vol.56 (32), p.9566-9570

International ed. in English, 2017

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Donor‐influenced Structure–Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido‐Monohydrido‐Dialkylaluminates

Chemistry : a European journal, 2018-07, Vol.24 (39), p.9940-9948

2018

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Facile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagent

Chemical communications (Cambridge, England), 2015-03, Vol.51 (25), p.5452-5455

2015

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Organozinc Pivalate Reagents: Segregation, Solubility, Stabilization, and Structural Insights

Angewandte Chemie (International ed.), 2014-03, Vol.53 (10), p.2706-2710

International ed. in English, 2014

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Synergic Sedation of Sensitive Anions: Alkali-Mediated Zincation of Cyclic Ethers and Ethene

Science (American Association for the Advancement of Science), 2009-10, Vol.326 (5953), p.706-708

2009

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Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran

Nature chemistry, 2010-07, Vol.2 (7), p.588-591

2010

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"LiZn(TMP)3", a Zincate or a Turbo-Lithium Amide Reagent? DOSY NMR Spectroscopic Evidence

Angewandte Chemie (International ed.), 2011-10, Vol.50 (41), p.9668-9671

International ed. in English, 2011

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Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases

Angewandte Chemie (International ed.), 2008-10, Vol.47 (42), p.8079-8081

2008

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Incorporating Trimethylaluminium into the Structures of Alkali Metal (Li, Na, K, Cs) dihydropyridines

Zeitschrift für anorganische und allgemeine Chemie (1950), 2023-03, Vol.649 (5), p.n/a

2023

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Concealed Cyclotrimeric Polymorph of Lithium 2,2,6,6-Tetramethylpiperidide Unconcealed: X-Ray Crystallographic and NMR Spectroscopic Studies

Chemistry : a European journal, 2013-10, Vol.19 (42), p.14069-14075

2013

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Diisopropylamide and TMP Turbo-Grignard Reagents: A Structural Rationale for their Contrasting Reactivities

Angewandte Chemie (International ed.), 2010-04, Vol.49 (18), p.3185-3188

2010

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Alkali-Metal-Mediated Manganation: A Method for Directly Attaching Manganese(II) Centers to Aromatic Frameworks

Angewandte Chemie (International ed.), 2007-01, Vol.46 (7), p.1105-1108

2007

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Synthesis, characterisation, and catalytic application of a soluble molecular carrier of sodium hydride activated by a substituted 4-(dimethylamino)pyridine

Communications chemistry, 2024-04, Vol.7 (1), p.94-94, Article 94

2024

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Alkali‐Metal Mediation: Diversity of Applications in Main‐Group Organometallic Chemistry

Avant-Garde Metalating Agents: Structural Basis of Alkali-Metal-Mediated Metalation

Alkali-Metal-Mediated Synergistic Effects in Polar Main Group Organometallic Chemistry

Synthetically Important Alkali-Metal Utility Amides: Lithium, Sodium, and Potassium Hexamethyldisilazides, Diisopropylamides, and Tetramethylpiperidides

Deprotonative Metalation Using Ate Compounds: Synergy, Synthesis, and Structure Building

An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry

Trans‐Metal‐Trapping: Concealed Crossover Complexes En Route to Transmetallation?

Modern Ate Chemistry: Applications of Synergic Mixed Alkali-Metal−Magnesium or −Zinc Reagents in Synthesis and Structure Building

Split Personality of Lithium Chloride: Recent Salt Effects in Organometallic Recipes

Rubidium and caesium aluminyls: synthesis, structures and reactivity in C-H bond activation of benzene

Directed ortho-meta′- and meta-meta′-dimetalations: A template base approach to deprotonation

Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans-Metal-Trapping

LiTMP Trans‐Metal‐Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

Donor‐influenced Structure–Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido‐Monohydrido‐Dialkylaluminates

Facile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagent

Organozinc Pivalate Reagents: Segregation, Solubility, Stabilization, and Structural Insights

Synergic Sedation of Sensitive Anions: Alkali-Mediated Zincation of Cyclic Ethers and Ethene

Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran

"LiZn(TMP)3", a Zincate or a Turbo-Lithium Amide Reagent? DOSY NMR Spectroscopic Evidence

Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases

Incorporating Trimethylaluminium into the Structures of Alkali Metal (Li, Na, K, Cs) dihydropyridines

Concealed Cyclotrimeric Polymorph of Lithium 2,2,6,6-Tetramethylpiperidide Unconcealed: X-Ray Crystallographic and NMR Spectroscopic Studies

Diisopropylamide and TMP Turbo-Grignard Reagents: A Structural Rationale for their Contrasting Reactivities

Alkali-Metal-Mediated Manganation: A Method for Directly Attaching Manganese(II) Centers to Aromatic Frameworks

Synthesis, characterisation, and catalytic application of a soluble molecular carrier of sodium hydride activated by a substituted 4-(dimethylamino)pyridine

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