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Recent Mechanistic and Synthetic Developments in the Chemistry of Transition-Metal Vinylidene Complexes

Chemistry : a European journal, 2010-07, Vol.16 (28), p.8238-8247

Lynam, Jason M.

2010

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Gold-alkynyls in catalysis: alkyne activation, gold cumulenes and nuclearity

Dalton transactions : an international journal of inorganic chemistry, 2016-08, Vol.45 (32), p.12611-12626

2016

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Computational mechanistic study in organometallic catalysis: Why prediction is still a challenge

Wiley interdisciplinary reviews. Computational molecular science, 2022-07, Vol.12 (4), p.e1590-n/a

2022

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Metallomimetic C–F Activation Catalysis by Simple Phosphines

Journal of the American Chemical Society, 2024-01, Vol.146 (3), p.2005-2014

2024

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Addition to “Metallomimetic C–F Activation Catalysis by Simple Phosphines”

Journal of the American Chemical Society, 2024-04, Vol.146 (16), p.11578-11578

2024

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Unveiling Mechanistic Complexity in Manganese-Catalyzed C–H Bond Functionalization Using IR Spectroscopy Over 16 Orders of Magnitude in Time

Accounts of chemical research, 2024-03, Vol.57 (6), p.919-932

2024

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Internal Nucleophilic Catalyst Mediated Cyclisation/Ring Expansion Cascades for the Synthesis of Medium‐Sized Lactones and Lactams

Angewandte Chemie International Edition, 2019-09, Vol.58 (39), p.13942-13947

International ed. in English, 2019

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Mapping Out the Role of σ‑Silane Complexes in the Ruthenium-Catalyzed Hydrosilylation of Nitriles

Organometallics, 2023-11, Vol.42 (21), p.3153-3163

2023

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IrI(η4-diene) precatalyst activation by strong bases: formation of an anionic IrIII tetrahydride

Dalton transactions : an international journal of inorganic chemistry, 2023-02, Vol.52 (8), p.2495-2505

2023

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Ring Expansion Strategies for the Synthesis of Medium Sized Ring and Macrocyclic Sulfonamides

Angewandte Chemie International Edition, 2023-03, Vol.62 (13), p.e202217178-n/a

International ed. in English, 2023

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Small bite-angle 2-phosphinophosphinine ligands enable rhodium-catalysed hydroboration of carbonyls

Chemical communications (Cambridge, England), 2018, Vol.54 (43), p.5482-5485

2018

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Selectivity, Speciation, and Substrate Control in the Gold-Catalyzed Coupling of Indoles and Alkynes

Organometallics, 2022-02, Vol.41 (4), p.497-507

2022

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Direct Observation of the Microscopic Reverse of the Ubiquitous Concerted Metalation Deprotonation Step in C–H Bond Activation Catalysis

Journal of the American Chemical Society, 2021-01, Vol.143 (3), p.1356-1364

2021

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Ring expansion reactions of PO-containing molecules

Chemical communications (Cambridge, England), 2023-06, Vol.59 (51), p.7927-7930

2023

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Manganese(I)-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination

Angewandte Chemie International Edition, 2016-09, Vol.55 (40), p.12455-12459

International ed. in English, 2016

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Correction: On the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand

Dalton transactions : an international journal of inorganic chemistry, 2024-04, Vol.53 (17), p.7641-7642

2024

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Mechanistic Insight into Catalytic Redox-Neutral C–H Bond Activation Involving Manganese(I) Carbonyls: Catalyst Activation, Turnover, and Deactivation Pathways Reveal an Intricate Network of Steps

Journal of the American Chemical Society, 2019-02, Vol.141 (6), p.2316-2328

2019

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Visible‐Light‐Mediated Energy Transfer Enables the Synthesis of β‐Lactams via Intramolecular Hydrogen Atom Transfer

Angewandte Chemie International Edition, 2022-11, Vol.61 (48), p.e202213086-n/a

International ed. in English, 2022

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On the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand

Dalton transactions : an international journal of inorganic chemistry, 2023-01, Vol.52 (4), p.872-876

2023

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Delineating the critical role of acid additives in Mn-catalysed C-H bond functionalisation processes

Chemical communications (Cambridge, England), 2019-03, Vol.55 (22), p.3211-3214

2019

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Indole-ynones as Privileged Substrates for Radical Dearomatizing Spirocyclization Cascades

Organic letters, 2022-01, Vol.24 (2), p.668-674

2022

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Deciphering complexity in Pd–catalyzed cross-couplings

Nature communications, 2024-05, Vol.15 (1), p.3968-3968, Article 3968

2024

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Ligand-to-metal charge transfer facilitates photocatalytic oxygen atom transfer (OAT) with cis -dioxo molybdenum(vi)-Schiff base complexes

Chemical science (Cambridge), 2024-10, Vol.15 (39), p.16186-16195

2024

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Ruthenium-Mediated C–H Functionalization of Pyridine: The Role of Vinylidene and Pyridylidene Ligands

Journal of the American Chemical Society, 2013-02, Vol.135 (6), p.2222-2234

2013

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Modification of the deoxy-myoglobin/carbonmonoxy-myoglobin UV-vis assay for reliable determination of CO-release rates from organometallic carbonyl complexes

Dalton transactions : an international journal of inorganic chemistry, 2011-01, Vol.40 (21), p.5755-5761

2011

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Recent Mechanistic and Synthetic Developments in the Chemistry of Transition-Metal Vinylidene Complexes

Gold-alkynyls in catalysis: alkyne activation, gold cumulenes and nuclearity

Computational mechanistic study in organometallic catalysis: Why prediction is still a challenge

Metallomimetic C–F Activation Catalysis by Simple Phosphines

Addition to “Metallomimetic C–F Activation Catalysis by Simple Phosphines”

Unveiling Mechanistic Complexity in Manganese-Catalyzed C–H Bond Functionalization Using IR Spectroscopy Over 16 Orders of Magnitude in Time

Internal Nucleophilic Catalyst Mediated Cyclisation/Ring Expansion Cascades for the Synthesis of Medium‐Sized Lactones and Lactams

Mapping Out the Role of σ‑Silane Complexes in the Ruthenium-Catalyzed Hydrosilylation of Nitriles

IrI(η4-diene) precatalyst activation by strong bases: formation of an anionic IrIII tetrahydride

Ring Expansion Strategies for the Synthesis of Medium Sized Ring and Macrocyclic Sulfonamides

Small bite-angle 2-phosphinophosphinine ligands enable rhodium-catalysed hydroboration of carbonyls

Selectivity, Speciation, and Substrate Control in the Gold-Catalyzed Coupling of Indoles and Alkynes

Direct Observation of the Microscopic Reverse of the Ubiquitous Concerted Metalation Deprotonation Step in C–H Bond Activation Catalysis

Ring expansion reactions of PO-containing molecules

Manganese(I)-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination

Correction: On the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand

Mechanistic Insight into Catalytic Redox-Neutral C–H Bond Activation Involving Manganese(I) Carbonyls: Catalyst Activation, Turnover, and Deactivation Pathways Reveal an Intricate Network of Steps

Visible‐Light‐Mediated Energy Transfer Enables the Synthesis of β‐Lactams via Intramolecular Hydrogen Atom Transfer

On the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand

Delineating the critical role of acid additives in Mn-catalysed C-H bond functionalisation processes

Indole-ynones as Privileged Substrates for Radical Dearomatizing Spirocyclization Cascades

Deciphering complexity in Pd–catalyzed cross-couplings

Ligand-to-metal charge transfer facilitates photocatalytic oxygen atom transfer (OAT) with cis -dioxo molybdenum(vi)-Schiff base complexes

Ruthenium-Mediated C–H Functionalization of Pyridine: The Role of Vinylidene and Pyridylidene Ligands

Modification of the deoxy-myoglobin/carbonmonoxy-myoglobin UV-vis assay for reliable determination of CO-release rates from organometallic carbonyl complexes

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