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Expedient Synthesis of Fused Azepine Derivatives Using a Sequential Rhodium(II)-Catalyzed Cyclopropanation/1-Aza-Cope Rearrangement of Dienyltriazoles

Angewandte Chemie (International ed.), 2014-09, Vol.53 (37), p.9904-9908

International ed. in English, 2014

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Stereodivergent Intramolecular C(sp3)–H Functionalization of Azavinyl Carbenes: Synthesis of Saturated Heterocycles and Fused N‑Heterotricycles

Journal of the American Chemical Society, 2015-07, Vol.137 (26), p.8368-8371

2015

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One-Pot Synthesis of Strain-Release Reagents from Methyl Sulfones

Journal of the American Chemical Society, 2022-03, Vol.144 (11), p.4764-4769

2022

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Synthesis of Cyclopentenones with Reverse Pauson–Khand Regiocontrol via Ni-Catalyzed C–C Activation of Cyclopropanone

Organic letters, 2020-11, Vol.22 (22), p.8872-8876

2020

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Benzimidazolyl Palladium Complexes as Highly Active and General Bifunctional Catalysts in Sustainable Cross-Coupling Reactions

ACS catalysis, 2019-08, Vol.9 (8), p.6993-6998

2019

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Stereospecific Synthesis of Enantioenriched Alkylidenecyclobutanones via Formal Vinylidene Insertion into Cyclopropanone Equivalents

Organic letters, 2021-08, Vol.23 (16), p.6482-6487

2021

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Asymmetric Rh(II)-Catalyzed Cyclopropanation of Alkenes with Diacceptor Diazo Compounds: p-Methoxyphenyl Ketone as a General Stereoselectivity Controlling Group

Journal of the American Chemical Society, 2011-06, Vol.133 (23), p.8972-8981

2011

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Experimental Evidence for the All-Up Reactive Conformation of Chiral Rhodium(II) Carboxylate Catalysts: Enantioselective Synthesis of cis-Cyclopropane α-Amino Acids

Journal of the American Chemical Society, 2009-11, Vol.131 (45), p.16383-16385

2009

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Stereoselective Rh2(S‑IBAZ)4‑Catalyzed Cyclopropanation of Alkenes, Alkynes, and Allenes: Asymmetric Synthesis of Diacceptor Cyclopropylphosphonates and Alkylidenecyclopropanes

Journal of the American Chemical Society, 2013-01, Vol.135 (4), p.1463-1470

2013

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General Synthesis of Cyclopropanols via Organometallic Addition to 1‑Sulfonylcyclopropanols as Cyclopropanone Precursors

Organic letters, 2020-08, Vol.22 (16), p.6510-6515

2020

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Design and Synthesis of Chiral Heteroleptic Rhodium(II) Carboxylate Catalysts: Experimental Investigation of Halogen Bond Rigidification Effects in Asymmetric Cyclopropanation

ACS catalysis, 2012-06, Vol.2 (6), p.1221-1225

2012

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Synthesis of Cycloprodigiosin Identifies the Natural Isolate as a Scalemic Mixture

Organic letters, 2015-07, Vol.17 (14), p.3474-3477

2015

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Expedient synthesis of spiro[3.3]heptan-1-ones via strain-relocating semipinacol rearrangements

Tetrahedron, 2023-03, Vol.134, p.133296, Article 133296

2023

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Application of the Chiral Bis(phosphine) Monoxide Ligand to Catalytic Enantioselective Addition of Dialkylzinc Reagents to β-Nitroalkenes

Organic letters, 2007-01, Vol.9 (1), p.85-87

2007

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Divergent Synthesis of β‑Fluoroamides via Silver-Catalyzed Oxidative Deconstruction of Cyclopropanone Hemiaminals

Organic letters, 2023-07, Vol.25 (28), p.5389-5394

2023

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Use of achiral additives to increase the stereoselectivity in Rh(II)-catalyzed cyclopropanations

Chemical communications (Cambridge, England), 2010-01, Vol.46 (6), p.910-912

2010

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Iron-Catalyzed Oxidative Rearrangement of Cyclopropanone Hemiaminals: General Access to Pyrroloindolones from Indoles

Organic letters, 2024-06, Vol.26 (22), p.4738-4743

2024

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Enantioselective Synthesis of Cyclopropanone Equivalents and Application to the Formation of Chiral β‐Lactams

Angewandte Chemie International Edition, 2020-10, Vol.59 (42), p.18655-18661

International ed. in English, 2020

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Expedient Synthesis of Bis(imidazolium) Dichloride Salts and Bis(NHC) Complexes from Imidazoles Using DMSO as a Key Polar Additive

Organometallics, 2021-12, Vol.40 (23), p.3871-3875

2021

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Expedient Synthesis of Fused Azepine Derivatives Using a Sequential Rhodium(II)-Catalyzed Cyclopropanation/1-Aza-Cope Rearrangement of Dienyltriazoles

Angewandte Chemie, 2014-09, Vol.126 (37), p.10062-10066

2014

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Controlled α-mono- and α,α-di-halogenation of alkyl sulfones using reagent-solvent halogen bonding

Chemical communications (Cambridge, England), 2019-03, Vol.55 (20), p.2912-2915

2019

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Effect of protic additives in Cu-catalysed asymmetric Diels-Alder cycloadditions of doubly activated dienophiles: towards the synthesis of magellanine-type Lycopodium alkaloids

Chemical communications (Cambridge, England), 2017-09, Vol.53 (74), p.10291-10294

2017

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Synthesis of Highly Congested Tertiary Alcohols via the [3,3] Radical Deconstruction of Breslow Intermediates

Organic letters, 2022-06, Vol.24 (23), p.4275-4280

2022

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Catalytic asymmetric synthesis of nitrocyclopropane carboxylates

Tetrahedron, 2012-04, Vol.68 (17), p.3487-3496

2012

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Enantioselective Synthesis of Cyclopropanone Equivalents and Application to the Formation of Chiral β‐Lactams

Angewandte Chemie, 2020-10, Vol.132 (42), p.18814-18820

2020

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Expedient Synthesis of Fused Azepine Derivatives Using a Sequential Rhodium(II)-Catalyzed Cyclopropanation/1-Aza-Cope Rearrangement of Dienyltriazoles

Stereodivergent Intramolecular C(sp3)–H Functionalization of Azavinyl Carbenes: Synthesis of Saturated Heterocycles and Fused N‑Heterotricycles

One-Pot Synthesis of Strain-Release Reagents from Methyl Sulfones

Synthesis of Cyclopentenones with Reverse Pauson–Khand Regiocontrol via Ni-Catalyzed C–C Activation of Cyclopropanone

Benzimidazolyl Palladium Complexes as Highly Active and General Bifunctional Catalysts in Sustainable Cross-Coupling Reactions

Stereospecific Synthesis of Enantioenriched Alkylidenecyclobutanones via Formal Vinylidene Insertion into Cyclopropanone Equivalents

Asymmetric Rh(II)-Catalyzed Cyclopropanation of Alkenes with Diacceptor Diazo Compounds: p-Methoxyphenyl Ketone as a General Stereoselectivity Controlling Group

Experimental Evidence for the All-Up Reactive Conformation of Chiral Rhodium(II) Carboxylate Catalysts: Enantioselective Synthesis of cis-Cyclopropane α-Amino Acids

Stereoselective Rh2(S‑IBAZ)4‑Catalyzed Cyclopropanation of Alkenes, Alkynes, and Allenes: Asymmetric Synthesis of Diacceptor Cyclopropylphosphonates and Alkylidenecyclopropanes

General Synthesis of Cyclopropanols via Organometallic Addition to 1‑Sulfonylcyclopropanols as Cyclopropanone Precursors

Design and Synthesis of Chiral Heteroleptic Rhodium(II) Carboxylate Catalysts: Experimental Investigation of Halogen Bond Rigidification Effects in Asymmetric Cyclopropanation

Synthesis of Cycloprodigiosin Identifies the Natural Isolate as a Scalemic Mixture

Expedient synthesis of spiro[3.3]heptan-1-ones via strain-relocating semipinacol rearrangements

Application of the Chiral Bis(phosphine) Monoxide Ligand to Catalytic Enantioselective Addition of Dialkylzinc Reagents to β-Nitroalkenes

Divergent Synthesis of β‑Fluoroamides via Silver-Catalyzed Oxidative Deconstruction of Cyclopropanone Hemiaminals

Use of achiral additives to increase the stereoselectivity in Rh(II)-catalyzed cyclopropanations

Iron-Catalyzed Oxidative Rearrangement of Cyclopropanone Hemiaminals: General Access to Pyrroloindolones from Indoles

Enantioselective Synthesis of Cyclopropanone Equivalents and Application to the Formation of Chiral β‐Lactams

Expedient Synthesis of Bis(imidazolium) Dichloride Salts and Bis(NHC) Complexes from Imidazoles Using DMSO as a Key Polar Additive

Expedient Synthesis of Fused Azepine Derivatives Using a Sequential Rhodium(II)-Catalyzed Cyclopropanation/1-Aza-Cope Rearrangement of Dienyltriazoles

Controlled α-mono- and α,α-di-halogenation of alkyl sulfones using reagent-solvent halogen bonding

Effect of protic additives in Cu-catalysed asymmetric Diels-Alder cycloadditions of doubly activated dienophiles: towards the synthesis of magellanine-type Lycopodium alkaloids

Synthesis of Highly Congested Tertiary Alcohols via the [3,3] Radical Deconstruction of Breslow Intermediates

Catalytic asymmetric synthesis of nitrocyclopropane carboxylates

Enantioselective Synthesis of Cyclopropanone Equivalents and Application to the Formation of Chiral β‐Lactams

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