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Synthesis of biaryls using aryne intermediates

Chemical Society reviews, 2016-12, Vol.45 (24), p.6766-6798

2016

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Trapping σ-Alkyl-Palladium(II) Intermediates with Arynes Encompassing Intramolecular C−H Activation: Spirobiaryls through Pd-Catalyzed Cascade Reactions

Angewandte Chemie International Edition, 2016-11, Vol.55 (46), p.14389-14393

2016

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Double Heteroatom Functionalization of Arenes Using Benzyne Three-Component Coupling

Angewandte Chemie International Edition, 2015-02, Vol.54 (7), p.2156-2159

International ed. in English, 2015

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Recent Advances on Synthetic Methodology Merging C-H Functionalization and C-C Cleavage

Molecules (Basel, Switzerland), 2020-12, Vol.25 (24), p.5900

2020

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Ruthenium-Catalyzed Cascade CH Functionalization of Phenylacetophenones

Angewandte Chemie International Edition, 2014-02, Vol.53 (6), p.1529-1533

2014

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Synthesis and Reactivity of Model Intermediates Proposed for the Pd-Catalyzed Remote C–H Functionalization of N‑(2-Haloaryl)acrylamides

Organometallics, 2017-11, Vol.36 (22), p.4465-4476

2017

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Exploring the mechanism of the Pd-catalyzed spirocyclization reaction: a combined DFT and experimental study

Chemical science (Cambridge), 2018, Vol.9 (6), p.1496-1509

2018

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Use of 2‑Bromophenylboronic Esters as Benzyne Precursors in the Pd-Catalyzed Synthesis of Triphenylenes

Organic letters, 2014-05, Vol.16 (9), p.2338-2341

2014

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Chasing C,C‐Palladacycles

European journal of inorganic chemistry, 2021-09, Vol.2021 (36), p.3655-3683

2021

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Synthesis of Benzofused O- and N‑Heterocycles through Cascade Carbopalladation/Cross-Alkylation of Alkynes Involving the C–C Cleavage of Cyclobutanols

Organometallics, 2022-03, Vol.41 (5), p.649-658

2022

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Synthesis of [3.4]‐Spirooxindoles through Cascade Carbopalladation of Skipped Dienes

Advanced synthesis & catalysis, 2020-04, Vol.362 (9), p.1899-1904

2020

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Synthesis of Hindered Biaryls via Aryne Addition and in Situ Dimerization

Organic letters, 2015-06, Vol.17 (11), p.2649-2651

2015

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2-Arylacetamides as Versatile Precursors for 3-Aminoisocoumarin and Homophthalimide Derivatives: Palladium-Catalyzed Cascade Double Carbonylation Reactions

Advanced synthesis & catalysis, 2016-08, Vol.358 (16), p.2692-2700

2016

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Synthesis of spiro-oxoindoles through Pd-catalyzed remote C-H alkylation using α-diazocarbonyl compounds

Chemical communications (Cambridge, England), 2017-03, Vol.53 (19), p.2842-2845

2017

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Insertion Reactions on Carbopalladated Benzyne: From Eight- to Nine- and Ten-Membered Palladacycles. Applications to the Synthesis of N‑Heterocycles

Organometallics, 2014-11, Vol.33 (22), p.6420-6430

2014

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Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines

Organometallics, 2010-10, Vol.29 (19), p.4320-4338

2010

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Reactivity toward Neutral N- and P‑Donor Ligands of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C Bond of Orthopalladated Homoveratrylamine and Phentermine. A New Example of the Transphobia Effect

Organometallics, 2014-01, Vol.33 (1), p.33-39

2014

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Pd-catalyzed cascade reactions involving skipped dienes: from double carbopalladation to remote C-C cleavage

Chemical communications (Cambridge, England), 2019-08, Vol.55 (69), p.1281-1284

2019

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Pd-Catalyzed Ring-Opening Polymerization of Cyclobutanols through C(sp3)–C(sp3) Bond Cleavage

Macromolecules, 2024-07, Vol.57 (14), p.6577-6582

2024

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Reactivity toward CO of Eight-Membered Palladacycles Derived from the Insertion of Alkenes into the Pd–C Bond of Cyclopalladated Primary Arylalkylamines of Pharmaceutical Interest. Synthesis of Tetrahydrobenzazocinones, Ortho-Functionalized Phenethylamines, Ureas, and an Isocyanate

Organometallics, 2012-09, Vol.31 (17), p.6351-6364

2012

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Pd-Catalyzed Formal [2 + 2]-Retrocyclization of Cyclobutanols via 2‑Fold Csp3–Csp3 Bond Cleavage

Journal of organic chemistry, 2024-01, Vol.89 (2), p.882-886

2024

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Insertion of Allenes into the Pd–C Bond of Ortho-Palladated Primary Arylamines of Biological Relevance: Phenethylamine, Phentermine, (l)‑Phenylalanine Methyl Ester, and (l)‑Tryptophan Methyl Ester. Synthesis of Tetrahydro-3-benzazepines and Their Salts

Organometallics, 2012-12, Vol.31 (23), p.8333-8347

2012

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Sequential Insertion of Alkynes, Alkenes, and CO into the Pd–C Bond of ortho-Palladated Primary Phenethylamines: from η3‑Allyl Complexes and Enlarged Palladacycles to Functionalized Arylalkylamines

Organometallics, 2021-02, Vol.40 (4), p.539-556

2021

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Fe3O4‐SAHPG‐Pd0 nanoparticles: A ligand‐free and low Pd loading quasiheterogeneous catalyst active for mild Suzuki–Miyaura coupling and CH activation of pyrimidine cores

Applied organometallic chemistry, 2021-01, Vol.35 (1), p.n/a

2021

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A New Method for High-Yield Cyclopalladation of Primary and Secondary Amines. Atom-Efficient Open-to-Air Inexpensive Synthesis of Buchwald-Type Precatalysts

Organometallics, 2011-09, Vol.30 (17), p.4624-4631

2011

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Synthesis of biaryls using aryne intermediates

Trapping σ-Alkyl-Palladium(II) Intermediates with Arynes Encompassing Intramolecular C−H Activation: Spirobiaryls through Pd-Catalyzed Cascade Reactions

Double Heteroatom Functionalization of Arenes Using Benzyne Three-Component Coupling

Recent Advances on Synthetic Methodology Merging C-H Functionalization and C-C Cleavage

Ruthenium-Catalyzed Cascade CH Functionalization of Phenylacetophenones

Synthesis and Reactivity of Model Intermediates Proposed for the Pd-Catalyzed Remote C–H Functionalization of N‑(2-Haloaryl)acrylamides

Exploring the mechanism of the Pd-catalyzed spirocyclization reaction: a combined DFT and experimental study

Use of 2‑Bromophenylboronic Esters as Benzyne Precursors in the Pd-Catalyzed Synthesis of Triphenylenes

Chasing C,C‐Palladacycles

Synthesis of Benzofused O- and N‑Heterocycles through Cascade Carbopalladation/Cross-Alkylation of Alkynes Involving the C–C Cleavage of Cyclobutanols

Synthesis of [3.4]‐Spirooxindoles through Cascade Carbopalladation of Skipped Dienes

Synthesis of Hindered Biaryls via Aryne Addition and in Situ Dimerization

2-Arylacetamides as Versatile Precursors for 3-Aminoisocoumarin and Homophthalimide Derivatives: Palladium-Catalyzed Cascade Double Carbonylation Reactions

Synthesis of spiro-oxoindoles through Pd-catalyzed remote C-H alkylation using α-diazocarbonyl compounds

Insertion Reactions on Carbopalladated Benzyne: From Eight- to Nine- and Ten-Membered Palladacycles. Applications to the Synthesis of N‑Heterocycles

Reactivity toward Neutral N- and P‑Donor Ligands of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C Bond of Orthopalladated Homoveratrylamine and Phentermine. A New Example of the Transphobia Effect

Pd-catalyzed cascade reactions involving skipped dienes: from double carbopalladation to remote C-C cleavage

Pd-Catalyzed Ring-Opening Polymerization of Cyclobutanols through C(sp3)–C(sp3) Bond Cleavage

Reactivity toward CO of Eight-Membered Palladacycles Derived from the Insertion of Alkenes into the Pd–C Bond of Cyclopalladated Primary Arylalkylamines of Pharmaceutical Interest. Synthesis of Tetrahydrobenzazocinones, Ortho-Functionalized Phenethylamines, Ureas, and an Isocyanate

Pd-Catalyzed Formal [2 + 2]-Retrocyclization of Cyclobutanols via 2‑Fold Csp3–Csp3 Bond Cleavage

Insertion of Allenes into the Pd–C Bond of Ortho-Palladated Primary Arylamines of Biological Relevance: Phenethylamine, Phentermine, (l)‑Phenylalanine Methyl Ester, and (l)‑Tryptophan Methyl Ester. Synthesis of Tetrahydro-3-benzazepines and Their Salts

Sequential Insertion of Alkynes, Alkenes, and CO into the Pd–C Bond of ortho-Palladated Primary Phenethylamines: from η3‑Allyl Complexes and Enlarged Palladacycles to Functionalized Arylalkylamines

Fe3O4‐SAHPG‐Pd0 nanoparticles: A ligand‐free and low Pd loading quasiheterogeneous catalyst active for mild Suzuki–Miyaura coupling and CH activation of pyrimidine cores

A New Method for High-Yield Cyclopalladation of Primary and Secondary Amines. Atom-Efficient Open-to-Air Inexpensive Synthesis of Buchwald-Type Precatalysts

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