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Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis

Chemical reviews, 2017-10, Vol.117 (19), p.12564-12580

2017

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Catalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol-Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier

Accounts of chemical research, 2017-09, Vol.50 (9), p.2371-2380

2017

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Feedstock Reagents in Metal‐Catalyzed Carbonyl Reductive Coupling: Minimizing Preactivation for Efficiency in Target‐Oriented Synthesis

Angewandte Chemie (International ed.), 2019-10, Vol.58 (40), p.14055-14064

International ed. in English, 2019

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Alkynes as Electrophilic or Nucleophilic Allylmetal Precursors in Transition‐Metal Catalysis

Angewandte Chemie (International ed.), 2017-09, Vol.56 (38), p.11312-11325

International ed. in English, 2017

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Catalytic Reductive Aldol and Mannich Reactions of Enone, Acrylate, and Vinyl Heteroaromatic Pronucleophiles

Chemical reviews, 2020-04, Vol.120 (8), p.3721-3748

2020

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Enantioselective Formation of All-Carbon Quaternary Centers via C–H Functionalization of Methanol: Iridium-Catalyzed Diene Hydrohydroxymethylation

Journal of the American Chemical Society, 2016-11, Vol.138 (43), p.14210-14213

2016

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Enantioselective Alcohol C–H Functionalization for Polyketide Construction: Unlocking Redox-Economy and Site-Selectivity for Ideal Chemical Synthesis

Journal of the American Chemical Society, 2016-05, Vol.138 (17), p.5467-5478

2016

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Catalytic Enantioselective CH Functionalization of Alcohols by Redox-Triggered Carbonyl Addition: Borrowing Hydrogen, Returning Carbon

Angewandte Chemie (International ed.), 2014-08, Vol.53 (35), p.9142-9150

2014

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Metal-catalyzed reductive coupling of olefin-derived nucleophiles: Reinventing carbonyl addition

Science (American Association for the Advancement of Science), 2016-10, Vol.354 (6310), p.300-300

2016

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Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

Science (American Association for the Advancement of Science), 2012-04, Vol.336 (6079), p.324-327

2012

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Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

Journal of the American Chemical Society, 2012-12, Vol.134 (51), p.20628-20631

2012

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Enantioselective Formation of CF3‑Bearing All-Carbon Quaternary Stereocenters via C–H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation

Journal of the American Chemical Society, 2017-06, Vol.139 (24), p.8114-8117

2017

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Ruthenium-BINAP Catalyzed Alcohol C–H tert-Prenylation via 1,3-Enyne Transfer Hydrogenation: Beyond Stoichiometric Carbanions in Enantioselective Carbonyl Propargylation

Journal of the American Chemical Society, 2016-04, Vol.138 (16), p.5238-5241

2016

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Total Synthesis of Swinholide A: An Exposition in Hydrogen-Mediated C–C Bond Formation

Journal of the American Chemical Society, 2016-11, Vol.138 (43), p.14246-14249

2016

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Enantioselective Allylation, Crotylation, and Reverse Prenylation of Substituted Isatins: Iridium-Catalyzed C----C Bond-Forming Transfer Hydrogenation

Angewandte Chemie (International ed.), 2009-08, Vol.48 (34), p.6313-6316

2009

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Total Synthesis of Bryostatin 7 via C–C Bond-Forming Hydrogenation

Journal of the American Chemical Society, 2011-09, Vol.133 (35), p.13876-13879

2011

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Formation of C–C bonds via ruthenium-catalyzed transfer hydrogenation

Pure and applied chemistry, 2012-01, Vol.84 (8), p.1729-1739

2012

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Enantioselective Total Synthesis of Andrographolide and 14‐Hydroxy‐Colladonin: Carbonyl Reductive Coupling and trans‐Decalin Formation by Hydrogen Transfer

Angewandte Chemie International Edition, 2020-12, Vol.59 (51), p.23169-23173

International ed. in English, 2020

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Ruthenium-Catalyzed Cycloadditions to Form Five‑, Six‑, and Seven-Membered Rings

Chemical reviews, 2021-04, Vol.121 (7), p.4045-4083

2021

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Enantioselective Ruthenium-Catalyzed Carbonyl Allylation via Alkyne–Alcohol C–C Bond-Forming Transfer Hydrogenation: Allene Hydrometalation vs Oxidative Coupling

Journal of the American Chemical Society, 2015-03, Vol.137 (9), p.3161-3164

2015

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Catalyst-Directed Diastereo- and Site-Selectivity in Successive Nucleophilic and Electrophilic Allylations of Chiral 1,3-Diols: Protecting-Group-Free Synthesis of Substituted Pyrans

Chemistry : a European journal, 2014-10, Vol.20 (41), p.13382-13389

2014

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Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents

Angewandte Chemie (International ed.), 2009-01, Vol.48 (1), p.34-46

2009

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Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition

Journal of the American Chemical Society, 2008-11, Vol.130 (44), p.14891-14899

2008

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Oxetane‑, Azetidine‑, and Bicyclopentane-Bearing N‑Heterocycles from Ynones: Scaffold Diversification via Ruthenium-Catalyzed Oxidative Alkynylation

Organic letters, 2023-08, Vol.25 (31), p.5907-5910

2023

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Direct Generation of Acyclic Polypropionate Stereopolyads via Double Diastereo- and Enantioselective Iridium-Catalyzed Crotylation of 1,3-Diols: Beyond Stepwise Carbonyl Addition in Polyketide Construction

Journal of the American Chemical Society, 2011-08, Vol.133 (32), p.12795-12800

2011

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Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis

Catalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol-Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier

Feedstock Reagents in Metal‐Catalyzed Carbonyl Reductive Coupling: Minimizing Preactivation for Efficiency in Target‐Oriented Synthesis

Alkynes as Electrophilic or Nucleophilic Allylmetal Precursors in Transition‐Metal Catalysis

Catalytic Reductive Aldol and Mannich Reactions of Enone, Acrylate, and Vinyl Heteroaromatic Pronucleophiles

Enantioselective Formation of All-Carbon Quaternary Centers via C–H Functionalization of Methanol: Iridium-Catalyzed Diene Hydrohydroxymethylation

Enantioselective Alcohol C–H Functionalization for Polyketide Construction: Unlocking Redox-Economy and Site-Selectivity for Ideal Chemical Synthesis

Catalytic Enantioselective CH Functionalization of Alcohols by Redox-Triggered Carbonyl Addition: Borrowing Hydrogen, Returning Carbon

Metal-catalyzed reductive coupling of olefin-derived nucleophiles: Reinventing carbonyl addition

Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

Enantioselective Formation of CF3‑Bearing All-Carbon Quaternary Stereocenters via C–H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation

Ruthenium-BINAP Catalyzed Alcohol C–H tert-Prenylation via 1,3-Enyne Transfer Hydrogenation: Beyond Stoichiometric Carbanions in Enantioselective Carbonyl Propargylation

Total Synthesis of Swinholide A: An Exposition in Hydrogen-Mediated C–C Bond Formation

Enantioselective Allylation, Crotylation, and Reverse Prenylation of Substituted Isatins: Iridium-Catalyzed C----C Bond-Forming Transfer Hydrogenation

Total Synthesis of Bryostatin 7 via C–C Bond-Forming Hydrogenation

Formation of C–C bonds via ruthenium-catalyzed transfer hydrogenation

Enantioselective Total Synthesis of Andrographolide and 14‐Hydroxy‐Colladonin: Carbonyl Reductive Coupling and trans‐Decalin Formation by Hydrogen Transfer

Ruthenium-Catalyzed Cycloadditions to Form Five‑, Six‑, and Seven-Membered Rings

Enantioselective Ruthenium-Catalyzed Carbonyl Allylation via Alkyne–Alcohol C–C Bond-Forming Transfer Hydrogenation: Allene Hydrometalation vs Oxidative Coupling

Catalyst-Directed Diastereo- and Site-Selectivity in Successive Nucleophilic and Electrophilic Allylations of Chiral 1,3-Diols: Protecting-Group-Free Synthesis of Substituted Pyrans

Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents

Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition

Oxetane‑, Azetidine‑, and Bicyclopentane-Bearing N‑Heterocycles from Ynones: Scaffold Diversification via Ruthenium-Catalyzed Oxidative Alkynylation

Direct Generation of Acyclic Polypropionate Stereopolyads via Double Diastereo- and Enantioselective Iridium-Catalyzed Crotylation of 1,3-Diols: Beyond Stepwise Carbonyl Addition in Polyketide Construction

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