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Engineering electronic structure to prolong relaxation times in molecular qubits by minimising orbital angular momentum

Nature communications, 2019-07, Vol.10 (1), p.3330-8, Article 3330

2019

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Reassessment of N 2 activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N 2 adduct is actually an arene adduct

Chemical science (Cambridge), 2022-11, Vol.13 (45), p.13330-13337

2022

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Organometallic rhenium(III) chalcogenide clusters: coordination of N-heterocyclic carbenes

Chemical communications (Cambridge, England), 2015-07, Vol.51 (52), p.10536-10538

2015

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2.2.2-Cryptand as a bidentate ligand in rare-earth metal chemistry

Inorganic chemistry frontiers, 2020-11, Vol.7 (22), p.4445-4451

2020

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Mechanistic study of pyrazole synthesis via oxidation-induced N-N coupling of diazatitanacycles

Dalton transactions : an international journal of inorganic chemistry, 2024-06, Vol.53 (22), p.9510-9515

2024

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Multicomponent syntheses of 5- and 6-membered aromatic heterocycles using group 4-8 transition metal catalysts

Chemical science (Cambridge), 2021-07, Vol.12 (28), p.9574-959

2021

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Synthesis of Ln(II)-in-Cryptand Complexes by Chemical Reduction of Ln(III)-in-Cryptand Precursors: Isolation of a Nd(II)-in-Cryptand Complex

Angewandte Chemie International Edition, 2020-09

2020

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Isolation of reactive Ln(ii) complexes with C5H4Me ligands (CpMe) using inverse sandwich countercations: synthesis and structure of [(18-crown-6)K(μ-CpMe)K(18-crown-6)][CpMe3LnII] (Ln = Tb, Ho) (Dedicated to Professor Geoffrey Cloke for enlivening organometallic chemistry by his always innovative contributions and for his groundbreaking discoveries using metal vapor chemistry.)

Dalton transactions : an international journal of inorganic chemistry, 2018, Vol.47 (48), p.17285-17290

2018

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Facile Encapsulation of Ln(II) Ions into Cryptate Complexes from LnI2(THF)2 Precursors (Ln = Sm, Eu, Yb)

Inorganic chemistry, 2019-08, Vol.58 (15), p.9613-9617

2019

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Ligand Effects on the Spin Relaxation Dynamics and Coherent Manipulation of Organometallic La(II) Potential Qu d its

Journal of the American Chemical Society, 2024-06, Vol.146 (22), p.15000-15009

2024

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Ligand Effects on the Spin Relaxation Dynamics and Coherent Manipulation of Organometallic La(II) Potential Qudits

Journal of the American Chemical Society, 2024-06, Vol.146 (22), p.15000-15009

2024

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Reassessment of N2 activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N2 adduct is actually an arene adduct

Chemical science (Cambridge), 2022-10, Vol.13 (45), p.13330-13337

2022

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Facile Encapsulation of Ln(II) Ions into Cryptate Complexes from LnI 2 (THF) 2 Precursors (Ln = Sm, Eu, Yb)

Inorganic chemistry, 2019-08, Vol.58 (15), p.9613-9617

2019

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Stabilization of U(III) to Oxidation and Hydrolysis by Encapsulation Using 2.2.2-Cryptand

Inorganic chemistry, 2020-12, Vol.59 (23), p.17077-17083

2020

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High-Resolution X-ray Photoelectron Spectroscopy of Organometallic (C 5 H 4 SiMe 3 ) 3 Ln III and [(C 5 H 4 SiMe 3 ) 3 Ln II ] 1- Complexes (Ln = Sm, Eu, Gd, Tb)

Journal of the American Chemical Society, 2021-10, Vol.143 (40), p.16610-16620

2021

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A Single Small-Scale Plutonium Redox Reaction System Yields Three Crystallographically-Characterizable Organoplutonium Complexes

Inorganic chemistry, 2020-09, Vol.59 (18), p.13301-13314

2020

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Synthesis of uranium-in-cryptand complexes

Chemical communications (Cambridge, England), 2018, Vol.54 (73), p.10272-10275

2018

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Chelate-Free Synthesis of the U(II) Complex, [(C5H3(SiMe3)2)3U]1–, Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs

Inorganic chemistry, 2018-09, Vol.57 (18), p.11809-11814

2018

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Isolation of reactive Ln(ii) complexes with C 5 H 4 Me ligands (Cp Me ) using inverse sandwich countercations: synthesis and structure of [(18-crown-6)K(μ-Cp Me )K(18-crown-6)][Cp Me 3 Ln II ] (Ln = Tb, Ho)

Dalton transactions : an international journal of inorganic chemistry, 2018-12, Vol.47 (48), p.17285-17290

2018

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Synthesis of Ba(II) analogs of Ln(II)-in-(2.2.2-cryptand) and layered hexagonal net Ln(II) complexes, [(THF)Cs(µ–η5:η5–C5H4SiMe3)3LnII]

Polyhedron, 2021-12, Vol.210, p.115493, Article 115493

2021

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Synthesis of LnII‐in‐Cryptand Complexes by Chemical Reduction of LnIII‐in‐Cryptand Precursors: Isolation of a NdII‐in‐Cryptand Complex

Angewandte Chemie International Edition, 2020-09, Vol.59 (37), p.16141-16146

International ed. in English, 2020

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Electronic structure analysis and reactivity of the bimetallic bis-titanocene vinylcarboxylate complex, [(Cp2Ti)2(O2C3TMS2)]

Polyhedron, 2021-10, Vol.207, p.115368, Article 115368

2021

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Utility of Lithium in Rare-Earth Metal Reduction Reactions to Form Nontraditional Ln 2+ Complexes and Unusual [Li(2.2.2-cryptand)] 1+ Cations

Inorganic chemistry, 2018-02, Vol.57 (4), p.2096-2102

2018

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Utility of Lithium in Rare-Earth Metal Reduction Reactions to Form Nontraditional Ln2+ Complexes and Unusual [Li(2.2.2-cryptand)]1+ Cations

Inorganic chemistry, 2018-02, Vol.57 (4), p.2096-2102

2018

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Structural variations in cyclopentadienyl uranium(III) iodide complexes

Journal of coordination chemistry, 2020-12, Vol.74 (1-3), p.74-91

2020

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Engineering electronic structure to prolong relaxation times in molecular qubits by minimising orbital angular momentum

Reassessment of N 2 activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N 2 adduct is actually an arene adduct

Organometallic rhenium(III) chalcogenide clusters: coordination of N-heterocyclic carbenes

2.2.2-Cryptand as a bidentate ligand in rare-earth metal chemistry

Mechanistic study of pyrazole synthesis via oxidation-induced N-N coupling of diazatitanacycles

Multicomponent syntheses of 5- and 6-membered aromatic heterocycles using group 4-8 transition metal catalysts

Synthesis of Ln(II)-in-Cryptand Complexes by Chemical Reduction of Ln(III)-in-Cryptand Precursors: Isolation of a Nd(II)-in-Cryptand Complex

Facile Encapsulation of Ln(II) Ions into Cryptate Complexes from LnI2(THF)2 Precursors (Ln = Sm, Eu, Yb)

Ligand Effects on the Spin Relaxation Dynamics and Coherent Manipulation of Organometallic La(II) Potential Qu d its

Ligand Effects on the Spin Relaxation Dynamics and Coherent Manipulation of Organometallic La(II) Potential Qudits

Reassessment of N2 activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N2 adduct is actually an arene adduct

Facile Encapsulation of Ln(II) Ions into Cryptate Complexes from LnI 2 (THF) 2 Precursors (Ln = Sm, Eu, Yb)

Stabilization of U(III) to Oxidation and Hydrolysis by Encapsulation Using 2.2.2-Cryptand

High-Resolution X-ray Photoelectron Spectroscopy of Organometallic (C 5 H 4 SiMe 3 ) 3 Ln III and [(C 5 H 4 SiMe 3 ) 3 Ln II ] 1- Complexes (Ln = Sm, Eu, Gd, Tb)

A Single Small-Scale Plutonium Redox Reaction System Yields Three Crystallographically-Characterizable Organoplutonium Complexes

Synthesis of uranium-in-cryptand complexes

Chelate-Free Synthesis of the U(II) Complex, [(C5H3(SiMe3)2)3U]1–, Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs

Isolation of reactive Ln(ii) complexes with C 5 H 4 Me ligands (Cp Me ) using inverse sandwich countercations: synthesis and structure of [(18-crown-6)K(μ-Cp Me )K(18-crown-6)][Cp Me 3 Ln II ] (Ln = Tb, Ho)

Synthesis of Ba(II) analogs of Ln(II)-in-(2.2.2-cryptand) and layered hexagonal net Ln(II) complexes, [(THF)Cs(µ–η5:η5–C5H4SiMe3)3LnII]

Synthesis of LnII‐in‐Cryptand Complexes by Chemical Reduction of LnIII‐in‐Cryptand Precursors: Isolation of a NdII‐in‐Cryptand Complex

Electronic structure analysis and reactivity of the bimetallic bis-titanocene vinylcarboxylate complex, [(Cp2Ti)2(O2C3TMS2)]

Utility of Lithium in Rare-Earth Metal Reduction Reactions to Form Nontraditional Ln 2+ Complexes and Unusual [Li(2.2.2-cryptand)] 1+ Cations

Utility of Lithium in Rare-Earth Metal Reduction Reactions to Form Nontraditional Ln2+ Complexes and Unusual [Li(2.2.2-cryptand)]1+ Cations

Structural variations in cyclopentadienyl uranium(III) iodide complexes

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