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Applications of Iridium-Catalyzed Asymmetric Allylic Substitution Reactions in Target-Oriented Synthesis

Accounts of chemical research, 2017-10, Vol.50 (10), p.2539-2555

2017

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Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

Chemical reviews, 2019-02, Vol.119 (3), p.1855-1969

2019

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Enantio- and Regioselective Iridium-Catalyzed Allylic Esterification

Journal of the American Chemical Society, 2014-01, Vol.136 (4), p.1272-1275

2014

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Enantioselective Total Synthesis of (−)-α-Kainic Acid

Organic letters, 2010-03, Vol.12 (5), p.1108-1111

2010

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Enantio- and Regioselective Iridium-Catalyzed Allylic Hydroxylation

Journal of the American Chemical Society, 2011-02, Vol.133 (7), p.2072-2075

2011

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Iridium-Catalyzed Allylic Vinylation and Asymmetric Allylic Amination Reactions with o-Aminostyrenes

Journal of the American Chemical Society, 2011-11, Vol.133 (46), p.19006-19014

2011

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Enantioselective Syntheses of the Alkaloids cis-195A (Pumiliotoxin C) and trans-195A Based on Multiple Applications of Asymmetric Catalysis

Journal of organic chemistry, 2012-01, Vol.77 (2), p.1186-1190

2012

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Mechanistic Aspects of the Crabtree‐Pfaltz Hydrogenation of Olefins ‐ An Interplay of Experimentation and Quantum Chemical Computation

Chemistry : a European journal, 2023-10, Vol.29 (55), p.e202301488-n/a

Helmchen, Günter

2023

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Highly Enantioselective Syntheses of Heterocycles via Intramolecular Ir-Catalyzed Allylic Amination and Etherification

Organic letters, 2005-03, Vol.7 (7), p.1239-1242

2005

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Enantioselective Modular Synthesis of Cyclohexenones: Total Syntheses of (+)-Crypto- and (+)-Infectocaryone

Organic letters, 2010-09, Vol.12 (17), p.3886-3889

2010

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Definition of the term asymmetric synthesis—History and revision

Chirality (New York, N.Y.), 2023-08, Vol.35 (8), p.469-476

Helmchen, Günter

2023

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A Configurational Switch Based on Iridium-Catalyzed Allylic Cyclization: Application in Asymmetric Total Syntheses of Prosopis, Dendrobate, and Spruce Alkaloids

Chemistry : a European journal, 2009-10, Vol.15 (40), p.10514-10532

2009

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Gold-Catalyzed Intermolecular Addition of Carbonyl Compounds to 1,6-Enynes

Angewandte Chemie (International ed.), 2007-01, Vol.46 (29), p.5598-5601

2007

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Ir-Catalysed Asymmetric Allylic Substitutions with Cyclometalated (Phosphoramidite)Ir Complexes-Resting States, Catalytically Active (π-Allyl)Ir Complexes and Computational Exploration

Chemistry : a European journal, 2010-06, Vol.16 (22), p.6601-6615

2010

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Preparation of 2,4-Disubstituted Cyclopentenones by Enantioselective Iridium-Catalyzed Allylic Alkylation: Synthesis of 2′-Methylcarbovir and TEI-9826

Chemistry : a European journal, 2008-07, Vol.14 (22), p.6722-6733

2008

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Enantioselective Iridium-Catalyzed Allylic Substitutions with Hydroxamic Acid Derivatives as N-Nucleophiles

Organic letters, 2011-06, Vol.13 (11), p.2810-2813

2011

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Enantioselective Total Synthesis and Absolute Configuration of Apiosporic Acid

Journal of organic chemistry, 2012-05, Vol.77 (9), p.4491-4495

2012

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50 Jahre Spezifikation der molekularen Chiralität durch Cahn, Ingold und Prelog

Angewandte Chemie, 2016-06, Vol.128 (24), p.6910-6911

Helmchen, Günter

2016

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Stereoselective Synthesis of 2,6-Disubstituted Piperidines Using the Iridium-Catalyzed Allylic Cyclization as Configurational Switch: Asymmetric Total Synthesis of (+)-241 D and Related Piperidine Alkaloids

Chemistry : a European journal, 2009-02, Vol.15 (9), p.2050-2054

2009

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Enantio- and Diastereoselective Syntheses of 3-Hydroxypiperidines through Iridium-Catalyzed Allylic Substitution

European journal of organic chemistry, 2013-08, Vol.2013 (23), p.5149-5159

2013

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The 50th Anniversary of the Cahn-Ingold-Prelog Specification of Molecular Chirality

Angewandte Chemie (International ed.), 2016-06, Vol.55 (24), p.6798-6799

Helmchen, Günter

International ed. in English, 2016

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Gold-Catalyzed Intermolecular Addition of Carbonyl Compounds to 1,6-Enynes: Reactivity, Scope, and Mechanistic Aspects

Chemistry : a European journal, 2009-10, Vol.15 (41), p.10888-10900

2009

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Enantioselective Modular Synthesis of 2,4-Disubstituted Cyclopentenones by Iridium-Catalyzed Allylic Alkylation

Angewandte Chemie (International ed.), 2006-04, Vol.45 (15), p.2466-2469

2006

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Addition of Organometallic Reagents to Chiral N-Methoxylactams: Enantioselective Syntheses of Pyrrolidines and Piperidines

Chemistry : a European journal, 2013-12, Vol.19 (49), p.16746-16755

2013

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Synthesis and Biological Properties of Novel Brefeldin A Analogues

Journal of medicinal chemistry, 2013-07, Vol.56 (14), p.5872-5884

2013

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Applications of Iridium-Catalyzed Asymmetric Allylic Substitution Reactions in Target-Oriented Synthesis

Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

Enantio- and Regioselective Iridium-Catalyzed Allylic Esterification

Enantioselective Total Synthesis of (−)-α-Kainic Acid

Enantio- and Regioselective Iridium-Catalyzed Allylic Hydroxylation

Iridium-Catalyzed Allylic Vinylation and Asymmetric Allylic Amination Reactions with o-Aminostyrenes

Enantioselective Syntheses of the Alkaloids cis-195A (Pumiliotoxin C) and trans-195A Based on Multiple Applications of Asymmetric Catalysis

Mechanistic Aspects of the Crabtree‐Pfaltz Hydrogenation of Olefins ‐ An Interplay of Experimentation and Quantum Chemical Computation

Highly Enantioselective Syntheses of Heterocycles via Intramolecular Ir-Catalyzed Allylic Amination and Etherification

Enantioselective Modular Synthesis of Cyclohexenones: Total Syntheses of (+)-Crypto- and (+)-Infectocaryone

Definition of the term asymmetric synthesis—History and revision

A Configurational Switch Based on Iridium-Catalyzed Allylic Cyclization: Application in Asymmetric Total Syntheses of Prosopis, Dendrobate, and Spruce Alkaloids

Gold-Catalyzed Intermolecular Addition of Carbonyl Compounds to 1,6-Enynes

Ir-Catalysed Asymmetric Allylic Substitutions with Cyclometalated (Phosphoramidite)Ir Complexes-Resting States, Catalytically Active (π-Allyl)Ir Complexes and Computational Exploration

Preparation of 2,4-Disubstituted Cyclopentenones by Enantioselective Iridium-Catalyzed Allylic Alkylation: Synthesis of 2′-Methylcarbovir and TEI-9826

Enantioselective Iridium-Catalyzed Allylic Substitutions with Hydroxamic Acid Derivatives as N-Nucleophiles

Enantioselective Total Synthesis and Absolute Configuration of Apiosporic Acid

50 Jahre Spezifikation der molekularen Chiralität durch Cahn, Ingold und Prelog

Stereoselective Synthesis of 2,6-Disubstituted Piperidines Using the Iridium-Catalyzed Allylic Cyclization as Configurational Switch: Asymmetric Total Synthesis of (+)-241 D and Related Piperidine Alkaloids

Enantio- and Diastereoselective Syntheses of 3-Hydroxypiperidines through Iridium-Catalyzed Allylic Substitution

The 50th Anniversary of the Cahn-Ingold-Prelog Specification of Molecular Chirality

Gold-Catalyzed Intermolecular Addition of Carbonyl Compounds to 1,6-Enynes: Reactivity, Scope, and Mechanistic Aspects

Enantioselective Modular Synthesis of 2,4-Disubstituted Cyclopentenones by Iridium-Catalyzed Allylic Alkylation

Addition of Organometallic Reagents to Chiral N-Methoxylactams: Enantioselective Syntheses of Pyrrolidines and Piperidines

Synthesis and Biological Properties of Novel Brefeldin A Analogues

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