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Chemical glycosylation in the synthesis of glycoconjugate antitumour vaccines

Nature, 2007-04, Vol.446 (7139), p.1000-1007

2007

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Total Synthesis, Relay Synthesis, and Structural Confirmation of the C18-Norditerpenoid Alkaloid Neofinaconitine

Journal of the American Chemical Society, 2013-09, Vol.135 (38), p.14313-14320

2013

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Asymmetric Synthetic Access to the Hetisine Alkaloids: Total Synthesis of (+)-Nominine

Chemistry : a European journal, 2008-01, Vol.14 (5), p.1654-1665

2008

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Efficient Synthetic Access to the Hetisine C20-Diterpenoid Alkaloids. A Concise Synthesis of Nominine via Oxidoisoquinolinium-1,3-Dipolar and Dienamine-Diels−Alder Cycloadditions

Journal of the American Chemical Society, 2006-07, Vol.128 (27), p.8734-8735

2006

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Synthesis and Preclinical Evaluation of QS-21 Variants Leading to Simplified Vaccine Adjuvants and Mechanistic Probes

Journal of the American Chemical Society, 2012-08, Vol.134 (32), p.13448-13457

2012

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Strain-Release Rearrangement of N-Vinyl-2-Arylaziridines. Total Synthesis of the Anti-Leukemia Alkaloid (−)-Deoxyharringtonine

Journal of the American Chemical Society, 2006-08, Vol.128 (32), p.10370-10371

2006

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Design and Synthesis of Potent Quillaja Saponin Vaccine Adjuvants

Journal of the American Chemical Society, 2010-02, Vol.132 (6), p.1939-1945

2010

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Synthetic Studies of Complex Immunostimulants from Quillaja saponaria: Synthesis of the Potent Clinical Immunoadjuvant QS-21Aapi

Journal of the American Chemical Society, 2006-09, Vol.128 (36), p.11906-11915

2006

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Synthesis of QS-21-Xylose: Establishment of the Immunopotentiating Activity of Synthetic QS-21 Adjuvant with a Melanoma Vaccine

Angewandte Chemie (International ed.), 2008-01, Vol.47 (34), p.6395-6398

2008

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Annulation of Thioimidates and Vinyl Carbodiimides to Prepare 2-Aminopyrimidines, Competent Nucleophiles for Intramolecular Alkyne Hydroamination. Synthesis of (−)-Crambidine

Journal of the American Chemical Society, 2010-02, Vol.132 (6), p.1802-1803

2010

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Development of Improved Vaccine Adjuvants Based on the Saponin Natural Product QS-21 through Chemical Synthesis

Accounts of chemical research, 2016-09, Vol.49 (9), p.1741-1756

2016

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Synthesis of Antiproliferative Cephalotaxus Esters and Their Evaluation against Several Human Hematopoietic and Solid Tumor Cell Lines: Uncovering Differential Susceptibilities to Multidrug Resistance

Chemistry : a European journal, 2008-01, Vol.14 (14), p.4293-4306

2008

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Probing the Mechanism of Sulfoxide-Catalyzed Hemiacetal Activation in Dehydrative Glycosylation

Journal of organic chemistry, 2005-07, Vol.70 (15), p.5818-5826

2005

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Synthesis of the Potent Immunostimulatory Adjuvant QS-21A

Journal of the American Chemical Society, 2005-03, Vol.127 (10), p.3256-3257

2005

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C2-Amidoglycosylation. Scope and Mechanism of Nitrogen Transfer

Journal of the American Chemical Society, 2002-08, Vol.124 (33), p.9789-9797

2002

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Aziridine-2-carboxylic Acid-Containing Peptides: Application to Solution- and Solid-Phase Convergent Site-Selective Peptide Modification

Journal of the American Chemical Society, 2005-05, Vol.127 (20), p.7359-7369

2005

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Application of an intramolecular dipolar cycloaddition to an asymmetric synthesis of the fully oxygenated tricyclic core of the stemofoline alkaloids

Tetrahedron, 2008-04, Vol.64 (17), p.3629-3641

2008

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Natural and synthetic saponin adjuvant QS-21 for vaccines against cancer

Expert review of vaccines, 2011-04, Vol.10 (4), p.463-470

2011

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Enantioselective Total Synthesis of Ecteinascidin 743

Journal of the American Chemical Society, 1996-09, Vol.118 (38), p.9202-9203

1996

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Synthesis of the hexacyclic triterpene core of the jujuboside saponins via tandem Wolff rearrangement–intramolecular ketene hetero-Diels–Alder reaction

Tetrahedron, 2018-06, Vol.74 (26), p.3370-3383

2018

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Enantioselective Approach to the Hetisine Alkaloids. Synthesis of the 3-Methyl-1-aza-tricyclo[5.2.1.03,8]decane Core via Intramolecular Dipolar Cycloaddition

Organic letters, 2005-07, Vol.7 (15), p.3323-3325

2005

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Rapid assembly of the doubly-branched pentasaccharide domain of the immunoadjuvant jujuboside A via convergent B(C 6 F 5 ) 3 -catalyzed glycosylation of sterically-hindered precursors

Chemical communications (Cambridge, England), 2017-05, Vol.53 (43), p.5838-5841

2017

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Enantiospecific Synthesis of the Bridged Pyrrolizidine Core of Asparagamine A: Dipolar Cycloadditions of Azomethine Ylides Derived from the Sulfonylation of Vinylogous Amides

Angewandte Chemie (International ed.), 2002-05, Vol.41 (10), p.1778-1780

2002

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Synthesis of Readily Modifiable Cyclodextrin Analogues via Cyclodimerization of an Alkynyl−Azido Trisaccharide

Journal of the American Chemical Society, 2004-02, Vol.126 (6), p.1638-1639

2004

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Development of a minimal saponin vaccine adjuvant based on QS-21

Nature chemistry, 2014-07, Vol.6 (7), p.635

2014

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Chemical glycosylation in the synthesis of glycoconjugate antitumour vaccines

Total Synthesis, Relay Synthesis, and Structural Confirmation of the C18-Norditerpenoid Alkaloid Neofinaconitine

Asymmetric Synthetic Access to the Hetisine Alkaloids: Total Synthesis of (+)-Nominine

Efficient Synthetic Access to the Hetisine C20-Diterpenoid Alkaloids. A Concise Synthesis of Nominine via Oxidoisoquinolinium-1,3-Dipolar and Dienamine-Diels−Alder Cycloadditions

Synthesis and Preclinical Evaluation of QS-21 Variants Leading to Simplified Vaccine Adjuvants and Mechanistic Probes

Strain-Release Rearrangement of N-Vinyl-2-Arylaziridines. Total Synthesis of the Anti-Leukemia Alkaloid (−)-Deoxyharringtonine

Design and Synthesis of Potent Quillaja Saponin Vaccine Adjuvants

Synthetic Studies of Complex Immunostimulants from Quillaja saponaria: Synthesis of the Potent Clinical Immunoadjuvant QS-21Aapi

Synthesis of QS-21-Xylose: Establishment of the Immunopotentiating Activity of Synthetic QS-21 Adjuvant with a Melanoma Vaccine

Annulation of Thioimidates and Vinyl Carbodiimides to Prepare 2-Aminopyrimidines, Competent Nucleophiles for Intramolecular Alkyne Hydroamination. Synthesis of (−)-Crambidine

Development of Improved Vaccine Adjuvants Based on the Saponin Natural Product QS-21 through Chemical Synthesis

Synthesis of Antiproliferative Cephalotaxus Esters and Their Evaluation against Several Human Hematopoietic and Solid Tumor Cell Lines: Uncovering Differential Susceptibilities to Multidrug Resistance

Probing the Mechanism of Sulfoxide-Catalyzed Hemiacetal Activation in Dehydrative Glycosylation

Synthesis of the Potent Immunostimulatory Adjuvant QS-21A

C2-Amidoglycosylation. Scope and Mechanism of Nitrogen Transfer

Aziridine-2-carboxylic Acid-Containing Peptides: Application to Solution- and Solid-Phase Convergent Site-Selective Peptide Modification

Application of an intramolecular dipolar cycloaddition to an asymmetric synthesis of the fully oxygenated tricyclic core of the stemofoline alkaloids

Natural and synthetic saponin adjuvant QS-21 for vaccines against cancer

Enantioselective Total Synthesis of Ecteinascidin 743

Synthesis of the hexacyclic triterpene core of the jujuboside saponins via tandem Wolff rearrangement–intramolecular ketene hetero-Diels–Alder reaction

Enantioselective Approach to the Hetisine Alkaloids. Synthesis of the 3-Methyl-1-aza-tricyclo[5.2.1.03,8]decane Core via Intramolecular Dipolar Cycloaddition

Rapid assembly of the doubly-branched pentasaccharide domain of the immunoadjuvant jujuboside A via convergent B(C 6 F 5 ) 3 -catalyzed glycosylation of sterically-hindered precursors

Enantiospecific Synthesis of the Bridged Pyrrolizidine Core of Asparagamine A: Dipolar Cycloadditions of Azomethine Ylides Derived from the Sulfonylation of Vinylogous Amides

Synthesis of Readily Modifiable Cyclodextrin Analogues via Cyclodimerization of an Alkynyl−Azido Trisaccharide

Development of a minimal saponin vaccine adjuvant based on QS-21

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