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Kinetic UV–Vis Spectroscopic and DFT Mechanistic Study of the Redox Reaction of [OsVIIIO4(OH) n ] n− (n = 1, 2) and Methanol in a Basic Aqueous Matrix

Inorganic chemistry, 2021-01, Vol.60 (2), p.782-797

2021

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New VIVO-complexes for oxidative desulfurization of refractory sulfur compounds in fuel: synthesis, structure, reactivity trend and mechanistic studies

Dalton transactions : an international journal of inorganic chemistry, 2019-01, Vol.48 (44), p.16687-16704

2019

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A robust method for speciation, separation and photometric characterization of all [PtCl 6− n Br n ] 2− ( n = 0–6) and [PtCl 4− n Br n ] 2− ( n = 0–4) complex anions by means of ion-pairing RP-HPLC coupled to ICP-MS/OES, validated by high resolution 195Pt NMR spectroscopy

Analytica chimica acta, 2011-10, Vol.704 (1), p.154-161

2011

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Spectroscopic and DFT Study of Rh III Chloro Complex Transformation in Alkaline Solutions

Inorganic chemistry, 2017-09, Vol.56 (17), p.10724-10734

2017

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A DFT Mechanistic Study of the trans-[OsVIO2(OH)4]2– and [OsVIIIO4(OH) n ] n− (n = 1, 2 cis) Comproportionation Proton-Coupled Electron Transfer Reaction

Inorganic chemistry, 2018-08, Vol.57 (15), p.8909-8922

2018

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New VO-complexes for oxidative desulfurization of refractory sulfur compounds in fuel: synthesis, structure, reactivity trend and mechanistic studies

Dalton transactions : an international journal of inorganic chemistry, 2019-11, Vol.48 (44), p.16687-1674

2019

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A kinetic and thermodynamic study of the unexpected comproportionation reaction between cis-[OsVIIIO4(OH)2]2− and trans-[OsVIO2(OH)4]2− to form a postulated [OsVIIO3(OH)3]2− complex anion

Dalton transactions : an international journal of inorganic chemistry, 2011-01, Vol.40 (34), p.8581-8588

2011

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A DFT study to unravel the ligand exchange kinetics and thermodynamics of Os(VIII) oxo/hydroxido/aqua complexes in aqueous matrices

Dalton transactions : an international journal of inorganic chemistry, 2016-04, Vol.45 (16), p.7028-7041

2016

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Cyclometallated platinum(II) complexes of benzylidene-2,6-di-isopropylphenylamine containing bidentate phosphines: synthesis, structural properties and reactivity studies

Dalton transactions : an international journal of inorganic chemistry, 2015-01, Vol.44 (4), p.1969-1981

2015

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Separation and quantification of [RhCln(H2O)(6-n)](3-n) (n=0-6) complexes, including stereoisomers, by means of ion-pair HPLC-ICP-MS

Talanta (Oxford), 2010-06, Vol.82 (1), p.348-358

2010

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A kinetic and thermodynamic study of the unexpected comproportionation reaction between cis-[Os(VIII)O4(OH)2](2-) and trans-[Os(VI)O2(OH)4](2-) to form a postulated [Os(VII)O3(OH)3](2-) complex anion

Dalton transactions : an international journal of inorganic chemistry, 2011-09, Vol.40 (34), p.8581-8588

2011

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(195)Pt NMR isotopologue and isotopomer distributions of [PtCl(n)(H(2)O)(6 - n)](4 - n) (n = 6,5,4) species as a fingerprint for unambiguous assignment of isotopic stereoisomers

Dalton transactions : an international journal of inorganic chemistry, 2008-08 (31), p.4113-4117

2008

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35Cl/37Cl isotope effects in 103Rh NMR of [RhCln(H2O)6−n]3−n complex anions in hydrochloric acid solution as a unique ‘NMR finger-print’ for unambiguous speciation

Analytica chimica acta, 2012-06, Vol.730, p.93-98

2012

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Configurational isomerism in asymmetrically substituted acylthiourea-based Co(III) complexes; new crystallographic, 59Co NMR, Hirshfeld surface and computational insights

Journal of molecular structure, 2021-11, Vol.1244, p.131009, Article 131009

2021

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Separation and quantification of [RhCl (H2O)6−]3− (n= 0–6) complexes, including stereoisomers, by means of ion-pair HPLC–ICP-MS

Talanta (Oxford), 2010-06, Vol.82 (1), p.348-358

2010

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Separation and quantification of [RhCl n (H 2O) 6− n ] 3− n ( n = 0–6) complexes, including stereoisomers, by means of ion-pair HPLC–ICP-MS

Talanta (Oxford), 2010, Vol.82 (1), p.348-358

2010

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A spectroscopic (stopped-flow UV–Vis and 1H NMR Evans method) and DFT thermodynamic study of the comproportionation reaction of [OsVIIIO4(OH)n]n− (n=1, 2) and [OsVIO2(OH)4]2

Inorganica Chimica Acta, 2017-01, Vol.455, p.140-151

2017

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A spectroscopic (stopped-flow UV–Vis and ^sup 1^H NMR Evans method) and DFT thermodynamic study of the comproportionation reaction of [Os^sup VIII^O^sub 4^(OH)^sub n^]^sup n-^ (n = 1, 2) and [Os^sup VI^O^sub 2^(OH)^sub 4^]^sup 2-

Inorganica Chimica Acta, 2017-01, Vol.455, p.140

2017

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Spectroscopic and DFT Study of RhIII Chloro Complex Transformation in Alkaline Solutions

Inorganic chemistry, 2017-09, Vol.56 (17), p.10724-10734

2017

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New V IV O-complexes for oxidative desulfurization of refractory sulfur compounds in fuel: synthesis, structure, reactivity trend and mechanistic studies

Dalton transactions : an international journal of inorganic chemistry, 2019-11, Vol.48 (44), p.16687-16704

2019

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A DFT study to unravel the ligand exchange kinetics and thermodynamics of OsVIII oxo/hydroxido/aqua complexes in aqueous matricesElectronic supplementary information (ESI) available: Supplementary UV-Vis spectrum, additional computational results and Cartesian coordinates of all optimised structures. See DOI: 10.1039/c6dt00657d

2016-04

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A DFT study to unravel the ligand exchange kinetics and thermodynamics of Os super(VIII) oxo/hydroxido/aqua complexes in aqueous matrices

Dalton transactions : an international journal of inorganic chemistry, 2016-04, Vol.45 (16), p.7028-7041

2016

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A DFT study to unravel the ligand exchange kinetics and thermodynamics of Os VIII oxo/hydroxido/aqua complexes in aqueous matrices

Dalton transactions : an international journal of inorganic chemistry, 2016, Vol.45 (16), p.7028-7041

2016

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35/37Cl and 16/18O isotope resolved 195Pt NMR: unique spectroscopic 'fingerprints' for unambiguous speciation of [PtCln(H2O)6n]4n (n = 2-5) complexes in an acidic aqueous solutionDedicated to Professor David Cole-Hamilton on the occasion of his retirement and for his outstanding contribution to transition metal catalysis.Electronic supplementary information (ESI) available: Four figures (S1-S4) and two tables (S1 and S2). See DOI: 10.1039/c2dt31201h

2012-08

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Cyclometallated platinum(ii) complexes of benzylidene-2,6-di-isopropylphenylamine containing bidentate phosphines: synthesis, structural properties and reactivity studiesElectronic supplementary information (ESI) available: Additional crystallographic data in CIF format and figures for IR spectra, UV spectra, tables for conductivity, UV data etc., as well as tables of structural refinement. Tables giving Cartesian coordinates for the calculated stationary structures obtained from the DFT calcula

2014-12

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Kinetic UV–Vis Spectroscopic and DFT Mechanistic Study of the Redox Reaction of [OsVIIIO4(OH) n ] n− (n = 1, 2) and Methanol in a Basic Aqueous Matrix

New VIVO-complexes for oxidative desulfurization of refractory sulfur compounds in fuel: synthesis, structure, reactivity trend and mechanistic studies

A robust method for speciation, separation and photometric characterization of all [PtCl 6− n Br n ] 2− ( n = 0–6) and [PtCl 4− n Br n ] 2− ( n = 0–4) complex anions by means of ion-pairing RP-HPLC coupled to ICP-MS/OES, validated by high resolution 195Pt NMR spectroscopy

Spectroscopic and DFT Study of Rh III Chloro Complex Transformation in Alkaline Solutions

A DFT Mechanistic Study of the trans-[OsVIO2(OH)4]2– and [OsVIIIO4(OH) n ] n− (n = 1, 2 cis) Comproportionation Proton-Coupled Electron Transfer Reaction

New VO-complexes for oxidative desulfurization of refractory sulfur compounds in fuel: synthesis, structure, reactivity trend and mechanistic studies

A kinetic and thermodynamic study of the unexpected comproportionation reaction between cis-[OsVIIIO4(OH)2]2− and trans-[OsVIO2(OH)4]2− to form a postulated [OsVIIO3(OH)3]2− complex anion

A DFT study to unravel the ligand exchange kinetics and thermodynamics of Os(VIII) oxo/hydroxido/aqua complexes in aqueous matrices

Cyclometallated platinum(II) complexes of benzylidene-2,6-di-isopropylphenylamine containing bidentate phosphines: synthesis, structural properties and reactivity studies

Separation and quantification of [RhCln(H2O)(6-n)](3-n) (n=0-6) complexes, including stereoisomers, by means of ion-pair HPLC-ICP-MS

A kinetic and thermodynamic study of the unexpected comproportionation reaction between cis-[Os(VIII)O4(OH)2](2-) and trans-[Os(VI)O2(OH)4](2-) to form a postulated [Os(VII)O3(OH)3](2-) complex anion

(195)Pt NMR isotopologue and isotopomer distributions of [PtCl(n)(H(2)O)(6 - n)](4 - n) (n = 6,5,4) species as a fingerprint for unambiguous assignment of isotopic stereoisomers

35Cl/37Cl isotope effects in 103Rh NMR of [RhCln(H2O)6−n]3−n complex anions in hydrochloric acid solution as a unique ‘NMR finger-print’ for unambiguous speciation

Configurational isomerism in asymmetrically substituted acylthiourea-based Co(III) complexes; new crystallographic, 59Co NMR, Hirshfeld surface and computational insights

Separation and quantification of [RhCl (H2O)6−]3− (n= 0–6) complexes, including stereoisomers, by means of ion-pair HPLC–ICP-MS

Separation and quantification of [RhCl n (H 2O) 6− n ] 3− n ( n = 0–6) complexes, including stereoisomers, by means of ion-pair HPLC–ICP-MS

A spectroscopic (stopped-flow UV–Vis and 1H NMR Evans method) and DFT thermodynamic study of the comproportionation reaction of [OsVIIIO4(OH)n]n− (n=1, 2) and [OsVIO2(OH)4]2

A spectroscopic (stopped-flow UV–Vis and ^sup 1^H NMR Evans method) and DFT thermodynamic study of the comproportionation reaction of [Os^sup VIII^O^sub 4^(OH)^sub n^]^sup n-^ (n = 1, 2) and [Os^sup VI^O^sub 2^(OH)^sub 4^]^sup 2-

Spectroscopic and DFT Study of RhIII Chloro Complex Transformation in Alkaline Solutions

New V IV O-complexes for oxidative desulfurization of refractory sulfur compounds in fuel: synthesis, structure, reactivity trend and mechanistic studies

A DFT study to unravel the ligand exchange kinetics and thermodynamics of Os super(VIII) oxo/hydroxido/aqua complexes in aqueous matrices

A DFT study to unravel the ligand exchange kinetics and thermodynamics of Os VIII oxo/hydroxido/aqua complexes in aqueous matrices

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