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Anisotropic Thermal Expansion as the Source of Macroscopic and Molecular Scale Motion in Phosphorescent Amphidynamic Crystals

Angewandte Chemie International Edition, 2019-12, Vol.58 (50), p.18003-18010

International ed. in English, 2019

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Molecular Crystals on the Move: From Single-Crystal-to-Single-Crystal Photoreactions to Molecular Machinery

Angewandte Chemie (International ed.), 2007-01, Vol.46 (47), p.8945-8947

Garcia-Garibay, Miguel A

2007

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Correlated motion and mechanical gearing in amphidynamic crystalline molecular machines

Chemical science (Cambridge), 2020-10, Vol.11 (48), p.12994-137

2020

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Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of 1,4-Bis[tri‑(p‑fluorophenyl)phosphane-gold(I)-ethynyl]benzene

Journal of the American Chemical Society, 2017-12, Vol.139 (49), p.18115-18121

2017

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The Roles of Intrinsic Barriers and Crystal Fluidity in Determining the Dynamics of Crystalline Molecular Rotors and Molecular Machines

Journal of organic chemistry, 2019-08, Vol.84 (16), p.9835-9849

2019

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Encapsulating N‑Heterocyclic Carbene Binuclear Transition-Metal Complexes as a New Platform for Molecular Rotation in Crystalline Solid-State

Journal of the American Chemical Society, 2021-01, Vol.143 (2), p.1144-1153

2021

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Crystalline Molecular Machines: Encoding Supramolecular Dynamics into Molecular Structure

Proceedings of the National Academy of Sciences - PNAS, 2005-08, Vol.102 (31), p.10771-10776

2005

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Ultrafast rotation in an amphidynamic crystalline metal organic framework

Proceedings of the National Academy of Sciences - PNAS, 2017-12, Vol.114 (52), p.13613-13618

2017

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Kinetic Control in the Synthesis of a Möbius Tris((ethynyl)[5]helicene) Macrocycle Using Alkyne Metathesis

Journal of the American Chemical Society, 2020-04, Vol.142 (14), p.6493-6498

2020

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Discovery and Total Synthesis of a Bis(cyclotryptamine) Alkaloid Bearing the Elusive Piperidinoindoline Scaffold

Journal of the American Chemical Society, 2020-07, Vol.142 (27), p.11685-11690

2020

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Fluorescence and Rotational Dynamics of a Crystalline Molecular Rotor Featuring an Aggregation-Induced Emission Fluorophore

Journal of organic chemistry, 2019-08, Vol.84 (15), p.9570-9576

2019

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Dynamic Characterization of Crystalline Supramolecular Rotors Assembled through Halogen Bonding

Journal of the American Chemical Society, 2015-12, Vol.137 (49), p.15386-15389

2015

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Phosphine-Mediated Iterative Arene Homologation Using Allenes

Journal of the American Chemical Society, 2015-09, Vol.137 (35), p.11258-11261

2015

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Throwing in a Monkey Wrench to Test and Determine Geared Motion in the Dynamics of a Crystalline One-Dimensional (1D) Columnar Rotor Array

Journal of the American Chemical Society, 2019-02, Vol.141 (6), p.2413-2420

2019

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NMR and X-ray Study Revealing the Rigidity of Zeolitic Imidazolate Frameworks

Journal of physical chemistry. C, 2012-06, Vol.116 (24), p.13307-13312

2012

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Scalable Synthesis of Vicinal Quaternary Stereocenters via the Solid-State Photodecarbonylation of a Crystalline Hexasubstituted Ketone

Organic letters, 2020-11, Vol.22 (22), p.8855-8859

2020

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Rotational Dynamics of Diazabicyclo[2.2.2]octane in Isomorphous Halogen-Bonded Co-crystals: Entropic and Enthalpic Effects

Journal of the American Chemical Society, 2017-01, Vol.139 (2), p.843-848

2017

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Thermally Activated Transient Dipoles and Rotational Dynamics of Hydrogen-Bonded and Charge-Transferred Diazabicyclo [2.2.2]Octane Molecular Rotors

Journal of the American Chemical Society, 2019-10, Vol.141 (42), p.16802-16809

2019

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Amphidynamic Character of Crystalline MOF-5: Rotational Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered Environment

Journal of the American Chemical Society, 2008-03, Vol.130 (11), p.3246-3247

2008

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Rotation of a Bulky Triptycene in the Solid State: Toward Engineered Nanoscale Artificial Molecular Machines

Journal of the American Chemical Society, 2014-06, Vol.136 (25), p.8871-8874

2014

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Crystal Fluidity Reflected by Fast Rotational Motion at the Core, Branches, and Peripheral Aromatic Groups of a Dendrimeric Molecular Rotor

Journal of the American Chemical Society, 2016-04, Vol.138 (13), p.4650-4656

2016

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Enhanced Rotation by Ground State Destabilization in Amphidynamic Crystals of a Dipolar 2,3-Difluorophenylene Rotator as Established by Solid State 2H NMR and Dielectric Spectroscopy

Journal of physical chemistry. C, 2020-07, Vol.124 (28), p.15391-15398

2020

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Transmission Spectroscopy and Kinetics in Crystalline Solids Using Aqueous Nanocrystalline Suspensions: The Spiropyran-Merocyanine Photochromic System

Crystal growth & design, 2017-02, Vol.17 (2), p.637-642

2017

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Options in extracorporeal support of multiple organ failure

Medizinische Klinik, Intensivmedizin und Notfallmedizin, 2020-05, Vol.115 (Suppl 1), p.28-36

2020

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An Unusual Fullerene–Carbene Adduct: Thermal Motion, Disorder, or Both?

Helvetica chimica acta, 2023-02, Vol.106 (2), p.n/a

2023

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Anisotropic Thermal Expansion as the Source of Macroscopic and Molecular Scale Motion in Phosphorescent Amphidynamic Crystals

Molecular Crystals on the Move: From Single-Crystal-to-Single-Crystal Photoreactions to Molecular Machinery

Correlated motion and mechanical gearing in amphidynamic crystalline molecular machines

Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of 1,4-Bis[tri‑(p‑fluorophenyl)phosphane-gold(I)-ethynyl]benzene

The Roles of Intrinsic Barriers and Crystal Fluidity in Determining the Dynamics of Crystalline Molecular Rotors and Molecular Machines

Encapsulating N‑Heterocyclic Carbene Binuclear Transition-Metal Complexes as a New Platform for Molecular Rotation in Crystalline Solid-State

Crystalline Molecular Machines: Encoding Supramolecular Dynamics into Molecular Structure

Ultrafast rotation in an amphidynamic crystalline metal organic framework

Kinetic Control in the Synthesis of a Möbius Tris((ethynyl)[5]helicene) Macrocycle Using Alkyne Metathesis

Discovery and Total Synthesis of a Bis(cyclotryptamine) Alkaloid Bearing the Elusive Piperidinoindoline Scaffold

Fluorescence and Rotational Dynamics of a Crystalline Molecular Rotor Featuring an Aggregation-Induced Emission Fluorophore

Dynamic Characterization of Crystalline Supramolecular Rotors Assembled through Halogen Bonding

Phosphine-Mediated Iterative Arene Homologation Using Allenes

Throwing in a Monkey Wrench to Test and Determine Geared Motion in the Dynamics of a Crystalline One-Dimensional (1D) Columnar Rotor Array

NMR and X-ray Study Revealing the Rigidity of Zeolitic Imidazolate Frameworks

Scalable Synthesis of Vicinal Quaternary Stereocenters via the Solid-State Photodecarbonylation of a Crystalline Hexasubstituted Ketone

Rotational Dynamics of Diazabicyclo[2.2.2]octane in Isomorphous Halogen-Bonded Co-crystals: Entropic and Enthalpic Effects

Thermally Activated Transient Dipoles and Rotational Dynamics of Hydrogen-Bonded and Charge-Transferred Diazabicyclo [2.2.2]Octane Molecular Rotors

Amphidynamic Character of Crystalline MOF-5: Rotational Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered Environment

Rotation of a Bulky Triptycene in the Solid State: Toward Engineered Nanoscale Artificial Molecular Machines

Crystal Fluidity Reflected by Fast Rotational Motion at the Core, Branches, and Peripheral Aromatic Groups of a Dendrimeric Molecular Rotor

Enhanced Rotation by Ground State Destabilization in Amphidynamic Crystals of a Dipolar 2,3-Difluorophenylene Rotator as Established by Solid State 2H NMR and Dielectric Spectroscopy

Transmission Spectroscopy and Kinetics in Crystalline Solids Using Aqueous Nanocrystalline Suspensions: The Spiropyran-Merocyanine Photochromic System

Options in extracorporeal support of multiple organ failure

An Unusual Fullerene–Carbene Adduct: Thermal Motion, Disorder, or Both?

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