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Activation of Pig Liver Esterase in Organic Media with Organic Polymers. Application to the Enantioselective Acylation of Racemic Functionalized Secondary Alcohols

Journal of organic chemistry, 2001-05, Vol.66 (10), p.3384-3396

2001

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(E)-4-Methyl-1-tributylstannyl-oct-1-en-6-yn-3-ol: Circular Dichroism Measurement and Determination of the Absolute Configuration by Quantum-chemical CD Calculations

Zeitschrift für Naturforschung. A, A journal of physical sciences, 2004-03, Vol.59 (3), p.124-132

2004

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Stereochemistry of chiral, nonracemic lithium salts of acyclic .alpha.-sulfonyl carbanions: the asymmetric induction exerted by the lithium-coordinated sulfonyl group

Journal of the American Chemical Society, 1992-05, Vol.114 (11), p.4439-4440

1992

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Enzymatic resolution of analgesics: δ-hydroxytramadol, ε-hydroxytramadol and O-desmethyltramadol

Tetrahedron: asymmetry, 2000-03, Vol.11 (4), p.917-928

2000

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Palladium-Catalyzed Deracemization of Allylic Carbonates in Water with Formation of Allylic Alcohols: Hydrogen Carbonate Ion as Nucleophile in the Palladium-Catalyzed Allylic Substitution and Kinetic Resolution

Journal of the American Chemical Society, 2003-05, Vol.125 (20), p.6066-6067

2003

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Asymmetric Synthesis of Unsaturated, Fused Bicyclic Proline Analogues through Amino Alkylation of Cyclic Bis(allylsulfoximine)titanium Complexes and Migratory Cyclization of δ-Amino Alkenyl Aminosulfoxonium Salts

Journal of the American Chemical Society, 2003-10, Vol.125 (43), p.13243-13251

2003

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Highly Selective Palladium Catalyzed Kinetic Resolution and Enantioselective Substitution of Racemic Allylic Carbonates with Sulfur Nucleophiles: Asymmetric Synthesis of Allylic Sulfides, Allylic Sulfones, and Allylic Alcohols

Chemistry : a European journal, 2003-09, Vol.9 (17), p.4202-4221

2003

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Palladium-catalyzed asymmetric synthesis of allylic alcohols from unsymmetrical and symmetrical racemic allylic carbonates featuring C–O-bond formation and dynamic kinetic resolution

Tetrahedron letters, 2005-09, Vol.46 (37), p.6279-6283

2005

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Nickel-catalyzed cross-couplings of alkenyl and .alpha.-metalated alkenyl sulfoximines with organometallics. Stereoselective synthesis of carbacyclins

Journal of the American Chemical Society, 1989-02, Vol.111 (3), p.1125-1126

1989

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Rearrangement of allylic sulfoximines to allylic sulfinamides

Tetrahedron letters, 1994-10, Vol.35 (40), p.7361-7364

1994

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Asymmetric Synthesis of Fused Bicyclic α-Amino Acids Having a Hexahydro-cyclopenta[c]pyridine Skeleton via Intramolecular Pauson−Khand Reaction of 1-Sulfonimidoyl-Substituted 5-Azaoct-1-en-7-ynes

Journal of organic chemistry, 2003-10, Vol.68 (21), p.8037-8041

2003

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Double metal-catalyzed cross-coupling reactions of alkenyl sulfoximines with diorganozinc reagents: Synthesis of optically active axial chiral allylic silanes

Tetrahedron letters, 1992, Vol.33 (4), p.461-464

1992

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Palladium-Catalyzed Enantioselective Allylic Alkylation of Thiocarboxylate Ions: Asymmetric Synthesis of Allylic Thioesters and Memory Effect/Dynamic Kinetic Resolution of Allylic Esters

Journal of organic chemistry, 2004-06, Vol.69 (12), p.4041-4052

2004

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BINOL-derived N-phosphino sulfoximines as ligands for asymmetric catalysis

Tetrahedron letters, 2005-08, Vol.46 (34), p.5643-5646

2005

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Regioselective and enantioselective substitution of allylic sulfoximines with organocopper reagents. A versatile approach to optically active isocarbacyclins

Journal of the American Chemical Society, 1991-02, Vol.113 (4), p.1442-1444

1991

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Structure of a free, unassociated alkyl-substituted .alpha.-sulfonyl carbanion: isolation and x-ray crystal structure analysis of the inclusive lithium cryptate (Me2CSO2Ph)(Li.cntdot.[2.1.1]cryptand)

Journal of the American Chemical Society, 1991-05, Vol.113 (10), p.4002-4003

1991

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Fully Stereocontrolled Total Syntheses of the Prostacyclin Analogues 16S-Iloprost and 16S-3-Oxa-Iloprost by a Common Route, Using Alkenylcopper-Azoalkene Conjugate Addition, Asymmetric Olefination, and Allylic Alkylation

Journal of the American Chemical Society, 2005-12, Vol.127 (50), p.17910-17920

2005

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On the configuration of open chain α-sulfonyl carbanions: X-ray crystal structure of [(phenylsulfonyl)isopropyllithium-diglyme]2 and [(α-phenylsulfonyl)-α-(methyl)benzyllithium-diglyme]2

Tetrahedron letters, 1988, Vol.29 (11), p.1259-1262

1988

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Palladium(0)-Catalyzed Enantioselective O,S-Rearrangement of Racemic O-Allylic Thiocarbamates: A New Entry to Enantioenriched Allylic Sulfur Compounds

Journal of organic chemistry, 2002-02, Vol.67 (4), p.1153-1161

2002

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Lactonisierung von makrolid-secosäuren mit “push-pull acetylenen”

Tetrahedron letters, 1984, Vol.25 (3), p.273-276

Gais, H.-J

1984

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Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O,Si-Bond Insertion of Chiral Disubstituted β-Silyloxy Alkylidene Carbenes

Journal of the American Chemical Society, 2004-04, Vol.126 (15), p.4859-4864

2004

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X-ray crystal structure analysis of bis[(dimethylisopropoxysilyl)methyl]zinc, a diorganozinc compound with an oxygen-coordinated trigonal-planar zinc atom in the solid state

Journal of the American Chemical Society, 1993-08, Vol.115 (16), p.7215-7218

1993

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Acetylene mit Elektronendonator und Elektronenakzeptorgruppen

Helvetica chimica acta, 1969, Vol.52 (8), p.2641-2657

1969

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Diastereoselective D-galactopyranosyl transfer to meso diols catalyzed by β-galactosidases

Tetrahedron letters, 1988, Vol.29 (45), p.5743-5744

1988

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An efficient resolution of (±)- S-methyl- S-phenylsulfoximine with (+)-10-camphorsulfonic acid by the method of half-quantities

Tetrahedron: asymmetry, 1997-03, Vol.8 (6), p.909-912

1997

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Activation of Pig Liver Esterase in Organic Media with Organic Polymers. Application to the Enantioselective Acylation of Racemic Functionalized Secondary Alcohols

(E)-4-Methyl-1-tributylstannyl-oct-1-en-6-yn-3-ol: Circular Dichroism Measurement and Determination of the Absolute Configuration by Quantum-chemical CD Calculations

Stereochemistry of chiral, nonracemic lithium salts of acyclic .alpha.-sulfonyl carbanions: the asymmetric induction exerted by the lithium-coordinated sulfonyl group

Enzymatic resolution of analgesics: δ-hydroxytramadol, ε-hydroxytramadol and O-desmethyltramadol

Palladium-Catalyzed Deracemization of Allylic Carbonates in Water with Formation of Allylic Alcohols: Hydrogen Carbonate Ion as Nucleophile in the Palladium-Catalyzed Allylic Substitution and Kinetic Resolution

Asymmetric Synthesis of Unsaturated, Fused Bicyclic Proline Analogues through Amino Alkylation of Cyclic Bis(allylsulfoximine)titanium Complexes and Migratory Cyclization of δ-Amino Alkenyl Aminosulfoxonium Salts

Highly Selective Palladium Catalyzed Kinetic Resolution and Enantioselective Substitution of Racemic Allylic Carbonates with Sulfur Nucleophiles: Asymmetric Synthesis of Allylic Sulfides, Allylic Sulfones, and Allylic Alcohols

Palladium-catalyzed asymmetric synthesis of allylic alcohols from unsymmetrical and symmetrical racemic allylic carbonates featuring C–O-bond formation and dynamic kinetic resolution

Nickel-catalyzed cross-couplings of alkenyl and .alpha.-metalated alkenyl sulfoximines with organometallics. Stereoselective synthesis of carbacyclins

Rearrangement of allylic sulfoximines to allylic sulfinamides

Asymmetric Synthesis of Fused Bicyclic α-Amino Acids Having a Hexahydro-cyclopenta[c]pyridine Skeleton via Intramolecular Pauson−Khand Reaction of 1-Sulfonimidoyl-Substituted 5-Azaoct-1-en-7-ynes

Double metal-catalyzed cross-coupling reactions of alkenyl sulfoximines with diorganozinc reagents: Synthesis of optically active axial chiral allylic silanes

Palladium-Catalyzed Enantioselective Allylic Alkylation of Thiocarboxylate Ions: Asymmetric Synthesis of Allylic Thioesters and Memory Effect/Dynamic Kinetic Resolution of Allylic Esters

BINOL-derived N-phosphino sulfoximines as ligands for asymmetric catalysis

Regioselective and enantioselective substitution of allylic sulfoximines with organocopper reagents. A versatile approach to optically active isocarbacyclins

Structure of a free, unassociated alkyl-substituted .alpha.-sulfonyl carbanion: isolation and x-ray crystal structure analysis of the inclusive lithium cryptate (Me2CSO2Ph)(Li.cntdot.[2.1.1]cryptand)

Fully Stereocontrolled Total Syntheses of the Prostacyclin Analogues 16S-Iloprost and 16S-3-Oxa-Iloprost by a Common Route, Using Alkenylcopper-Azoalkene Conjugate Addition, Asymmetric Olefination, and Allylic Alkylation

On the configuration of open chain α-sulfonyl carbanions: X-ray crystal structure of [(phenylsulfonyl)isopropyllithium-diglyme]2 and [(α-phenylsulfonyl)-α-(methyl)benzyllithium-diglyme]2

Palladium(0)-Catalyzed Enantioselective O,S-Rearrangement of Racemic O-Allylic Thiocarbamates: A New Entry to Enantioenriched Allylic Sulfur Compounds

Lactonisierung von makrolid-secosäuren mit “push-pull acetylenen”

Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O,Si-Bond Insertion of Chiral Disubstituted β-Silyloxy Alkylidene Carbenes

X-ray crystal structure analysis of bis[(dimethylisopropoxysilyl)methyl]zinc, a diorganozinc compound with an oxygen-coordinated trigonal-planar zinc atom in the solid state

Acetylene mit Elektronendonator und Elektronenakzeptorgruppen

Diastereoselective D-galactopyranosyl transfer to meso diols catalyzed by β-galactosidases

An efficient resolution of (±)- S-methyl- S-phenylsulfoximine with (+)-10-camphorsulfonic acid by the method of half-quantities

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