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Enantioselection mechanism in Rh-catalyzed asymmetric hydrogenation

Russian chemical bulletin, 2016-06, Vol.65 (6), p.1514-1534

2016

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Formation of Trinuclear Rhodium-Hydride Complexes [{Rh(PP)H}3- (μ2-H)3(μ3-H)][anion]2-During Asymmetric Hydrogenation?

Chemistry : a European journal, 2013-06, Vol.19 (23), p.7443-7451

2013

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Asymmetric Hydrogenation of Enamides with Rh-BisP and Rh-MiniPHOS Catalysts. Scope, Limitations, and Mechanism

Journal of the American Chemical Society, 2001-06, Vol.123 (22), p.5268-5276

2001

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Interconversion of Monohydride Intermediates in Rh(I)-Catalyzed Asymmetric Hydrogenation of Dimethyl 1-Benzoyloxyethenephosphonate

Journal of the American Chemical Society, 2001-05, Vol.123 (19), p.4631-4632

2001

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Highly Enantioselective Hydrogenation of (E)-β-(Acylamino)acrylates Catalyzed by Rh(I)-Complexes of Electron-Rich P-Chirogenic Diphosphines

Organic letters, 2001-05, Vol.3 (11), p.1701-1704

2001

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On the Origin of Opposite Stereoselection in the Asymmetric Hydrogenation of Phenyl- and tert-Butyl-Substituted Enamides

Journal of the American Chemical Society, 2000-10, Vol.122 (42), p.10486-10487

2000

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Investigation of the Dynamic Equilibrium between 2-(Dialkylboryl)-1-methylenecyclobutane and 1-((dialkylboryl)methyl)-1-cyclobutene

Organometallics, 1996-08, Vol.15 (17), p.3696-3702

1996

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On the Mechanism of Stereoselection in Rh-Catalyzed Asymmetric Hydrogenation: A General Approach for Predicting the Sense of Enantioselectivity

Accounts of chemical research, 2004-09, Vol.37 (9), p.633-644

2004

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Synthesis of a new enantiomerically pure P-chiral phosphine and its use in probing the mechanism of the Mitsunobu reaction

Chirality (New York, N.Y.), 2000, Vol.12 (5-6), p.346-351

2000

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Formation of Trinuclear Rhodium-Hydride Complexes [{Rh(PP)H} sub(3)- ( mu sub(2)-H) sub(3)( mu sub(3)-H)][anion] sub(2)-During Asymmetric Hydrogenation?

Chemistry : a European journal, 2013-06, Vol.19 (23), p.7443-7451

2013

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Determination of the free activation energies for the interconversion of isomers of 2,4-pentadienyldipropylborane via consecutive 1,3-boron shifts

Organometallics, 1992-12, Vol.11 (12), p.4056-4061

1992

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Convenient one-pot synthesis of vinylic sulfides from thioalkynes via a catalytic hydroboration-coupling sequence

Journal of organic chemistry, 1993-09, Vol.58 (20), p.5351-5354

1993

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Solution Structure and Reagent Binding of the Zinc Alkoxide Catalyst in the Soai Asymmetric Autocatalytic Reaction

Angewandte Chemie (International ed.), 2004-09, Vol.43 (37), p.4884-4887

2004

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Enantioselective 1,4-Addition of Ar3Bi, [ArBF3]K, and ArSiF3 to Enones Catalyzed by a Dicationic Palladium(II)−Chiraphos or −Dipamp Complex

Organometallics, 2005-10, Vol.24 (21), p.5025-5032

2005

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Mechanism of Asymmetric Hydrogenation Catalyzed by a Rhodium Complex of (S,S)-1,2-Bis(tert-butylmethylphosphino)ethane. Dihydride Mechanism of Asymmetric Hydrogenation

Journal of the American Chemical Society, 2000-08, Vol.122 (30), p.7183-7194

2000

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Catalytic Cyclization of o-Alkynylbenzaldehyde Acetals and Thioacetals. Unprecedented Activation of the Platinum Catalyst by Olefins. Scope and Mechanism of the Reaction

Journal of the American Chemical Society, 2004-12, Vol.126 (47), p.15423-15430

2004

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Determination of the activation parameters of permanent allylic rearrangement in allyl- and methallylboranes and in 1,1-bis(dipropylborylmethyl)ethylene by dynamic NMR spectroscopy

Journal of organometallic chemistry, 1992-02, Vol.424 (2), p.127-132

1992

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Asymmetric Autocatalysis: Novel Structures, Novel Mechanism?

Proceedings of the National Academy of Sciences - PNAS, 2004-04, Vol.101 (16), p.5727-5731

2004

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Asymmetric Hydrogenation of α,β-Unsaturated Phosphonates with Rh-BisP and Rh-MiniPHOS Catalysts: Scope and Mechanism of the Reaction

Proceedings of the National Academy of Sciences - PNAS, 2004-04, Vol.101 (15), p.5385-5390

2004

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Stereospecific syn-acylamidation of olefins

Tetrahedron letters, 1989, Vol.30 (15), p.1987-1990

1989

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Reflections on spontaneous asymmetric synthesis by amplifying autocatalysis

Organic & biomolecular chemistry, 2003-11, Vol.1 (21), p.3811-3819

2003

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Stepwise Delivery of Two Methoxy Groups of Arylaldehyde Acetals across the Phenyl Ring. Vacant Site-Controlled Palladium Catalysis

Journal of the American Chemical Society, 2005-07, Vol.127 (27), p.9844-9847

2005

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P-Chiral Tetraphosphine Dirhodium Complex as a Catalyst for Asymmetric Hydrogenation: Synthesis, Structure, Enantioselectivity, and Mechanism. Stereoselective Formation of a Dirhodium Tetrahydride Complex and Its Reaction with Methyl (Z)-α-Acetamidocinnamate

Organometallics, 2006-02, Vol.25 (4), p.908-914

2006

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Optically Pure 1,2-Bis[(o-alkylphenyl)phenylphosphino]ethanes and Their Use in Rhodium-Catalyzed Asymmetric Hydrogenations of α-(Acylamino)acrylic Derivatives

Advanced synthesis & catalysis, 2004-06, Vol.346 (7), p.777-788

2004

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Synthesis of Pyridinylpyrrole Derivatives via the Palladium-Catalyzed Reaction of Acetylpyridines with Methyleneaziridines

Journal of the American Chemical Society, 2004-11, Vol.126 (43), p.13898-13899

2004

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Enantioselection mechanism in Rh-catalyzed asymmetric hydrogenation

Formation of Trinuclear Rhodium-Hydride Complexes [{Rh(PP)H}3- (μ2-H)3(μ3-H)][anion]2-During Asymmetric Hydrogenation?

Asymmetric Hydrogenation of Enamides with Rh-BisP and Rh-MiniPHOS Catalysts. Scope, Limitations, and Mechanism

Interconversion of Monohydride Intermediates in Rh(I)-Catalyzed Asymmetric Hydrogenation of Dimethyl 1-Benzoyloxyethenephosphonate

Highly Enantioselective Hydrogenation of (E)-β-(Acylamino)acrylates Catalyzed by Rh(I)-Complexes of Electron-Rich P-Chirogenic Diphosphines

On the Origin of Opposite Stereoselection in the Asymmetric Hydrogenation of Phenyl- and tert-Butyl-Substituted Enamides

Investigation of the Dynamic Equilibrium between 2-(Dialkylboryl)-1-methylenecyclobutane and 1-((dialkylboryl)methyl)-1-cyclobutene

On the Mechanism of Stereoselection in Rh-Catalyzed Asymmetric Hydrogenation: A General Approach for Predicting the Sense of Enantioselectivity

Synthesis of a new enantiomerically pure P-chiral phosphine and its use in probing the mechanism of the Mitsunobu reaction

Formation of Trinuclear Rhodium-Hydride Complexes [{Rh(PP)H} sub(3)- ( mu sub(2)-H) sub(3)( mu sub(3)-H)][anion] sub(2)-During Asymmetric Hydrogenation?

Determination of the free activation energies for the interconversion of isomers of 2,4-pentadienyldipropylborane via consecutive 1,3-boron shifts

Convenient one-pot synthesis of vinylic sulfides from thioalkynes via a catalytic hydroboration-coupling sequence

Solution Structure and Reagent Binding of the Zinc Alkoxide Catalyst in the Soai Asymmetric Autocatalytic Reaction

Enantioselective 1,4-Addition of Ar3Bi, [ArBF3]K, and ArSiF3 to Enones Catalyzed by a Dicationic Palladium(II)−Chiraphos or −Dipamp Complex

Mechanism of Asymmetric Hydrogenation Catalyzed by a Rhodium Complex of (S,S)-1,2-Bis(tert-butylmethylphosphino)ethane. Dihydride Mechanism of Asymmetric Hydrogenation

Catalytic Cyclization of o-Alkynylbenzaldehyde Acetals and Thioacetals. Unprecedented Activation of the Platinum Catalyst by Olefins. Scope and Mechanism of the Reaction

Determination of the activation parameters of permanent allylic rearrangement in allyl- and methallylboranes and in 1,1-bis(dipropylborylmethyl)ethylene by dynamic NMR spectroscopy

Asymmetric Autocatalysis: Novel Structures, Novel Mechanism?

Asymmetric Hydrogenation of α,β-Unsaturated Phosphonates with Rh-BisP and Rh-MiniPHOS Catalysts: Scope and Mechanism of the Reaction

Stereospecific syn-acylamidation of olefins

Reflections on spontaneous asymmetric synthesis by amplifying autocatalysis

Stepwise Delivery of Two Methoxy Groups of Arylaldehyde Acetals across the Phenyl Ring. Vacant Site-Controlled Palladium Catalysis

P-Chiral Tetraphosphine Dirhodium Complex as a Catalyst for Asymmetric Hydrogenation: Synthesis, Structure, Enantioselectivity, and Mechanism. Stereoselective Formation of a Dirhodium Tetrahydride Complex and Its Reaction with Methyl (Z)-α-Acetamidocinnamate

Optically Pure 1,2-Bis[(o-alkylphenyl)phenylphosphino]ethanes and Their Use in Rhodium-Catalyzed Asymmetric Hydrogenations of α-(Acylamino)acrylic Derivatives

Synthesis of Pyridinylpyrrole Derivatives via the Palladium-Catalyzed Reaction of Acetylpyridines with Methyleneaziridines

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