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Tetrazine Ligation: Fast Bioconjugation Based on Inverse-Electron-Demand Diels−Alder Reactivity

Journal of the American Chemical Society, 2008-10, Vol.130 (41), p.13518-13519

2008

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A Mixed-Ligand Chiral Rhodium(II) Catalyst Enables the Enantioselective Total Synthesis of Piperarborenine B

Angewandte Chemie (International ed.), 2016-04, Vol.55 (16), p.4983-4987

2016

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Genetic Encoding of Bicyclononynes and trans-Cyclooctenes for Site-Specific Protein Labeling in Vitro and in Live Mammalian Cells via Rapid Fluorogenic Diels–Alder Reactions

Journal of the American Chemical Society, 2012-06, Vol.134 (25), p.10317-10320

2012

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Design and Synthesis of Highly Reactive Dienophiles for the Tetrazine–trans-Cyclooctene Ligation

Journal of the American Chemical Society, 2011-06, Vol.133 (25), p.9646-9649

2011

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Thiomethyltetrazines Are Reversible Covalent Cysteine Warheads Whose Dynamic Behavior can be “Switched Off” via Bioorthogonal Chemistry Inside Live Cells

Journal of the American Chemical Society, 2023-07, Vol.145 (29), p.16069-16080

2023

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Rhodium(II)-Catalyzed Enantioselective C−H Functionalization of Indoles

Journal of the American Chemical Society, 2011-02, Vol.133 (6), p.1650-1653

2011

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Enabling In Vivo Photocatalytic Activation of Rapid Bioorthogonal Chemistry by Repurposing Silicon-Rhodamine Fluorophores as Cytocompatible Far-Red Photocatalysts

Journal of the American Chemical Society, 2021-07, Vol.143 (28), p.10793-10803

2021

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Divergent Synthesis of Monosubstituted and Unsymmetrical 3,6‐Disubstituted Tetrazines from Carboxylic Ester Precursors

Angewandte Chemie International Edition, 2020-09, Vol.59 (39), p.16967-16973

International ed. in English, 2020

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Rapid Bioorthogonal Chemistry Turn-on through Enzymatic or Long Wavelength Photocatalytic Activation of Tetrazine Ligation

Journal of the American Chemical Society, 2016-05, Vol.138 (18), p.5978-5983

2016

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Diels–Alder Cycloaddition for Fluorophore Targeting to Specific Proteins inside Living Cells

Journal of the American Chemical Society, 2012-01, Vol.134 (2), p.792-795

2012

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Dual-Reactivity trans-Cyclooctenol Probes for Sulfenylation in Live Cells Enable Temporal Control via Bioorthogonal Quenching

Journal of the American Chemical Society, 2019-07, Vol.141 (28), p.10932-10937

2019

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Enantioselective Synthesis of Cyclobutanes via Sequential Rh-catalyzed Bicyclobutanation/Cu-catalyzed Homoconjugate Addition

Journal of the American Chemical Society, 2013-06, Vol.135 (25), p.9283-9286

2013

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Rh-Catalyzed Intermolecular Reactions of α‑Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β‑Hydride Migration

Accounts of chemical research, 2016-01, Vol.49 (1), p.115-127

2016

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Modeling the Maturation of the Vocal Fold Lamina Propria Using a Bioorthogonally Tunable Hydrogel Platform

Advanced healthcare materials, 2023-11, Vol.12 (29), p.e2301701-e2301701

2023

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A Photochemical Synthesis of Functionalized trans-Cyclooctenes Driven by Metal Complexation

Journal of the American Chemical Society, 2008-03, Vol.130 (12), p.3760-3761

2008

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trans-Cyclooctene—a stable, voracious dienophile for bioorthogonal labeling

Current opinion in chemical biology, 2013-10, Vol.17 (5), p.753-760

2013

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Unusually Reactive and Selective Carbonyl Ylides for Three-Component Cycloaddition Reactions

Journal of the American Chemical Society, 2009-01, Vol.131 (3), p.1101-1105

2009

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Directed Carbozincation Reactions of Cyclopropene Derivatives

Journal of the American Chemical Society, 2009-04, Vol.131 (15), p.5382-5383

2009

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Facially Selective Cu-Catalyzed Carbozincation of Cyclopropenes Using Arylzinc Reagents Formed by Sequential I/Mg/Zn Exchange

Journal of organic chemistry, 2012-11, Vol.77 (21), p.9900-9904

2012

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Enantioselective, Facially Selective Carbomagnesation of Cyclopropenes

Journal of the American Chemical Society, 2006-05, Vol.128 (17), p.5600-5601

2006

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Synthesis of Benzodihydrofurans by Asymmetric C−H Insertion Reactions of Donor/Donor Rhodium Carbenes

Chemistry : a European journal, 2017-09, Vol.23 (49), p.11843-11855

2017

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Enantioselective Synthesis of (−)-Pentalenene

Organic letters, 2007-12, Vol.9 (26), p.5625-5628

2007

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The chiral crown conformation in paddlewheel complexes

Chemical communications (Cambridge, England), 2010-07, Vol.46 (25), p.4541-4543

2010

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Stereospecific Synthesis of Alkylidenecyclopropanes via Sequential Cyclopropene Carbomagnesation/1,3-Carbon Shift

Journal of organic chemistry, 2010-06, Vol.75 (11), p.3847-3850

2010

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Facially Selective and Regioselective Carbometalation of Cyclopropenes by Aryl Grignard Reagents

Journal of organic chemistry, 2008-01, Vol.73 (2), p.563-568

2008

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Tetrazine Ligation: Fast Bioconjugation Based on Inverse-Electron-Demand Diels−Alder Reactivity

A Mixed-Ligand Chiral Rhodium(II) Catalyst Enables the Enantioselective Total Synthesis of Piperarborenine B

Genetic Encoding of Bicyclononynes and trans-Cyclooctenes for Site-Specific Protein Labeling in Vitro and in Live Mammalian Cells via Rapid Fluorogenic Diels–Alder Reactions

Design and Synthesis of Highly Reactive Dienophiles for the Tetrazine–trans-Cyclooctene Ligation

Thiomethyltetrazines Are Reversible Covalent Cysteine Warheads Whose Dynamic Behavior can be “Switched Off” via Bioorthogonal Chemistry Inside Live Cells

Rhodium(II)-Catalyzed Enantioselective C−H Functionalization of Indoles

Enabling In Vivo Photocatalytic Activation of Rapid Bioorthogonal Chemistry by Repurposing Silicon-Rhodamine Fluorophores as Cytocompatible Far-Red Photocatalysts

Divergent Synthesis of Monosubstituted and Unsymmetrical 3,6‐Disubstituted Tetrazines from Carboxylic Ester Precursors

Rapid Bioorthogonal Chemistry Turn-on through Enzymatic or Long Wavelength Photocatalytic Activation of Tetrazine Ligation

Diels–Alder Cycloaddition for Fluorophore Targeting to Specific Proteins inside Living Cells

Dual-Reactivity trans-Cyclooctenol Probes for Sulfenylation in Live Cells Enable Temporal Control via Bioorthogonal Quenching

Enantioselective Synthesis of Cyclobutanes via Sequential Rh-catalyzed Bicyclobutanation/Cu-catalyzed Homoconjugate Addition

Rh-Catalyzed Intermolecular Reactions of α‑Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β‑Hydride Migration

Modeling the Maturation of the Vocal Fold Lamina Propria Using a Bioorthogonally Tunable Hydrogel Platform

A Photochemical Synthesis of Functionalized trans-Cyclooctenes Driven by Metal Complexation

trans-Cyclooctene—a stable, voracious dienophile for bioorthogonal labeling

Unusually Reactive and Selective Carbonyl Ylides for Three-Component Cycloaddition Reactions

Directed Carbozincation Reactions of Cyclopropene Derivatives

Facially Selective Cu-Catalyzed Carbozincation of Cyclopropenes Using Arylzinc Reagents Formed by Sequential I/Mg/Zn Exchange

Enantioselective, Facially Selective Carbomagnesation of Cyclopropenes

Synthesis of Benzodihydrofurans by Asymmetric C−H Insertion Reactions of Donor/Donor Rhodium Carbenes

Enantioselective Synthesis of (−)-Pentalenene

The chiral crown conformation in paddlewheel complexes

Stereospecific Synthesis of Alkylidenecyclopropanes via Sequential Cyclopropene Carbomagnesation/1,3-Carbon Shift

Facially Selective and Regioselective Carbometalation of Cyclopropenes by Aryl Grignard Reagents

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