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Preparation of [(1,4,7-Trimethyl-1,4,7-triazacyclononane)Rh(PR3)(H)(CH3)]+ and Its Carbon-Hydrogen Reductive-Elimination and Oxidative-Addition Chemistry

Journal of the American Chemical Society, 1995-02, Vol.117 (5), p.1647-1648

1995

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Coordination polymerization of ethylene by single-component rhodium catalysts in protic solvents

Journal of the American Chemical Society, 1993-07, Vol.115 (15), p.6999-7000

1993

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Preparations of (1,4,7-Trimethyl-1,4,7-triazacyclononane)RhMe3, Some of Its Rh−C Acid-Cleavage Derivatives, and (1,4,7-Trineohexyl-1,4,7-triazacyclononane)RhMe3

Organometallics, 1996-01, Vol.15 (2), p.491-498

1996

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Deuterium Migration in {(1,4,7-Triazacyclononane)Rh(alkyl)D[P(OMe)3]}+. Evidence for Mobility of Rhodium along Linear Alkane Chains in Inferred Rhodium−Alkane Complexes

Journal of the American Chemical Society, 2000-07, Vol.122 (28), p.6783-6784

2000

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Synthesis and Characterization of Triazacyclononane-Ligated Iridium Dihydride Complexes

Organometallics, 2003-12, Vol.22 (25), p.5370-5373

2003

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Mechanism of activation of carbon-hydrogen bonds in tetramethylsilane and mesitylene and mechanism of intramolecular activation in trimethylphosphine on thermolysis of tetrakis(trimethylphosphine)hydridoneopentylosmium(II)

Journal of the American Chemical Society, 1990, Vol.112 (2), p.704-713

1990

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Reactions of (Trimethyltriazacyclononane)Rh(vinyl)3, −Rh(Z-propenyl)3, and −Rh(vinyl)2Me with Protic Acids. The Relative Migratory Aptitude of Methyl and Vinyl Groups to an (Ethylidene)Rh Alkylidene Carbon

Organometallics, 1998-11, Vol.17 (24), p.5397-5405

1998

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Phosphine Ligand Exchange in Tetrakis(trimethylphosphine)(hydrido)osmium Anilides, Phenoxides, and Thiophenoxides. Examples of Anion Dissociation and of Labilization by Ligand π-Base Effects

Organometallics, 2000-03, Vol.19 (6), p.1166-1174

2000

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Ethylene insertion into the rhodium-methyl bond in chelated tris(tertiary amine) complexes. A new class of Group 9 organometallic complexes

Journal of the American Chemical Society, 1992-04, Vol.114 (8), p.3169-3170

1992

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Synthesis, characterization, and rearrangements of [(1-methylcyclobutyl)methyl]platinum(II) complexes. Very mild ring-strain-induced carbon-carbon activation

Organometallics, 1984-12, Vol.3 (12), p.1795-1803

1984

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Generation of Coordinative Unsaturation at Osmium via Ring-Opening Equilibration of a 2-Pyridonato Chelate Complex

Organometallics, 2000-06, Vol.19 (12), p.2310-2317

2000

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Stereochemistry at manganese of the carbon monoxide insertion in pentacarbonylmethylmanganese(I). The geometry of the intermediate

Journal of the American Chemical Society, 1981-07, Vol.103 (15), p.4410-4414

1981

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Stereochemistry at Carbon of the Cyclometalation of 8-(α-Deuterioethyl)quinoline by Palladium(II) Salts

Organometallics, 1996-10, Vol.15 (20), p.4228-4234

1996

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Preparation of (1,4,7-triazacyclononane)Rh(hydrocarbyl)3 Compounds and Their Derivatives. Strong Donor Labilization of RhCl Bonds toward Alkylation and Preparation of Unusually Stable Alkyl Hydride Complexes of Rhodium

Organometallics, 1997-02, Vol.16 (3), p.434-441

1997

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XPS Investigations of (1,4,7-trimethyl-1,4,7-triazacyclononane)RhMe3 and [1,1,1-tris((dimethylphosphino)methyl)ethane]RhMe3 and Their Rh−C Cleavage Derivatives. Comparison of Hard- and Soft-Ligated Rhodium Organometallics

Organometallics, 1996-10, Vol.15 (20), p.4240-4246

1996

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Kinetics and conformation in the reversible insertion of an alkene into a platinum-carbon bond in a chelated (pentenyl)platinum complex

Organometallics, 1993-07, Vol.12 (7), p.2634-2643

1993

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Activation of methane by the reactive intermediate tris(trimethylphosphine)osmium(0)

Journal of the American Chemical Society, 1988-11, Vol.110 (23), p.7915-7916

1988

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Reversible formal alkene insertion into a chelated platinum-alkyl bond

Journal of the American Chemical Society, 1984-10, Vol.106 (20), p.6076-6077

1984

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Intra- and intermolecular activation of carbon-hydrogen bonds in a tetrakis(trimethylphosphine)osmium(II) system

Journal of the American Chemical Society, 1986-03, Vol.108 (6), p.1346-1347

1986

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Stereochemical lability of (CO)3Fe(.mu.-ER2)2Fe(CO)2PR3. Evidence for two distinct carbonyl averaging processes without bridge opening

Inorganic chemistry, 1978-06, Vol.17 (6), p.1643-1646

1978

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Activation of benzene by a tetrakis(trimethylphosphine)osmium(II) system. Mechanism of activation

Journal of the American Chemical Society, 1986-12, Vol.108 (25), p.7964-7970

1986

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Spectroscopic characterization of an electrophilic transition-metal-methylene complex, .eta.5-C5H5[(C6H5)2PCH2CH2P(C6H5)2]Fe:CH2

Journal of the American Chemical Society, 1980-01, Vol.102 (3), p.1203-1205

1980

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Mechanism of cyclometalation of tris(trimethylphosphine)(neopentyl)iridium(I)

Organometallics, 1990-09, Vol.9 (9), p.2523-2528

1990

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Oxidation of [(cyclic triamine)(1,5-cyclooctadiene)iridium]+ cations by hydrogen peroxide forms metallaoxetanes

Chemical communications (Cambridge, England), 2000-01 (17), p.1681-1682

2000

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Preparation of [(1,4,7-Trimethyl-1,4,7-triazacyclononane)Rh(PR3)(H)(CH3)]+ and Its Carbon-Hydrogen Reductive-Elimination and Oxidative-Addition Chemistry

Coordination polymerization of ethylene by single-component rhodium catalysts in protic solvents

Preparations of (1,4,7-Trimethyl-1,4,7-triazacyclononane)RhMe3, Some of Its Rh−C Acid-Cleavage Derivatives, and (1,4,7-Trineohexyl-1,4,7-triazacyclononane)RhMe3

Deuterium Migration in {(1,4,7-Triazacyclononane)Rh(alkyl)D[P(OMe)3]}+. Evidence for Mobility of Rhodium along Linear Alkane Chains in Inferred Rhodium−Alkane Complexes

Synthesis and Characterization of Triazacyclononane-Ligated Iridium Dihydride Complexes

Mechanism of activation of carbon-hydrogen bonds in tetramethylsilane and mesitylene and mechanism of intramolecular activation in trimethylphosphine on thermolysis of tetrakis(trimethylphosphine)hydridoneopentylosmium(II)

Reactions of (Trimethyltriazacyclononane)Rh(vinyl)3, −Rh(Z-propenyl)3, and −Rh(vinyl)2Me with Protic Acids. The Relative Migratory Aptitude of Methyl and Vinyl Groups to an (Ethylidene)Rh Alkylidene Carbon

Phosphine Ligand Exchange in Tetrakis(trimethylphosphine)(hydrido)osmium Anilides, Phenoxides, and Thiophenoxides. Examples of Anion Dissociation and of Labilization by Ligand π-Base Effects

Ethylene insertion into the rhodium-methyl bond in chelated tris(tertiary amine) complexes. A new class of Group 9 organometallic complexes

Synthesis, characterization, and rearrangements of [(1-methylcyclobutyl)methyl]platinum(II) complexes. Very mild ring-strain-induced carbon-carbon activation

Generation of Coordinative Unsaturation at Osmium via Ring-Opening Equilibration of a 2-Pyridonato Chelate Complex

Stereochemistry at manganese of the carbon monoxide insertion in pentacarbonylmethylmanganese(I). The geometry of the intermediate

Stereochemistry at Carbon of the Cyclometalation of 8-(α-Deuterioethyl)quinoline by Palladium(II) Salts

Preparation of (1,4,7-triazacyclononane)Rh(hydrocarbyl)3 Compounds and Their Derivatives. Strong Donor Labilization of RhCl Bonds toward Alkylation and Preparation of Unusually Stable Alkyl Hydride Complexes of Rhodium

XPS Investigations of (1,4,7-trimethyl-1,4,7-triazacyclononane)RhMe3 and [1,1,1-tris((dimethylphosphino)methyl)ethane]RhMe3 and Their Rh−C Cleavage Derivatives. Comparison of Hard- and Soft-Ligated Rhodium Organometallics

Kinetics and conformation in the reversible insertion of an alkene into a platinum-carbon bond in a chelated (pentenyl)platinum complex

Activation of methane by the reactive intermediate tris(trimethylphosphine)osmium(0)

Reversible formal alkene insertion into a chelated platinum-alkyl bond

Intra- and intermolecular activation of carbon-hydrogen bonds in a tetrakis(trimethylphosphine)osmium(II) system

Stereochemical lability of (CO)3Fe(.mu.-ER2)2Fe(CO)2PR3. Evidence for two distinct carbonyl averaging processes without bridge opening

Activation of benzene by a tetrakis(trimethylphosphine)osmium(II) system. Mechanism of activation

Spectroscopic characterization of an electrophilic transition-metal-methylene complex, .eta.5-C5H5[(C6H5)2PCH2CH2P(C6H5)2]Fe:CH2

Mechanism of cyclometalation of tris(trimethylphosphine)(neopentyl)iridium(I)

Oxidation of [(cyclic triamine)(1,5-cyclooctadiene)iridium]+ cations by hydrogen peroxide forms metallaoxetanes

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