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A review of modern transition-metal nanoclusters: their synthesis, characterization, and applications in catalysis

Journal of Molecular Catalysis. A, Chemical, 1999-09, Vol.145 (1), p.1-44

1999

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A review of soluble transition-metal nanoclusters as arene hydrogenation catalysts

Journal of Molecular Catalysis. A, Chemical, 2003-01, Vol.191 (2), p.187-207

2003

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The story of a mechanism-based solution to an irreproducible synthesis resulting in an unexpected closed-system requirement for the LiBEt3H-based reduction: The case of the novel subnanometer cluster, [Ir(1,5-COD)(μ-H)]4, and the resulting improved, independently repeatable, reliable synthesis

Inorganica Chimica Acta, 2015-06, Vol.432 (C), p.250-257

2015

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Polyoxoanion-supported catalysis: evidence for a P2W15Nb3O629- -supported iridium cyclohexene oxidation catalyst starting from [n-Bu4N]5Na3[(1,5-COD)Ir-P2W15Nb3O62]

Journal of molecular catalysis. A, Chemical, 2003, Vol.191 (2), p.253-279

2003

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Vanadium-Based, Extended Catalytic Lifetime Catechol Dioxygenases: Evidence for a Common Catalyst

Journal of the American Chemical Society, 2005-06, Vol.127 (25), p.9003-9013

2005

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The First Experimental Test of the Hypothesis that Enzymes Have Evolved To Enhance Hydrogen Tunneling

Journal of the American Chemical Society, 2003-09, Vol.125 (36), p.10877-10884

2003

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Polyoxoanion- and tetrabutylammonium-stabilized Rh(o){sub n} nanoclusters: Unprecedented nanocluster catalytic lifetime in solution

Journal of the American Chemical Society, 1999-09, Vol.121 (38)

1999

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Kinetic and Mechanistic Studies of Vanadium-Based, Extended Catalytic Lifetime Catechol Dioxygenases

Journal of the American Chemical Society, 2005-10, Vol.127 (40), p.13988-13996

2005

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Polyoxoanion- and Tetrabutylammonium-Stabilized, Near-Monodisperse, 40 ± 6 Å Rh(0)∼ 1500 to Rh(0)∼ 3700 Nanoclusters: Synthesis, Characterization, and Hydrogenation Catalysis

Chemistry of materials, 1999-04, Vol.11 (4), p.1035-1047

1999

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Polyoxoanion-supported catalysis: evidence for a P 2W 15Nb 3O 629−-supported iridium cyclohexene oxidation catalyst starting from [ n-Bu 4N] 5Na 3[(1,5-COD)Ir·P 2W 15Nb 3O 62]

Journal of molecular catalysis. A, Chemical, 2003, Vol.191 (2), p.253-279

2003

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Characterization of large, polyanionic inorganic molecules: Fast atom bombardment mass spectrometry of P[sub 2]W[sub 15]Nb[sub 3]O[sub 62][sup 9[minus]] and of the supported organometallic catalyst precursor (1,5-COD)Ir[center dot]P[sub 2]W[sub 15]Nb[sub 3]O[sub 62][sup 8[minus]]

Inorganic chemistry, 1993-12, Vol.32:26

1993

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The polyoxoanion-supported, atomically dispersed transition-metal precatalyst [(1,5-COD)Ir[times]P[sub 2]W[sub 15]Nb[sub 3]O[sub 62]][sup 8[minus]]: Direct [sup 17]O NMR evidence for Ir-ONb[sub 2] bonding and for a C[sub 3] average symmetry, iridium-to-polyoxoanion support

Organometallics, 1993-04, Vol.12:4

1993

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Radical cage effects in coenzyme B12: Radical trapping, product and kinetic studies

Journal of inorganic biochemistry, 1993-07, Vol.51 (1-2), p.221-221

1993

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Polyoxoanions as soluble metal oxide analogues. 6. Catalytic activity and initial kinetic and mechanistic studies of polyoxoanion-supported, atomically dispersed iridium(I), (1,5-COD)Ir times P sub 2 W sub 15 Nb sub 3 O sub 62 sup 8 minus

Inorganic chemistry, 1990-05, Vol.29:10

1990

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Coenzyme B12 model compounds: A quantitative electrochemical comparison

Journal of organometallic chemistry, 1980-12, Vol.202 (1), p.C25-C30

1980

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Polyoxoanions as soluble metal oxide analogs. Synthesis and characterization of the polyoxoanion-supported iridium(I) complex (1,5-COD)Ir[center dot]SiW[sub 9]Nb[sub 3]O[sub 40][sup 6[minus]]

Inorganic chemistry, 1993-12, Vol.32:26

1993

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Oxidation resistant inorganic-porphyrin analog polyoxometalates. 3. The synthesis and X-ray crystallographic characterization of a new heteropolyoxoanion structural type, the diruthenium-oxo-bridged bimetallic inorganic-porphyrin analog' KLi[sub 15][O[l brace]Ru[sup IV]Cl([alpha][sub 2]-P[sub 2]W[sub 17]O[sub 61])[r brace][sub 2]][center dot]2KCl[center dot]60H[sub 2]O

Inorganic chemistry, 1993-03, Vol.32:7

1993

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Polyoxoanions derived from A-[beta]-SiW[sub 9]O[sub 34][sup 10[minus]]: Synthesis, single-crystal structural determination, and solution structural characterization by [sup 183]W NMR and IR of A-[beta]-Si[sub 2]W[sub 18]Ti[sub 6]O[sub 77][sup 14[minus]]

Inorganic chemistry, 1993-11, Vol.32:23

1993

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Polyoxoanion-supported, atomically dispersed transition metals: The catalytic oxidation of cyclohexene with dioxygen by the catalyst precursors ((n-C sub 4 H sub 9 ) sub 4 N) sub 5 Na sub 3 ((1,5-COD)Irter dot P sub 2 W sub 15 Nb sub 3 O sub 62 ), ((n-C sub 4 H sub 9 ) sub 4 N) sub 5 Na sub 3 ((1,5-COD)Rhter dot P sub 2 W sub 15 Nb sub 3 O sub 62 ), and ((n-C sub 4 H sub 9 ) sub 4 N) sub 4. 5 Na sub 2. 5 ((C sub 6 H sub 6 )Ruter dot P sub 2 W sub 15 Nb sub 3 O sub 62 )

Journal of catalysis, 1991-03, Vol.128:1

1991

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Polyoxoanions derived from A-. beta. -SiW sub 9 O sub 34 sup 10 minus : Synthesis and crystallographic and sup 183 W NMR characterization of Si sub 2 W sub 18 Zr sub 3 O sub 71 H sub 3 sup 11 minus , including its organic solvent soluble Bu sub 4 N sup + salt

Inorganic chemistry, 1989-04, Vol.28:8

1989

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The nonasodium salt of the triniobium-substituted polyoxoanion P[sub 2]W[sub 15]Nb[sub 3]O[sub 62][sup 9[minus]]: A water-soluble, readily crystallized form of this Dawson-based soluble metal-oxide organometallics-support system

Inorganic chemistry, 1994-03, Vol.33:7

1994

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Characterization of very large polyoxoanions by fast atom bombardment mass spectroscopy (FABMS)

Inorganic chemistry, 1986, Vol.25 (2), p.241-243

1986

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Polyoxoanions as soluble metal oxide analogues. 5. Synthesis and characterization of polyoxoanion-supported, atomically dispersed iridium(I), (1. 5-COD)Ir-P sub 2 W sub 15 Nb sub 3 O sub 62 sup 8 minus

Inorganic chemistry, 1990-05, Vol.29:10 (10)

1990

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Solution behavior and complete sup 1 H and sup 13 C NMR assignments of the coenzyme B sub 12 derivative (5 prime -deoxyadenosyl)cobinamide using modern 2D NMR experiments, including 600-MHz sup 1 H NMR data

Journal of the American Chemical Society, 1989-02, Vol.111:4

1989

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Multilayered transition metal complexes of cyclophanes

Tetrahedron letters, 1980, Vol.21 (46), p.4405-4408

1980

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A review of modern transition-metal nanoclusters: their synthesis, characterization, and applications in catalysis

A review of soluble transition-metal nanoclusters as arene hydrogenation catalysts

The story of a mechanism-based solution to an irreproducible synthesis resulting in an unexpected closed-system requirement for the LiBEt3H-based reduction: The case of the novel subnanometer cluster, [Ir(1,5-COD)(μ-H)]4, and the resulting improved, independently repeatable, reliable synthesis

Polyoxoanion-supported catalysis: evidence for a P2W15Nb3O629- -supported iridium cyclohexene oxidation catalyst starting from [n-Bu4N]5Na3[(1,5-COD)Ir-P2W15Nb3O62]

Vanadium-Based, Extended Catalytic Lifetime Catechol Dioxygenases: Evidence for a Common Catalyst

The First Experimental Test of the Hypothesis that Enzymes Have Evolved To Enhance Hydrogen Tunneling

Polyoxoanion- and tetrabutylammonium-stabilized Rh(o){sub n} nanoclusters: Unprecedented nanocluster catalytic lifetime in solution

Kinetic and Mechanistic Studies of Vanadium-Based, Extended Catalytic Lifetime Catechol Dioxygenases

Polyoxoanion- and Tetrabutylammonium-Stabilized, Near-Monodisperse, 40 ± 6 Å Rh(0)∼ 1500 to Rh(0)∼ 3700 Nanoclusters: Synthesis, Characterization, and Hydrogenation Catalysis

Polyoxoanion-supported catalysis: evidence for a P 2W 15Nb 3O 629−-supported iridium cyclohexene oxidation catalyst starting from [ n-Bu 4N] 5Na 3[(1,5-COD)Ir·P 2W 15Nb 3O 62]

Characterization of large, polyanionic inorganic molecules: Fast atom bombardment mass spectrometry of P[sub 2]W[sub 15]Nb[sub 3]O[sub 62][sup 9[minus]] and of the supported organometallic catalyst precursor (1,5-COD)Ir[center dot]P[sub 2]W[sub 15]Nb[sub 3]O[sub 62][sup 8[minus]]

The polyoxoanion-supported, atomically dispersed transition-metal precatalyst [(1,5-COD)Ir[times]P[sub 2]W[sub 15]Nb[sub 3]O[sub 62]][sup 8[minus]]: Direct [sup 17]O NMR evidence for Ir-ONb[sub 2] bonding and for a C[sub 3] average symmetry, iridium-to-polyoxoanion support

Radical cage effects in coenzyme B12: Radical trapping, product and kinetic studies

Polyoxoanions as soluble metal oxide analogues. 6. Catalytic activity and initial kinetic and mechanistic studies of polyoxoanion-supported, atomically dispersed iridium(I), (1,5-COD)Ir times P sub 2 W sub 15 Nb sub 3 O sub 62 sup 8 minus

Coenzyme B12 model compounds: A quantitative electrochemical comparison

Polyoxoanions as soluble metal oxide analogs. Synthesis and characterization of the polyoxoanion-supported iridium(I) complex (1,5-COD)Ir[center dot]SiW[sub 9]Nb[sub 3]O[sub 40][sup 6[minus]]

Polyoxoanions derived from A-[beta]-SiW[sub 9]O[sub 34][sup 10[minus]]: Synthesis, single-crystal structural determination, and solution structural characterization by [sup 183]W NMR and IR of A-[beta]-Si[sub 2]W[sub 18]Ti[sub 6]O[sub 77][sup 14[minus]]

Polyoxoanions derived from A-. beta. -SiW sub 9 O sub 34 sup 10 minus : Synthesis and crystallographic and sup 183 W NMR characterization of Si sub 2 W sub 18 Zr sub 3 O sub 71 H sub 3 sup 11 minus , including its organic solvent soluble Bu sub 4 N sup + salt

The nonasodium salt of the triniobium-substituted polyoxoanion P[sub 2]W[sub 15]Nb[sub 3]O[sub 62][sup 9[minus]]: A water-soluble, readily crystallized form of this Dawson-based soluble metal-oxide organometallics-support system

Characterization of very large polyoxoanions by fast atom bombardment mass spectroscopy (FABMS)

Polyoxoanions as soluble metal oxide analogues. 5. Synthesis and characterization of polyoxoanion-supported, atomically dispersed iridium(I), (1. 5-COD)Ir-P sub 2 W sub 15 Nb sub 3 O sub 62 sup 8 minus

Solution behavior and complete sup 1 H and sup 13 C NMR assignments of the coenzyme B sub 12 derivative (5 prime -deoxyadenosyl)cobinamide using modern 2D NMR experiments, including 600-MHz sup 1 H NMR data

Multilayered transition metal complexes of cyclophanes

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