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Highly Diastereo- and Enantioselective Synthesis of Trifluoromethyl-Substituted Cyclopropanes via Myoglobin-Catalyzed Transfer of Trifluoromethylcarbene

Journal of the American Chemical Society, 2017-04, Vol.139 (15), p.5293-5296

2017

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Myoglobin-Catalyzed Olefination of Aldehydes

Angewandte Chemie International Edition, 2016-02, Vol.55 (7), p.2512-2516

International ed. in English, 2016

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Highly Diastereoselective and Enantioselective Olefin Cyclopropanation Using Engineered Myoglobin-Based Catalysts

Angewandte Chemie International Edition, 2015-02, Vol.54 (6), p.1744-1748

International ed. in English, 2015

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Highly Diastereo‐ and Enantioselective Synthesis of Nitrile‐Substituted Cyclopropanes by Myoglobin‐Mediated Carbene Transfer Catalysis

Angewandte Chemie International Edition, 2018-11, Vol.57 (48), p.15852-15856

International ed. in English, 2018

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Cyclopropanations via Heme Carbenes: Basic Mechanism and Effects of Carbene Substituent, Protein Axial Ligand, and Porphyrin Substitution

Journal of the American Chemical Society, 2018-02, Vol.140 (5), p.1649-1662

2018

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Myoglobin‐Catalyzed C−H Functionalization of Unprotected Indoles

Angewandte Chemie International Edition, 2018-07, Vol.57 (31), p.9911-9915

International ed. in English, 2018

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Biocatalytic Synthesis of Allylic and Allenyl Sulfides through a Myoglobin-Catalyzed Doyle-Kirmse Reaction

Angewandte Chemie International Edition, 2016-10, Vol.55 (43), p.13562-13566

International ed. in English, 2016

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Effect of proximal ligand substitutions on the carbene and nitrene transferase activity of myoglobin

Tetrahedron, 2019-04, Vol.75 (16), p.2357-2363

2019

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A Diverse Library of Chiral Cyclopropane Scaffolds via Chemoenzymatic Assembly and Diversification of Cyclopropyl Ketones

Journal of the American Chemical Society, 2021-02, Vol.143 (5), p.2221-2231

2021

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Mechanism-Guided Design and Discovery of Efficient Cytochrome P450-Derived C-H Amination Biocatalysts

Journal of the American Chemical Society, 2020-06, Vol.142 (23), p.10343-10357

2020

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Metal Substitution Modulates the Reactivity and Extends the Reaction Scope of Myoglobin Carbene Transfer Catalysts

Advanced synthesis & catalysis, 2017-06, Vol.359 (12), p.2076-2089

2017

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Biocatalytic Strategy for Highly Diastereo‐ and Enantioselective Synthesis of 2,3‐Dihydrobenzofuran‐Based Tricyclic Scaffolds

Angewandte Chemie International Edition, 2019-07, Vol.58 (30), p.10148-10152

International ed. in English, 2019

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Biocatalytic Strategy for the Highly Stereoselective Synthesis of CHF2‐Containing Trisubstituted Cyclopropanes

Angewandte Chemie International Edition, 2021-03, Vol.60 (13), p.7072-7076

International ed. in English, 2021

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Selective Functionalization of Aliphatic Amines via Myoglobin-Catalyzed Carbene N–H Insertion

Synlett, 2020-02, Vol.31 (3), p.224-229

2020

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Tuning P450 Enzymes as Oxidation Catalysts

ACS catalysis, 2012-04, Vol.2 (4), p.647-666

Fasan, Rudi

2012

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C−H Amination via Nitrene Transfer Catalyzed by Mononuclear Non‐Heme Iron‐Dependent Enzymes

Chembiochem : a European journal of chemical biology, 2020-07, Vol.21 (14), p.1981-1987

2020

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Efficient conversion of primary azides to aldehydes catalyzed by active site variants of myoglobin

Chemical science (Cambridge), 2016-01, Vol.7 (1), p.234-239

2016

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MOrPH-PhD: An Integrated Phage Display Platform for the Discovery of Functional Genetically Encoded Peptide Macrocycles

ACS central science, 2020-03, Vol.6 (3), p.368-381

2020

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Enhancing the Efficiency and Regioselectivity of P450 Oxidation Catalysts by Unnatural Amino Acid Mutagenesis

Chembiochem : a European journal of chemical biology, 2014-05, Vol.15 (7), p.1001-1010

2014

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Origin of High Stereocontrol in Olefin Cyclopropanation Catalyzed by an Engineered Carbene Transferase

ACS catalysis, 2019-02, Vol.9 (2), p.1514-1524

2019

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Chemo-enzymatic fluorination of unactivated organic compounds

Nature chemical biology, 2009-01, Vol.5 (1), p.26-28

2009

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Mechanistic manifold in a hemoprotein-catalyzed cyclopropanation reaction with diazoketone

Nature communications, 2023-12, Vol.14 (1), p.7985-7985, Article 7985

2023

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Mechanistic Investigation of Biocatalytic Heme Carbenoid Si−H Insertions

ChemCatChem, 2019-07, Vol.11 (13), p.3101-3108

2019

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Design and Evolution of a Macrocyclic Peptide Inhibitor of the Sonic Hedgehog/Patched Interaction

Journal of the American Chemical Society, 2017-09, Vol.139 (36), p.12559-12568

2017

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Myoglobin-catalyzed intermolecular carbene N-H insertion with arylamine substrates

Chemical communications (Cambridge, England), 2015-01, Vol.51 (8), p.1532-1534

2015

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Highly Diastereo- and Enantioselective Synthesis of Trifluoromethyl-Substituted Cyclopropanes via Myoglobin-Catalyzed Transfer of Trifluoromethylcarbene

Myoglobin-Catalyzed Olefination of Aldehydes

Highly Diastereoselective and Enantioselective Olefin Cyclopropanation Using Engineered Myoglobin-Based Catalysts

Highly Diastereo‐ and Enantioselective Synthesis of Nitrile‐Substituted Cyclopropanes by Myoglobin‐Mediated Carbene Transfer Catalysis

Cyclopropanations via Heme Carbenes: Basic Mechanism and Effects of Carbene Substituent, Protein Axial Ligand, and Porphyrin Substitution

Myoglobin‐Catalyzed C−H Functionalization of Unprotected Indoles

Biocatalytic Synthesis of Allylic and Allenyl Sulfides through a Myoglobin-Catalyzed Doyle-Kirmse Reaction

Effect of proximal ligand substitutions on the carbene and nitrene transferase activity of myoglobin

A Diverse Library of Chiral Cyclopropane Scaffolds via Chemoenzymatic Assembly and Diversification of Cyclopropyl Ketones

Mechanism-Guided Design and Discovery of Efficient Cytochrome P450-Derived C-H Amination Biocatalysts

Metal Substitution Modulates the Reactivity and Extends the Reaction Scope of Myoglobin Carbene Transfer Catalysts

Biocatalytic Strategy for Highly Diastereo‐ and Enantioselective Synthesis of 2,3‐Dihydrobenzofuran‐Based Tricyclic Scaffolds

Biocatalytic Strategy for the Highly Stereoselective Synthesis of CHF2‐Containing Trisubstituted Cyclopropanes

Selective Functionalization of Aliphatic Amines via Myoglobin-Catalyzed Carbene N–H Insertion

Tuning P450 Enzymes as Oxidation Catalysts

C−H Amination via Nitrene Transfer Catalyzed by Mononuclear Non‐Heme Iron‐Dependent Enzymes

Efficient conversion of primary azides to aldehydes catalyzed by active site variants of myoglobin

MOrPH-PhD: An Integrated Phage Display Platform for the Discovery of Functional Genetically Encoded Peptide Macrocycles

Enhancing the Efficiency and Regioselectivity of P450 Oxidation Catalysts by Unnatural Amino Acid Mutagenesis

Origin of High Stereocontrol in Olefin Cyclopropanation Catalyzed by an Engineered Carbene Transferase

Chemo-enzymatic fluorination of unactivated organic compounds

Mechanistic manifold in a hemoprotein-catalyzed cyclopropanation reaction with diazoketone

Mechanistic Investigation of Biocatalytic Heme Carbenoid Si−H Insertions

Design and Evolution of a Macrocyclic Peptide Inhibitor of the Sonic Hedgehog/Patched Interaction

Myoglobin-catalyzed intermolecular carbene N-H insertion with arylamine substrates

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