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Recent advances in B–H functionalization of icosahedral carboranes and boranes by transition metal catalysis

Pure and applied chemistry, 2018-04, Vol.90 (4), p.733-744

Duttwyler, Simon

2018

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Rhodium(III)-Catalyzed Alkenylation-Annulation of closo-Dodecaborate Anions through Double B−H Activation at Room Temperature

Angewandte Chemie (International ed.), 2016-12, Vol.55 (50), p.15609-15614

International ed. in English, 2016

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Proton-Catalyzed, Silane-Fueled Friedel-Crafts Coupling of Fluoroarenes

Science (American Association for the Advancement of Science), 2011-04, Vol.332 (6029), p.574-577

2011

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Palladium-Catalyzed Selective Five-Fold Cascade Arylation of the 12-Vertex Monocarborane Anion by B–H Activation

Journal of the American Chemical Society, 2018-10, Vol.140 (42), p.13798-13807

2018

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B-H functionalization of the monocarba-closo-dodecaborate anion by rhodium and iridium catalysis

Dalton transactions : an international journal of inorganic chemistry, 2017, Vol.46 (10), p.3135-3140

2017

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Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

Chemical communications (Cambridge, England), 2018, Vol.54 (14), p.1698-1701

2018

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Highly Diastereoselective Synthesis of Tetrahydropyridines by a C–H Activation–Cyclization–Reduction Cascade

Journal of the American Chemical Society, 2012-03, Vol.134 (9), p.4064-4067

2012

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Rhodium(iii)-catalyzed dehydrogenative dialkenylation of the monocarba-closo-decaborate cluster by regioselective B-H activation

Chemical communications (Cambridge, England), 2018, Vol.54 (88), p.12451-12454

2018

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A Microporous Metal‐Organic Framework Supramolecularly Assembled from a CuII Dodecaborate Cluster Complex for Selective Gas Separation

Angewandte Chemie International Edition, 2019-06, Vol.58 (24), p.8145-8150

International ed. in English, 2019

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Synthesis and full characterization of an iridium B-H activation intermediate of the monocarba-closo-dodecaborate anion

Chemical communications (Cambridge, England), 2017, Vol.53 (1), p.176-179

2017

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Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino- closo -dodecaborate Anion [B 12 H 11 NH₃]

Molecules (Basel, Switzerland), 2018-11, Vol.23 (12), p.3137

2018

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Transition Metal Complexes of a Monocarba‐closo‐dodecaborate Ligand via B–H Activation

European journal of inorganic chemistry, 2017-10, Vol.2017 (38-39), p.4420-4424

2017

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Gram-Scale Synthesis of an Ultrastable Microporous Metal-Organic Framework for Efficient Adsorptive Separation of C2H2/CO2 and C2H2/CH4

Molecules (Basel, Switzerland), 2021-08, Vol.26 (17), p.5121

2021

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Natural-Product-Directed Catalytic Stereoselective Synthesis of Functionalized Fused Borane Cluster–Oxazoles for the Discovery of Bactericidal Agents

ACS central science, 2022-03, Vol.8 (3), p.322-331

2022

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Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis

Science (American Association for the Advancement of Science), 2013-02, Vol.339 (6120), p.678-682

2013

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C----F Activation of Fluorobenzene by Silylium Carboranes: Evidence for Incipient Phenyl Cation Reactivity

Angewandte Chemie (International ed.), 2010-10, Vol.49 (41), p.7519-7522

2010

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A Microporous Metal-Organic Framework Supramolecularly Assembled from a Cu II Dodecaborate Cluster Complex for Selective Gas Separation

Angewandte Chemie International Edition, 2019-06, Vol.58 (24), p.8145-8150

2019

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Efficient access to amides of the carborane carboxylic acid [1-(COOH)-CB 11 H 11 ]

RSC advances, 2018-01, Vol.8 (40), p.22447-22451

2018

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Arenium Acid Catalyzed Deuteration of Aromatic Hydrocarbons

Journal of organic chemistry, 2013-03, Vol.78 (5), p.2134-2138

2013

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Rational Design of Microporous MOFs with Anionic Boron Cluster Functionality and Cooperative Dihydrogen Binding Sites for Highly Selective Capture of Acetylene

Angewandte Chemie International Edition, 2020-09, Vol.59 (40), p.17664-17669

International ed. in English, 2020

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Chemistry of three-dimensional icosahedral boron clusters anions: closo-dodecaborate (2-) [B12H12]2- and carba-closo-dodecaborate(-) [CB11H12]

Coordination chemistry reviews, 2024-10, Vol.516, p.215974, Article 215974

2024

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Highly selective gas separation by two isostructural boron cluster pillared MOFs

Separation and purification technology, 2022-01, Vol.283, p.120220, Article 120220

2022

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Highly selective palladium-catalyzed one-pot, five-fold B-H/C-H cross coupling of monocarboranes with alkenes

Chemical science (Cambridge), 2019-04, Vol.10 (15), p.4177-4184

2019

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Supramolecular Cu()-dipyridyl frameworks featuring weakly coordinating dodecaborate dianions for selective gas separation

CrystEngComm, 2021-01, Vol.23 (2), p.282-291

2021

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Efficient Brønsted‐Acid‐Catalyzed Deuteration of Arenes and Their Transformation to Functionalized Deuterated Products

Asian journal of organic chemistry, 2017-08, Vol.6 (8), p.1063-1071

2017

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Recent advances in B–H functionalization of icosahedral carboranes and boranes by transition metal catalysis

Rhodium(III)-Catalyzed Alkenylation-Annulation of closo-Dodecaborate Anions through Double B−H Activation at Room Temperature

Proton-Catalyzed, Silane-Fueled Friedel-Crafts Coupling of Fluoroarenes

Palladium-Catalyzed Selective Five-Fold Cascade Arylation of the 12-Vertex Monocarborane Anion by B–H Activation

B-H functionalization of the monocarba-closo-dodecaborate anion by rhodium and iridium catalysis

Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

Highly Diastereoselective Synthesis of Tetrahydropyridines by a C–H Activation–Cyclization–Reduction Cascade

Rhodium(iii)-catalyzed dehydrogenative dialkenylation of the monocarba-closo-decaborate cluster by regioselective B-H activation

A Microporous Metal‐Organic Framework Supramolecularly Assembled from a CuII Dodecaborate Cluster Complex for Selective Gas Separation

Synthesis and full characterization of an iridium B-H activation intermediate of the monocarba-closo-dodecaborate anion

Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino- closo -dodecaborate Anion [B 12 H 11 NH₃]

Transition Metal Complexes of a Monocarba‐closo‐dodecaborate Ligand via B–H Activation

Gram-Scale Synthesis of an Ultrastable Microporous Metal-Organic Framework for Efficient Adsorptive Separation of C2H2/CO2 and C2H2/CH4

Natural-Product-Directed Catalytic Stereoselective Synthesis of Functionalized Fused Borane Cluster–Oxazoles for the Discovery of Bactericidal Agents

Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis

C----F Activation of Fluorobenzene by Silylium Carboranes: Evidence for Incipient Phenyl Cation Reactivity

A Microporous Metal-Organic Framework Supramolecularly Assembled from a Cu II Dodecaborate Cluster Complex for Selective Gas Separation

Efficient access to amides of the carborane carboxylic acid [1-(COOH)-CB 11 H 11 ]

Arenium Acid Catalyzed Deuteration of Aromatic Hydrocarbons

Rational Design of Microporous MOFs with Anionic Boron Cluster Functionality and Cooperative Dihydrogen Binding Sites for Highly Selective Capture of Acetylene

Chemistry of three-dimensional icosahedral boron clusters anions: closo-dodecaborate (2-) [B12H12]2- and carba-closo-dodecaborate(-) [CB11H12]

Highly selective gas separation by two isostructural boron cluster pillared MOFs

Highly selective palladium-catalyzed one-pot, five-fold B-H/C-H cross coupling of monocarboranes with alkenes

Supramolecular Cu()-dipyridyl frameworks featuring weakly coordinating dodecaborate dianions for selective gas separation

Efficient Brønsted‐Acid‐Catalyzed Deuteration of Arenes and Their Transformation to Functionalized Deuterated Products

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