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Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon

Angewandte Chemie (International ed.), 2010-07, Vol.49 (32), p.5570-5573

2010

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Synthesis and Characterization of Dysprosium and Lanthanum Bis(iminophosphorano)methanide and -methanediide Complexes

Organometallics, 2010-05, Vol.29 (10), p.2315-2321

2010

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Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex

Angewandte Chemie (International ed.), 2014-06, Vol.53 (26), p.6696-6700

International ed. in English, 2014

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The Nature of the UC Double Bond: Pushing the Stability of High-Oxidation-State Uranium Carbenes to the Limit

Chemistry : a European journal, 2013-05, Vol.19 (22), p.7071

2013

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Uranium-carbon multiple bonding: facile access to the pentavalent uranium carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and comparison of U(V)=C and U(IV)=C bonds

Angewandte Chemie International Edition, 2011-03, Vol.50 (10), p.2383-2386

2011

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The Nature of the UC Double Bond: Pushing the Stability of High-Oxidation-State Uranium Carbenes to the Limit

Chemistry : a European journal, 2013-05, Vol.19 (22), p.7071-7083

2013

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Covalent Uranium Carbene Chemistry

Comments on modern chemistry. Part A, Comments on inorganic chemistry, 2015-09, Vol.35 (5), p.262-294

2015

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Reactivity of the uranium(IV) carbene complex [U(BIPM(TMS))(Cl)(μ-Cl)₂Li(THF)₂] (BIPM(TMS) = {C(PPh₂NSiMe₃)₂}) towards carbonyl and heteroallene substrates: metallo-Wittig, adduct formation, C-F bond activation, and [2 + 2]-cycloaddition reactions

Dalton transactions : an international journal of inorganic chemistry, 2014-10, Vol.43 (38), p.14275-14283

2014

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Synthesis and structure of [U{C(PPh2NMes)2}2] (Mes = 2,4,6-Me3C6H2): A homoleptic uranium bis(carbene) complex with two formal U=C double bonds

Dalton transactions : an international journal of inorganic chemistry, 2010-06, Vol.39 (21), p.5074-5076

2010

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Uranium-Carbene-Imido Metalla-Allenes: Ancillary-Ligand-Controlled cis-/trans-Isomerisation and Assessment of trans Influence in the R2C=UIV=NR′ Unit (R=Ph2PNSiMe3; R′=CPh3)

Chemistry : a European journal, 2016-08, Vol.22 (33), p.11559-11563

2016

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Synthesis and reactivity of the yttrium-alkyl-carbene complex [Y(BIPM)(CH2C6H5)(THF)] (BIPM = {C(PPh2NSiMe3)2})

Dalton transactions : an international journal of inorganic chemistry, 2009 (23), p.4547

2009

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Group 1 Bis(iminophosphorano)methanides, Part 2: N-Aryl Derivatives of the Sterically Demanding Methanes H2C(PPh2NR)2 (R = 2,4,6-trimethylphenyl or 2,6-diisopropylphenyl)

Organometallics, 2011-10, Vol.30 (20), p.5326-5337

2011

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Group 1 Bis(iminophosphorano)methanides, Part 1: N-Alkyl and Silyl Derivatives of the Sterically Demanding Methanes H2C(PPh2NR)2 (R = Adamantyl and Trimethylsilyl)

Organometallics, 2011-10, Vol.30 (20), p.5314-5325

2011

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Reactivity of the Yttrium Alkyl Carbene Complex [Y(BIPM)(CH2C6H5)(THF)] (BIPM = {C(PPh2NSiMe3)2})2–: From Insertions, Substitutions, and Additions to Nontypical Transformations

Organometallics, 2013-03, Vol.32 (5), p.1251-1264

2013

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Uranium-Carbon Multiple Bonding: Facile Access to the Pentavalent Uranium Carbene [U{C(PPh₂NSiMe₃)₂}(Cl)₂(I)] and Comparison of UVC and UIVC Bonds

Angewandte Chemie (International ed.), 2011-03, Vol.50 (10), p.2383-2386

2011

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Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex

Angewandte Chemie, 2014-06, Vol.126 (26), p.6814-6818

2014

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Reactivity of the uranium( iv ) carbene complex [U(BIPM TMS )(Cl)(μ-Cl) 2 Li(THF) 2 ] (BIPM TMS = {C(PPh 2 NSiMe 3 ) 2 }) towards carbonyl and heteroallene substrates: metallo-Wittig, adduct formation, C–F bond activation, and [2 + 2]-cycloaddition reactions

Dalton transactions : an international journal of inorganic chemistry, 2014-10, Vol.43 (38), p.14275-14283

2014

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Uranium–Carbon Multiple Bonding: Facile Access to the Pentavalent Uranium Carbene [U{C(PPh 2 NSiMe 3 ) 2 }(Cl) 2 (I)] and Comparison of U V C and U IV C Bonds

Angewandte Chemie International Edition, 2011-03, Vol.50 (10), p.2383-2386

2011

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Uranium–Carbene–Imido Metalla‐Allenes: Ancillary‐Ligand‐Controlled cis ‐/ trans ‐Isomerisation and Assessment of trans Influence in the R 2 C=U IV =NR′ Unit (R=Ph 2 PNSiMe 3 ; R′=CPh 3 )

Chemistry : a European journal, 2016-08, Vol.22 (33), p.11559-11563

2016

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Uranium-Carbene-Imido Metalla-Allenes: Ancillary-Ligand-Controlled cis-/trans-Isomerisation and Assessment of trans Influence in the R sub(2)C=U super(IV)=NR' Unit (R=Ph sub(2)PNSiMe sub(3); R'=CPh sub(3))

Chemistry : a European journal, 2016-08, Vol.22 (33), p.11559-11563

2016

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Reactivity of the uranium(iv) carbene complex [U(BIPMTMS)(Cl)(μ-Cl)2Li(THF)2] (BIPMTMS = {C(PPh2NSiMe3)2}) towards carbonyl and heteroallene substrates: metallo-Wittig, adduct formation, C-F bond activation, and [2 + 2]-cycloaddition reactionsCCDC 993178-993184 for 2-8. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c4dt00909f

2014-09

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Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R 2 C═U═O] 2+ Analogue of the [O═U═O] 2+ Uranyl Ion (R = Ph 2 PNSiMe 3 ), and Comparison of the Nature of U IV ═C, U V ═C, and U VI ═C Double Bonds

Journal of the American Chemical Society, 2012-06, Vol.134 (24), p.10047-10054

2012

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Uranium-Carbene-Imido Metalla-Allenes: Ancillary-Ligand-Controlled cis-/trans-Isomerisation and Assessment of trans Influence in the R2 C=U(IV) =NR' Unit (R=Ph2 PNSiMe3 ; R'=CPh3 )

Chemistry : a European journal, 2016-08, Vol.22 (33), p.11559-11563

2016

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Synthesis and structure of [U{C(PPh2NMes)2}2] (Mes = 2,4,6-Me3C6H2): A homoleptic uranium bis(carbene) complex with two formal U&z.dbd;C double bondsElectronic supplementary information (ESI) available: Full experimental, crystallographic and computational details for 2 and 3. CCDC reference numbers 764797 and 764798. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0dt00152j

2010-05

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Group 1 Bis(iminophosphorano)methanides, Part 2: N- Aryl Derivatives of the Sterically Demanding Methanes H 2 C(PPh 2 NR) 2 (R = 2,4,6-trimethylphenyl or 2,6-diisopropylphenyl)

Organometallics, 2011-10, Vol.30 (20), p.5326-5337

2011

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Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon

Synthesis and Characterization of Dysprosium and Lanthanum Bis(iminophosphorano)methanide and -methanediide Complexes

Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex

The Nature of the UC Double Bond: Pushing the Stability of High-Oxidation-State Uranium Carbenes to the Limit

Uranium-carbon multiple bonding: facile access to the pentavalent uranium carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and comparison of U(V)=C and U(IV)=C bonds

The Nature of the UC Double Bond: Pushing the Stability of High-Oxidation-State Uranium Carbenes to the Limit

Covalent Uranium Carbene Chemistry

Reactivity of the uranium(IV) carbene complex [U(BIPM(TMS))(Cl)(μ-Cl)₂Li(THF)₂] (BIPM(TMS) = {C(PPh₂NSiMe₃)₂}) towards carbonyl and heteroallene substrates: metallo-Wittig, adduct formation, C-F bond activation, and [2 + 2]-cycloaddition reactions

Synthesis and structure of [U{C(PPh2NMes)2}2] (Mes = 2,4,6-Me3C6H2): A homoleptic uranium bis(carbene) complex with two formal U=C double bonds

Uranium-Carbene-Imido Metalla-Allenes: Ancillary-Ligand-Controlled cis-/trans-Isomerisation and Assessment of trans Influence in the R2C=UIV=NR′ Unit (R=Ph2PNSiMe3; R′=CPh3)

Synthesis and reactivity of the yttrium-alkyl-carbene complex [Y(BIPM)(CH2C6H5)(THF)] (BIPM = {C(PPh2NSiMe3)2})

Group 1 Bis(iminophosphorano)methanides, Part 2: N-Aryl Derivatives of the Sterically Demanding Methanes H2C(PPh2NR)2 (R = 2,4,6-trimethylphenyl or 2,6-diisopropylphenyl)

Group 1 Bis(iminophosphorano)methanides, Part 1: N-Alkyl and Silyl Derivatives of the Sterically Demanding Methanes H2C(PPh2NR)2 (R = Adamantyl and Trimethylsilyl)

Reactivity of the Yttrium Alkyl Carbene Complex [Y(BIPM)(CH2C6H5)(THF)] (BIPM = {C(PPh2NSiMe3)2})2–: From Insertions, Substitutions, and Additions to Nontypical Transformations

Uranium-Carbon Multiple Bonding: Facile Access to the Pentavalent Uranium Carbene [U{C(PPh₂NSiMe₃)₂}(Cl)₂(I)] and Comparison of UVC and UIVC Bonds

Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex

Reactivity of the uranium( iv ) carbene complex [U(BIPM TMS )(Cl)(μ-Cl) 2 Li(THF) 2 ] (BIPM TMS = {C(PPh 2 NSiMe 3 ) 2 }) towards carbonyl and heteroallene substrates: metallo-Wittig, adduct formation, C–F bond activation, and [2 + 2]-cycloaddition reactions

Uranium–Carbon Multiple Bonding: Facile Access to the Pentavalent Uranium Carbene [U{C(PPh 2 NSiMe 3 ) 2 }(Cl) 2 (I)] and Comparison of U V C and U IV C Bonds

Uranium–Carbene–Imido Metalla‐Allenes: Ancillary‐Ligand‐Controlled cis ‐/ trans ‐Isomerisation and Assessment of trans Influence in the R 2 C=U IV =NR′ Unit (R=Ph 2 PNSiMe 3 ; R′=CPh 3 )

Uranium-Carbene-Imido Metalla-Allenes: Ancillary-Ligand-Controlled cis-/trans-Isomerisation and Assessment of trans Influence in the R sub(2)C=U super(IV)=NR' Unit (R=Ph sub(2)PNSiMe sub(3); R'=CPh sub(3))

Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R 2 C═U═O] 2+ Analogue of the [O═U═O] 2+ Uranyl Ion (R = Ph 2 PNSiMe 3 ), and Comparison of the Nature of U IV ═C, U V ═C, and U VI ═C Double Bonds

Uranium-Carbene-Imido Metalla-Allenes: Ancillary-Ligand-Controlled cis-/trans-Isomerisation and Assessment of trans Influence in the R2 C=U(IV) =NR' Unit (R=Ph2 PNSiMe3 ; R'=CPh3 )

Group 1 Bis(iminophosphorano)methanides, Part 2: N- Aryl Derivatives of the Sterically Demanding Methanes H 2 C(PPh 2 NR) 2 (R = 2,4,6-trimethylphenyl or 2,6-diisopropylphenyl)

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