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Site-Selective Deuteration of Amino Acids through Dual-Protein Catalysis

Journal of the American Chemical Society, 2022-04, Vol.144 (16), p.7327-7336

2022

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Intrinsic evolutionary constraints on protease structure, enzyme acylation, and the identity of the catalytic triad

Proceedings of the National Academy of Sciences - PNAS, 2013-02, Vol.110 (8), p.E653-E661

2013

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Peptides hit the catalysis walk

Nature chemical biology, 2023-04, Vol.19 (4), p.395

2023

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Substrate multiplexed protein engineering facilitates promiscuous biocatalytic synthesis

Nature communications, 2022-09, Vol.13 (1), p.5242-5242, Article 5242

2022

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Directed evolution of the tryptophan synthase β-subunit for stand-alone function recapitulates allosteric activation

Proceedings of the National Academy of Sciences - PNAS, 2015-11, Vol.112 (47), p.14599-14604

2015

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Consecutive radical S-adenosylmethionine methylations form the ethyl side chain in thienamycin biosynthesis

Proceedings of the National Academy of Sciences - PNAS, 2015-08, Vol.112 (33), p.10354-10358

2015

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Structure of a bound peptide phosphonate reveals the mechanism of nocardicin bifunctional thioesterase epimerase-hydrolase half-reactions

Nature communications, 2019-08, Vol.10 (1), p.3868-12, Article 3868

2019

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Structural Adaptability Facilitates Histidine Heme Ligation in a Cytochrome P450

Journal of the American Chemical Society, 2015-11, Vol.137 (43), p.13861-13865

2015

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Enantioselective, intermolecular benzylic C-H amination catalysed by an engineered iron-haem enzyme

Nature chemistry, 2017-07, Vol.9 (7), p.629

2017

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A Homozygous Mutation in Human PRICKLE1 Causes an Autosomal-Recessive Progressive Myoclonus Epilepsy-Ataxia Syndrome

American journal of human genetics, 2008-11, Vol.83 (5), p.572-581

2008

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Cofactor specificity motifs and the induced fit mechanism in class I ketol-acid reductoisomerases

Biochemical journal, 2015-06, Vol.468 (3), p.475-484

2015

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Engineered Biocatalytic Synthesis of β-N-Substituted-α-Amino Acids

Angewandte Chemie International Edition, 2023-10, Vol.62 (43), p.e202311189-e202311189

International ed. in English, 2023

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Engineering Enzyme Substrate Scope Complementarity for Promiscuous Cascade Synthesis of 1,2‐Amino Alcohols

Angewandte Chemie (International ed.), 2022-11, Vol.61 (46), p.e202212637-n/a

International ed. in English, 2022

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Enzyme-Controlled Nitrogen-Atom Transfer Enables Regiodivergent C–H Amination

Journal of the American Chemical Society, 2014-11, Vol.136 (44), p.15505-15508

2014

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Directed Evolution Mimics Allosteric Activation by Stepwise Tuning of the Conformational Ensemble

Journal of the American Chemical Society, 2018-06, Vol.140 (23), p.7256-7266

2018

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Catalytic iron-carbene intermediate revealed in a cytochrome c carbene transferase

Proceedings of the National Academy of Sciences - PNAS, 2018-07, Vol.115 (28), p.7308-7313

2018

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Synthesis of β‑Branched Tryptophan Analogues Using an Engineered Subunit of Tryptophan Synthase

Journal of the American Chemical Society, 2016-07, Vol.138 (27), p.8388-8391

2016

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De novo biosynthesis of a nonnatural cobalt porphyrin cofactor in E. coli and incorporation into hemoproteins

Proceedings of the National Academy of Sciences - PNAS, 2021-04, Vol.118 (16), p.1

2021

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l-Threonine Transaldolase Activity Is Enabled by a Persistent Catalytic Intermediate

ACS chemical biology, 2021-01, Vol.16 (1), p.86-95

2021

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Insights into cis-autoproteolysis reveal a reactive state formed through conformational rearrangement

Proceedings of the National Academy of Sciences - PNAS, 2012-02, Vol.109 (7), p.2308-2313

2012

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Engineered Biosynthesis of β‐Alkyl Tryptophan Analogues

Angewandte Chemie International Edition, 2018-11, Vol.57 (45), p.14764-14768

International ed. in English, 2018

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Facile in Vitro Biocatalytic Production of Diverse Tryptamines

Chembiochem : a European journal of chemical biology, 2019-08, Vol.20 (15), p.1939-1944

2019

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Autoproteolytic Activation of ThnT Results in Structural Reorganization Necessary for Substrate Binding and Catalysis

Journal of molecular biology, 2012-09, Vol.422 (4), p.508-518

2012

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Multiplexed Assessment of Promiscuous Non-Canonical Amino Acid Synthase Activity in a Pyridoxal Phosphate-Dependent Protein Family

ACS catalysis, 2023-09, Vol.13 (17), p.11644-11655

2023

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Asymmetric Alkylation of Ketones Catalyzed by Engineered TrpB

Angewandte Chemie (International ed.), 2021-09, Vol.60 (39), p.21412-21417

International ed. in English, 2021

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Site-Selective Deuteration of Amino Acids through Dual-Protein Catalysis

Intrinsic evolutionary constraints on protease structure, enzyme acylation, and the identity of the catalytic triad

Peptides hit the catalysis walk

Substrate multiplexed protein engineering facilitates promiscuous biocatalytic synthesis

Directed evolution of the tryptophan synthase β-subunit for stand-alone function recapitulates allosteric activation

Consecutive radical S-adenosylmethionine methylations form the ethyl side chain in thienamycin biosynthesis

Structure of a bound peptide phosphonate reveals the mechanism of nocardicin bifunctional thioesterase epimerase-hydrolase half-reactions

Structural Adaptability Facilitates Histidine Heme Ligation in a Cytochrome P450

Enantioselective, intermolecular benzylic C-H amination catalysed by an engineered iron-haem enzyme

A Homozygous Mutation in Human PRICKLE1 Causes an Autosomal-Recessive Progressive Myoclonus Epilepsy-Ataxia Syndrome

Cofactor specificity motifs and the induced fit mechanism in class I ketol-acid reductoisomerases

Engineered Biocatalytic Synthesis of β-N-Substituted-α-Amino Acids

Engineering Enzyme Substrate Scope Complementarity for Promiscuous Cascade Synthesis of 1,2‐Amino Alcohols

Enzyme-Controlled Nitrogen-Atom Transfer Enables Regiodivergent C–H Amination

Directed Evolution Mimics Allosteric Activation by Stepwise Tuning of the Conformational Ensemble

Catalytic iron-carbene intermediate revealed in a cytochrome c carbene transferase

Synthesis of β‑Branched Tryptophan Analogues Using an Engineered Subunit of Tryptophan Synthase

De novo biosynthesis of a nonnatural cobalt porphyrin cofactor in E. coli and incorporation into hemoproteins

l-Threonine Transaldolase Activity Is Enabled by a Persistent Catalytic Intermediate

Insights into cis-autoproteolysis reveal a reactive state formed through conformational rearrangement

Engineered Biosynthesis of β‐Alkyl Tryptophan Analogues

Facile in Vitro Biocatalytic Production of Diverse Tryptamines

Autoproteolytic Activation of ThnT Results in Structural Reorganization Necessary for Substrate Binding and Catalysis

Multiplexed Assessment of Promiscuous Non-Canonical Amino Acid Synthase Activity in a Pyridoxal Phosphate-Dependent Protein Family

Asymmetric Alkylation of Ketones Catalyzed by Engineered TrpB

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