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Selective Carbon-Carbon Bond Cleavage of Cyclopropylamine Derivatives

Chemical reviews, 2021-01, Vol.121 (1), p.80-109

2021

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Electrophilic Aminating Agents in Total Synthesis

Angewandte Chemie (International ed.), 2021-12, Vol.60 (49), p.25640-25666

International ed. in English, 2021

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Modular Access to Azepines by Directed Carbonylative C–C Bond Activation of Aminocyclopropanes

Journal of the American Chemical Society, 2018-02, Vol.140 (8), p.2743-2747

2018

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Transition Metal Free C–N Bond Forming Dearomatizations and Aryl C–H Aminations by in Situ Release of a Hydroxylamine-Based Aminating Agent

Journal of the American Chemical Society, 2017-10, Vol.139 (40), p.14005-14008

2017

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Synthesis and applications of rhodacyclopentanones derived from C-C bond activation

Chemical communications (Cambridge, England), 2016-01, Vol.52 (72), p.1817-1829

2016

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Branch-Selective and Enantioselective Iridium-Catalyzed Alkene Hydroarylation via Anilide-Directed C–H Oxidative Addition

Journal of the American Chemical Society, 2018-08, Vol.140 (30), p.9351-9356

2018

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Highly Efficient Narasaka-Heck Cyclizations Mediated by P(3,5-(CF3)2C6H3)3: Facile Access to N-Heterobicyclic Scaffolds

Angewandte Chemie (International ed.), 2012-02, Vol.51 (7), p.1675-1679

International ed. in English, 2012

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Recent developments in the use of aza-Heck cyclizations for the synthesis of chiral N-heterocycles

Chemical science (Cambridge), 2017-08, Vol.8 (8), p.5248-526

2017

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Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation

Journal of the American Chemical Society, 2017-09, Vol.139 (36), p.12386-12389

2017

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Enantioselective Aza-Heck Cyclizations of N‑(Tosyloxy)carbamates: Synthesis of Pyrrolidines and Piperidines

Journal of the American Chemical Society, 2019-02, Vol.141 (8), p.3356-3360

2019

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Recent Methodologies That Exploit C–C Single-Bond Cleavage of Strained Ring Systems by Transition Metal Complexes

Chemical reviews, 2017-07, Vol.117 (13), p.9404-9432

2017

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A Simple and Broadly Applicable C−N Bond Forming Dearomatization Protocol Enabled by Bifunctional Amino Reagents

Angewandte Chemie (International ed.), 2017-11, Vol.56 (46), p.14531-14535

International ed. in English, 2017

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Branch-Selective, Iridium-Catalyzed Hydroarylation of Monosubstituted Alkenes via a Cooperative Destabilization Strategy

Journal of the American Chemical Society, 2014-07, Vol.136 (29), p.10258-10261

2014

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Stereospecific Alkene Aziridination Using a Bifunctional Amino-Reagent: An Aza-Prilezhaev Reaction

Journal of the American Chemical Society, 2018-12, Vol.140 (51), p.17846-17850

2018

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Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents

Angewandte Chemie (International ed.), 2009-01, Vol.48 (1), p.34-46

2009

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Oxidative Addition, Transmetalation, and Reductive Elimination at a 2,2′-Bipyridyl-Ligated Gold Center

Journal of the American Chemical Society, 2018-03, Vol.140 (12), p.4440-4445

2018

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Branch-Selective Alkene Hydroarylation by Cooperative Destabilization: Iridium-Catalyzed ortho-Alkylation of Acetanilides

Angewandte Chemie (International ed.), 2015-12, Vol.54 (49), p.14866-14870

International ed. in English, 2015

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Pyrrolidines and Piperidines by Ligand‐Enabled Aza‐Heck Cyclizations and Cascades of N‐(Pentafluorobenzoyloxy)carbamates

Angewandte Chemie (International ed.), 2018-04, Vol.57 (18), p.5124-5128

International ed. in English, 2018

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Rhodacyclopentanones as Linchpins for the Atom Economical Assembly of Diverse Polyheterocycles

Journal of the American Chemical Society, 2020-01, Vol.142 (4), p.1740-1745

2020

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Modular Access to Substituted Azocanes via a Rhodium-Catalyzed Cycloaddition–Fragmentation Strategy

Journal of the American Chemical Society, 2015-07, Vol.137 (25), p.8054-8057

2015

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Reversible C–C Bond Activation Enables Stereocontrol in Rh-Catalyzed Carbonylative Cycloadditions of Aminocyclopropanes

Journal of the American Chemical Society, 2015-01, Vol.137 (1), p.463-468

2015

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Carbonylative C−C Bond Activation of Electron‐Poor Cyclopropanes: Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides

Angewandte Chemie International Edition, 2019-01, Vol.58 (1), p.221-225

International ed. in English, 2019

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Complex Polyheterocycles and the Stereochemical Reassignment of Pileamartine A via Aza-Heck Triggered Aryl C–H Functionalization Cascades

Journal of the American Chemical Society, 2021-09, Vol.143 (38), p.15593-15598

2021

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Dichotomous mechanistic behavior in Narasaka-Heck cyclizations: electron rich Pd-catalysts generate iminyl radicals

Chemical science (Cambridge), 2016-01, Vol.7 (2), p.1508-1513

2016

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Nucleophilic Aromatic Substitution (SNAr) as an Approach to Challenging Carbohydrate–Aryl Ethers

Organic letters, 2015-10, Vol.17 (19), p.4846-4849

2015

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Selective Carbon-Carbon Bond Cleavage of Cyclopropylamine Derivatives

Electrophilic Aminating Agents in Total Synthesis

Modular Access to Azepines by Directed Carbonylative C–C Bond Activation of Aminocyclopropanes

Transition Metal Free C–N Bond Forming Dearomatizations and Aryl C–H Aminations by in Situ Release of a Hydroxylamine-Based Aminating Agent

Synthesis and applications of rhodacyclopentanones derived from C-C bond activation

Branch-Selective and Enantioselective Iridium-Catalyzed Alkene Hydroarylation via Anilide-Directed C–H Oxidative Addition

Highly Efficient Narasaka-Heck Cyclizations Mediated by P(3,5-(CF3)2C6H3)3: Facile Access to N-Heterobicyclic Scaffolds

Recent developments in the use of aza-Heck cyclizations for the synthesis of chiral N-heterocycles

Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation

Enantioselective Aza-Heck Cyclizations of N‑(Tosyloxy)carbamates: Synthesis of Pyrrolidines and Piperidines

Recent Methodologies That Exploit C–C Single-Bond Cleavage of Strained Ring Systems by Transition Metal Complexes

A Simple and Broadly Applicable C−N Bond Forming Dearomatization Protocol Enabled by Bifunctional Amino Reagents

Branch-Selective, Iridium-Catalyzed Hydroarylation of Monosubstituted Alkenes via a Cooperative Destabilization Strategy

Stereospecific Alkene Aziridination Using a Bifunctional Amino-Reagent: An Aza-Prilezhaev Reaction

Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents

Oxidative Addition, Transmetalation, and Reductive Elimination at a 2,2′-Bipyridyl-Ligated Gold Center

Branch-Selective Alkene Hydroarylation by Cooperative Destabilization: Iridium-Catalyzed ortho-Alkylation of Acetanilides

Pyrrolidines and Piperidines by Ligand‐Enabled Aza‐Heck Cyclizations and Cascades of N‐(Pentafluorobenzoyloxy)carbamates

Rhodacyclopentanones as Linchpins for the Atom Economical Assembly of Diverse Polyheterocycles

Modular Access to Substituted Azocanes via a Rhodium-Catalyzed Cycloaddition–Fragmentation Strategy

Reversible C–C Bond Activation Enables Stereocontrol in Rh-Catalyzed Carbonylative Cycloadditions of Aminocyclopropanes

Carbonylative C−C Bond Activation of Electron‐Poor Cyclopropanes: Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides

Complex Polyheterocycles and the Stereochemical Reassignment of Pileamartine A via Aza-Heck Triggered Aryl C–H Functionalization Cascades

Dichotomous mechanistic behavior in Narasaka-Heck cyclizations: electron rich Pd-catalysts generate iminyl radicals

Nucleophilic Aromatic Substitution (SNAr) as an Approach to Challenging Carbohydrate–Aryl Ethers

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