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Mechanistic Studies on CysS - A Vitamin B 12 -Dependent Radical SAM Methyltransferase Involved in the Biosynthesis of the tert -Butyl Group of Cystobactamid

Journal of the American Chemical Society, 2020-06, Vol.142 (22), p.9944-9954

2020

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Alkylcysteine Sulfoxide C–S Monooxygenase Uses a Flavin-Dependent Pummerer Rearrangement

Journal of the American Chemical Society, 2023-06, Vol.145 (22), p.11933-11938

2023

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Dibenzothiophene Catabolism Proceeds via a Flavin-N5-oxide Intermediate

Journal of the American Chemical Society, 2016-05, Vol.138 (20), p.6424-6426

2016

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RutA-Catalyzed Oxidative Cleavage of the Uracil Amide Involves Formation of a Flavin-N5-oxide

Biochemistry (Easton), 2017-07, Vol.56 (29), p.3708-3709

2017

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Hexachlorobenzene Catabolism Involves a Nucleophilic Aromatic Substitution and Flavin-N5-Oxide Formation

Biochemistry (Easton), 2019-03, Vol.58 (9), p.1181-1183

2019

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Mechanistic Studies on CysS - A Vitamin B12-Dependent Radical SAM Methyltransferase Involved in the Biosynthesis of the tert-Butyl Group of Cystobactamid

Journal of the American Chemical Society, 2020-06, Vol.142 (22), p.9944-9954

2020

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The structural and biochemical foundations of thiamin biosynthesis

Annual review of biochemistry, 2009-01, Vol.78 (1), p.569-603

2009

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Menaquinone Biosynthesis: Formation of Aminofutalosine Requires a Unique Radical SAM Enzyme

Journal of the American Chemical Society, 2013-10, Vol.135 (41), p.15318-15321

2013

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Flavin-N5-oxide: A new, catalytic motif in flavoenzymology

Archives of biochemistry and biophysics, 2017-10, Vol.632, p.4-10

2017

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Mechanistic Studies on the Single-Turnover Yeast Thiamin Pyrimidine Synthase: Characterization of the Inactive Enzyme

Journal of the American Chemical Society, 2022-06, Vol.144 (24), p.10711-10717

2022

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Radical SAM Enzyme HydE Generates Adenosylated Fe(I) Intermediates En Route to the [FeFe]-Hydrogenase Catalytic H-Cluster

Journal of the American Chemical Society, 2020-06, Vol.142 (24), p.10841-10848

2020

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Tryptophan Lyase (NosL): A Cornucopia of 5′-Deoxyadenosyl Radical Mediated Transformations

Journal of the American Chemical Society, 2016-12, Vol.138 (50), p.16184-16187

2016

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Biosynthesis of Branched Alkoxy Groups: Iterative Methyl Group Alkylation by a Cobalamin-Dependent Radical SAM Enzyme

Journal of the American Chemical Society, 2017-02, Vol.139 (5), p.1742-1745

2017

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Biochemistry: Origin of a key player in methane biosynthesis

Nature (London), 2017-03, Vol.543 (7643), p.49-50

Begley, Tadhg P

2017

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Mechanistic Studies on Tryptophan Lyase (NosL): Identification of Cyanide as a Reaction Product

Journal of the American Chemical Society, 2018-01, Vol.140 (2), p.542-545

2018

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Oxidative Dearomatization of PLP in Thiamin Pyrimidine Biosynthesis in Candida albicans

Journal of the American Chemical Society, 2023-03, Vol.145 (8), p.4421-4430

2023

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Novel enzymology in futalosine-dependent menaquinone biosynthesis

Current opinion in chemical biology, 2018-12, Vol.47, p.134-141

2018

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Cysteine Dealkylation in Bacillus subtilis by a Novel Flavin-Dependent Monooxygenase

Biochemistry (Easton), 2022-06, Vol.61 (11), p.952-955

2022

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Anaerobic biosynthesis of the lower ligand of vitamin B12

Proceedings of the National Academy of Sciences - PNAS, 2015-08, Vol.112 (34), p.10792-10797

2015

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Aminofutalosine Synthase: Evidence for Captodative and Aryl Radical Intermediates Using β‑Scission and SRN1 Trapping Reactions

Journal of the American Chemical Society, 2017-08, Vol.139 (32), p.10952-10955

2017

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Menaquinone Biosynthesis: New Strategies to Trap Radical Intermediates in the MqnE-Catalyzed Reaction

Biochemistry (Easton), 2021-06, Vol.60 (21), p.1642-1646

2021

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Biosynthetic Versatility and Coordinated Action of 5′-Deoxyadenosyl Radicals in Deazaflavin Biosynthesis

Journal of the American Chemical Society, 2015-04, Vol.137 (16), p.5406-5413

2015

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Saccharomyces cerevisiae THI4p is a suicide thiamine thiazole synthase

Nature (London), 2011-10, Vol.478 (7370), p.542-546

2011

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Menaquinone Biosynthesis: The Mechanism of 5,8-Dihydroxy-2-naphthoate Synthase (MqnD)

Biochemistry (Easton), 2021-06, Vol.60 (25), p.1947-1951

2021

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Radiosynthesis of 5-[18F]Fluoro-1,2,3-triazoles through Aqueous Iodine–[18F]Fluorine Exchange Reaction

Molecules (Basel, Switzerland), 2021-09, Vol.26 (18), p.5522

2021

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Mechanistic Studies on CysS - A Vitamin B 12 -Dependent Radical SAM Methyltransferase Involved in the Biosynthesis of the tert -Butyl Group of Cystobactamid

Alkylcysteine Sulfoxide C–S Monooxygenase Uses a Flavin-Dependent Pummerer Rearrangement

Dibenzothiophene Catabolism Proceeds via a Flavin-N5-oxide Intermediate

RutA-Catalyzed Oxidative Cleavage of the Uracil Amide Involves Formation of a Flavin-N5-oxide

Hexachlorobenzene Catabolism Involves a Nucleophilic Aromatic Substitution and Flavin-N5-Oxide Formation

Mechanistic Studies on CysS - A Vitamin B12-Dependent Radical SAM Methyltransferase Involved in the Biosynthesis of the tert-Butyl Group of Cystobactamid

The structural and biochemical foundations of thiamin biosynthesis

Menaquinone Biosynthesis: Formation of Aminofutalosine Requires a Unique Radical SAM Enzyme

Flavin-N5-oxide: A new, catalytic motif in flavoenzymology

Mechanistic Studies on the Single-Turnover Yeast Thiamin Pyrimidine Synthase: Characterization of the Inactive Enzyme

Radical SAM Enzyme HydE Generates Adenosylated Fe(I) Intermediates En Route to the [FeFe]-Hydrogenase Catalytic H-Cluster

Tryptophan Lyase (NosL): A Cornucopia of 5′-Deoxyadenosyl Radical Mediated Transformations

Biosynthesis of Branched Alkoxy Groups: Iterative Methyl Group Alkylation by a Cobalamin-Dependent Radical SAM Enzyme

Biochemistry: Origin of a key player in methane biosynthesis

Mechanistic Studies on Tryptophan Lyase (NosL): Identification of Cyanide as a Reaction Product

Oxidative Dearomatization of PLP in Thiamin Pyrimidine Biosynthesis in Candida albicans

Novel enzymology in futalosine-dependent menaquinone biosynthesis

Cysteine Dealkylation in Bacillus subtilis by a Novel Flavin-Dependent Monooxygenase

Anaerobic biosynthesis of the lower ligand of vitamin B12

Aminofutalosine Synthase: Evidence for Captodative and Aryl Radical Intermediates Using β‑Scission and SRN1 Trapping Reactions

Menaquinone Biosynthesis: New Strategies to Trap Radical Intermediates in the MqnE-Catalyzed Reaction

Biosynthetic Versatility and Coordinated Action of 5′-Deoxyadenosyl Radicals in Deazaflavin Biosynthesis

Saccharomyces cerevisiae THI4p is a suicide thiamine thiazole synthase

Menaquinone Biosynthesis: The Mechanism of 5,8-Dihydroxy-2-naphthoate Synthase (MqnD)

Radiosynthesis of 5-[18F]Fluoro-1,2,3-triazoles through Aqueous Iodine–[18F]Fluorine Exchange Reaction

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