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Beyond Thermodynamic Acidity: A Perspective on the Complex-Induced Proximity Effect (CIPE) in Deprotonation Reactions

Angewandte Chemie (International ed.), 2004-04, Vol.43 (17), p.2206-2225

2004

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Dynamic Thermodynamic Resolution: Advantage by Separation of Equilibration and Resolution

Accounts of chemical research, 2009-02, Vol.42 (2), p.224-234

2009

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Asymmetric Synthesis of 4,5,6- and 3,4,5,6-Substituted Azepanes by a Highly Diastereoselective and Enantioselective Lithiation−Conjugate Addition Sequence

Journal of the American Chemical Society, 2006-02, Vol.128 (7), p.2178-2179

2006

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Regioselective, Diastereoselective, and Enantioselective Lithiation−Substitution Sequences: Reaction Pathways and Synthetic Applications

Accounts of chemical research, 1996-11, Vol.29 (11), p.552-560

1996

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Asymmetric Syntheses of Fused Bicyclic Lactams

Journal of organic chemistry, 2001-12, Vol.66 (26), p.9056-9062

2001

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The Endocyclic Restriction Test: The Geometries of Nucleophilic Substitutions at Sulfur(VI) and Sulfur(II)

Journal of organic chemistry, 2008-12, Vol.73 (24), p.9627-9632

2008

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Highly Diastereoselective and Enantioselective Carbon−Carbon Bond Formations in Conjugate Additions of Lithiated N-Boc Allylamines to Nitroalkenes: Enantioselective Synthesis of 3,4- and 3,4,5-Substituted Piperidines Including (−)-Paroxetine

Journal of the American Chemical Society, 2001-02, Vol.123 (5), p.1004-1005

2001

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Asymmetric Carbon−Carbon Bond Formations in Conjugate Additions of Lithiated N-Boc Allylic and Benzylic Amines to Nitroalkenes: Enantioselective Synthesis of Substituted Piperidines, Pyrrolidines, and Pyrimidinones

Journal of the American Chemical Society, 2002-10, Vol.124 (39), p.11689-11698

2002

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Dynamic Thermodynamic Resolution: Control of Enantioselectivity through Diastereomeric Equilibration

Accounts of chemical research, 2000-10, Vol.33 (10), p.715-727

2000

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An Experimental and Computational Investigation of the Enantioselective Deprotonation of Boc-piperidine

Journal of the American Chemical Society, 2002-03, Vol.124 (9), p.1889-1896

2002

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alpha.-Lithioamine synthetic equivalents: syntheses of diastereoisomers from Boc derivatives of cyclic amines

Journal of organic chemistry, 1993-02, Vol.58 (5), p.1109-1117

1993

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Enantioselective Syntheses of 2-Alkyl- and 2,6-Dialkylpiperidine Alkaloids: Preparations of the Hydrochlorides of (−)-Coniine, (−)-Solenopsin A, and (−)-Dihydropinidine

Organic letters, 2000-01, Vol.2 (2), p.155-158

2000

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Complex Induced Proximity Effects: Enantioselective Syntheses Based on Asymmetric Deprotonations of N-Boc-pyrrolidines

Journal of the American Chemical Society, 1994-04, Vol.116 (8), p.3231-3239

1994

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Asymmetric Deprotonation by BuLi/(−)-Sparteine: Convenient and Highly Enantioselective Syntheses of (S)-2-Aryl-Boc-Pyrrolidines

Journal of the American Chemical Society, 1996-01, Vol.118 (4), p.715-721

1996

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Complex-Induced Proximity Effects in Directed Lithiations: Analysis of Intra- and Intermolecular Kinetic Isotope Effects in Directed Aryl and Benzylic Lithiations

Journal of the American Chemical Society, 1999-08, Vol.121 (33), p.7553-7558

1999

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Kinetics and Mechanism of the (−)-Sparteine-Mediated Deprotonation of (E)-N-Boc-N-(p-methoxyphenyl)-3-cyclohexylallylamine

Journal of the American Chemical Society, 2001-05, Vol.123 (21), p.4919-4927

2001

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A Mechanistic and Structural Investigation of the (−)-Sparteine Mediated Asymmetric Benzylic Lithiation Substitution Reactions of N-Boc-N-(p-methoxyphenyl)benzylamine

Journal of the American Chemical Society, 1997-12, Vol.119 (48), p.11561-11570

1997

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Mechanism of Oxygen Transfer in the Epoxidation of an Olefin by Molecular Oxygen in the Presence of an Aldehyde

Organic letters, 2000-02, Vol.2 (3), p.357-360

2000

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Temperature- and Electrophile-Dependent Stereocontrol: A Structural and Mechanistic Investigation of (−)-Sparteine-Mediated Asymmetric Lithiation−Substitution Sequences of N-Boc-N-(p-Methoxyphenyl)cinnamylamine

Journal of the American Chemical Society, 1999-10, Vol.121 (41), p.9522-9530

1999

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Ligand Control and Asymmetric Michael Reactions of Enantioenriched Configurationally Stable N-Boc Anilino Benzylic and Allylic Organolithium Species

Journal of the American Chemical Society, 1997-10, Vol.119 (43), p.10537-10538

1997

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Asymmetric Syntheses of N-Boc 2-Substituted Pyrrolidines and Piperidines by Intramolecular Cyclization

Journal of organic chemistry, 1999-02, Vol.64 (4), p.1160-1165

1999

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Asymmetric Syntheses of Fused Bicyclic Compounds by Conjugate Additions of Allylic Organolithium Species to Activated Olefins and Subsequent Cyclizations

Organic letters, 2001-03, Vol.3 (5), p.711-714

2001

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Asymmetric Substitutions: High and Opposite Enantioselective Alkylations of a Racemic Organolithium Intermediate in the Presence of (-)-Sparteine

Journal of the American Chemical Society, 1994-10, Vol.116 (21), p.9755-9756

1994

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Asymmetric deprotonation of N,N-dihexyl-1-naphthamides to provide atropisomers of N,N-dihexyl-2-alkyl-1-naphthamides

Tetrahedron letters, 1996-04, Vol.37 (17), p.2899-2902

1996

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Pathways for Stereoinformation Transfer: Enhanced Enantioselectivity via Diastereomeric Recycling of Organolithium/(−)-Sparteine Complexes

Journal of organic chemistry, 1996-08, Vol.61 (17), p.5718-5719

1996

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Beyond Thermodynamic Acidity: A Perspective on the Complex-Induced Proximity Effect (CIPE) in Deprotonation Reactions

Dynamic Thermodynamic Resolution: Advantage by Separation of Equilibration and Resolution

Asymmetric Synthesis of 4,5,6- and 3,4,5,6-Substituted Azepanes by a Highly Diastereoselective and Enantioselective Lithiation−Conjugate Addition Sequence

Regioselective, Diastereoselective, and Enantioselective Lithiation−Substitution Sequences: Reaction Pathways and Synthetic Applications

Asymmetric Syntheses of Fused Bicyclic Lactams

The Endocyclic Restriction Test: The Geometries of Nucleophilic Substitutions at Sulfur(VI) and Sulfur(II)

Highly Diastereoselective and Enantioselective Carbon−Carbon Bond Formations in Conjugate Additions of Lithiated N-Boc Allylamines to Nitroalkenes: Enantioselective Synthesis of 3,4- and 3,4,5-Substituted Piperidines Including (−)-Paroxetine

Asymmetric Carbon−Carbon Bond Formations in Conjugate Additions of Lithiated N-Boc Allylic and Benzylic Amines to Nitroalkenes: Enantioselective Synthesis of Substituted Piperidines, Pyrrolidines, and Pyrimidinones

Dynamic Thermodynamic Resolution: Control of Enantioselectivity through Diastereomeric Equilibration

An Experimental and Computational Investigation of the Enantioselective Deprotonation of Boc-piperidine

alpha.-Lithioamine synthetic equivalents: syntheses of diastereoisomers from Boc derivatives of cyclic amines

Enantioselective Syntheses of 2-Alkyl- and 2,6-Dialkylpiperidine Alkaloids: Preparations of the Hydrochlorides of (−)-Coniine, (−)-Solenopsin A, and (−)-Dihydropinidine

Complex Induced Proximity Effects: Enantioselective Syntheses Based on Asymmetric Deprotonations of N-Boc-pyrrolidines

Asymmetric Deprotonation by BuLi/(−)-Sparteine: Convenient and Highly Enantioselective Syntheses of (S)-2-Aryl-Boc-Pyrrolidines

Complex-Induced Proximity Effects in Directed Lithiations: Analysis of Intra- and Intermolecular Kinetic Isotope Effects in Directed Aryl and Benzylic Lithiations

Kinetics and Mechanism of the (−)-Sparteine-Mediated Deprotonation of (E)-N-Boc-N-(p-methoxyphenyl)-3-cyclohexylallylamine

A Mechanistic and Structural Investigation of the (−)-Sparteine Mediated Asymmetric Benzylic Lithiation Substitution Reactions of N-Boc-N-(p-methoxyphenyl)benzylamine

Mechanism of Oxygen Transfer in the Epoxidation of an Olefin by Molecular Oxygen in the Presence of an Aldehyde

Temperature- and Electrophile-Dependent Stereocontrol: A Structural and Mechanistic Investigation of (−)-Sparteine-Mediated Asymmetric Lithiation−Substitution Sequences of N-Boc-N-(p-Methoxyphenyl)cinnamylamine

Ligand Control and Asymmetric Michael Reactions of Enantioenriched Configurationally Stable N-Boc Anilino Benzylic and Allylic Organolithium Species

Asymmetric Syntheses of N-Boc 2-Substituted Pyrrolidines and Piperidines by Intramolecular Cyclization

Asymmetric Syntheses of Fused Bicyclic Compounds by Conjugate Additions of Allylic Organolithium Species to Activated Olefins and Subsequent Cyclizations

Asymmetric Substitutions: High and Opposite Enantioselective Alkylations of a Racemic Organolithium Intermediate in the Presence of (-)-Sparteine

Asymmetric deprotonation of N,N-dihexyl-1-naphthamides to provide atropisomers of N,N-dihexyl-2-alkyl-1-naphthamides

Pathways for Stereoinformation Transfer: Enhanced Enantioselectivity via Diastereomeric Recycling of Organolithium/(−)-Sparteine Complexes

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