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Multiple and Highly Selective Alkyne-Isonitrile C−C and C−N Couplings at Group 4 Metallocenes

Chemistry : a European journal, 2016-06, Vol.22 (27), p.9169-9180

2016

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Reactivity of a Seven-Membered Zirconacyclocumulene towards CN Multiple Bonds - Formation of Metallaheterocycles by Insertion of C≡N and C=N Groups

European journal of inorganic chemistry, 2014-11, Vol.2014 (31), p.5304-5310

2014

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The Titanocene Complex of Bis(trimethylsilyl)acetylene: Synthesis, Structure, and Chemistry

Organometallics, 2003-03, Vol.22 (5), p.884-900

2003

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Five-Membered Titana- and Zirconacyclocumulenes: Stable 1-Metallacyclopenta-2,3,4-trienes

Organometallics, 2005-02, Vol.24 (4), p.456-471

2005

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Room-temperature catalytic hydrodefluorination of pentafluoro-pyridine by zirconocene fluoro complexes and diisobutylaluminumhydride

Journal of molecular catalysis. A, Chemical, 2007-01, Vol.261 (2), p.184-189

2007

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Combination of Spectroscopic Methods: In Situ NMR and UV/Vis Measurements To Understand the Formation of Group 4 Metallacyclopentanes from the Corresponding Metallacyclopropenes

Journal of the American Chemical Society, 2009-04, Vol.131 (12), p.4463-4469

2009

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Formation of a 1-Zircona-2,5-disilacyclopent-3-yne: Coordination of 1,4-Disilabutatriene to Zirconocene

Angewandte Chemie (International ed.), 2010-04, Vol.49 (16), p.2937-2940

2010

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Si−H Bond Activation of Alkynylsilanes by Group 4 Metallocene Complexes

Journal of the American Chemical Society, 2010-03, Vol.132 (12), p.4369-4380

2010

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Crystal structure of bis-{μ2-[(2-imino-cyclo-pentyl-idene)methyl-idene]aza-nido-κ(2) N:N'}bis-[(η(5)-penta-methyl-cyclo-penta-dien-yl)zirconium(IV)] hexane monosolvate

Acta crystallographica. Section E, Crystallographic communications, 2015-12, Vol.71 (Pt 12), p.m219-m220

2015

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(Cyanido-κ C )(2,2-diphenylacetamido-κ 2 N , O )bis(η 5 -pentamethylcyclopentadienyl)zirconium(IV)

Acta crystallographica. Section E, Structure reports online, 2014-02, Vol.70 (2), p.m57-m57

2014

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Crystal structure of bis(η5-cyclopentadienyl)(1,4-di-tert-butylbuta-1-en-3-yn-1-yl)zirconium(IV) μ2-hydroxido-bis[tris(pentafluorophenyl)borate]

Acta crystallographica. Section E, Crystallographic communications, 2015-03, Vol.71 (Pt 3), p.m71-m72

2015

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Synthesis and crystallographic characterization of [2,2-bis(η 5 -pentamethylcyclopentadienyl)-3,4-bis(trimethylsilyl)-2-zirconafuran-5-one-κ O 5 ]triisobutylaluminium

Acta crystallographica. Section E, Crystallographic communications, 2018-04, Vol.74 (4), p.566-568

2018

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Crystal structure of di- n -butylbis( η 5 -pentamethylcyclopentadienyl)hafnium(IV)

Acta crystallographica. Section E, Crystallographic communications, 2015-02, Vol.71 (2), p.m19-m20

2015

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Crystal structure of bis(η 5 -cyclopentadienyl)(2,3-diethylbutane-1,4-diyl)hafnium(IV)

Acta crystallographica. Section E, Crystallographic communications, 2015-01, Vol.71 (1), p.m7-m7

2015

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Complexation of Bis(trimethylsilyl)acetylene by Decamethylhafnocene To Give the Hafnacyclopropene Cp2Hf(η2-Me3SiC2SiMe3): An Unusually Strong Metal−Alkyne Interaction

Organometallics, 2007-01, Vol.26 (2), p.247-249

2007

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Nitrile-Nitrile CC Coupling at Group 4 Metallocenes to Form 1-Metalla-2,5-diaza-cyclopenta-2,4-dienes: Synthesis and Reactivity

Angewandte Chemie (International ed.), 2013-10, Vol.52 (43), p.11396-11400

2013

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Reduction of 1,4-dichlorobut-2-yne by titanocene to a 1,2,3-butatriene. Formation of a 1-titanacyclopent-3-yne and a 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene

Chemical communications (Cambridge, England), 2004-09 (18), p.2074-2075

2004

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Ring-Opening Reactions of Tetrahydrofuran versus Alkyne Complexation by Group 4 Metallocene Complexes Leading to General Consequences for Synthesis and Reactions of Metallocene Complexes

Organometallics, 2007-06, Vol.26 (12), p.3000-3004

2007

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1-Titanacyclobuta-2,3-diene - an elusive four-membered cyclic allene

Chemical science (Cambridge), 2019-05, Vol.1 (2), p.5319-5325

2019

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Group 4 Metallocene Mediated Homo- and Heterocoupling of Heteroaromatic Nitriles

Organometallics, 2018-12, Vol.37 (23), p.4415-4423

2018

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Reactions of Group 4 Metallocenes with Monosubstituted Acetonitriles: Keteniminate Formation versus CC Coupling

Chemistry : a European journal, 2015-02, Vol.21 (8), p.3242-3248

2015

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Formation of Tri- and Tetranuclear Titanacycles through Decamethyltitanocene-Mediated Intermolecular C-C Coupling of Dinitriles

Angewandte Chemie (International ed.), 2015-04, Vol.54 (18), p.5523-5526

International ed. in English, 2015

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Visiting the Limits between a Highly Strained 1‐Zirconacyclobuta‐2,3‐diene and Chemically Robust Dizirconacyclooctatetraene

Chemistry : a European journal, 2018-04, Vol.24 (21), p.5667-5674

2018

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Reactions of rac-(ebthi)M(η2-Me3SiC2SiMe3) (M=Ti, Zr) with Aryl Nitriles

Chemistry : a European journal, 2014-09, Vol.20 (39), p.12595-12600

2014

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A general benzylic C–H activation and C–C coupling reaction of zirconocenes mediated by C–N bond cleavage in tert -butylisocyanide – unusual formation of iminoacyl complexes

Dalton transactions : an international journal of inorganic chemistry, 2019-11, Vol.48 (44), p.16525-16533

2019

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Multiple and Highly Selective Alkyne-Isonitrile C−C and C−N Couplings at Group 4 Metallocenes

Reactivity of a Seven-Membered Zirconacyclocumulene towards CN Multiple Bonds - Formation of Metallaheterocycles by Insertion of C≡N and C=N Groups

The Titanocene Complex of Bis(trimethylsilyl)acetylene: Synthesis, Structure, and Chemistry

Five-Membered Titana- and Zirconacyclocumulenes: Stable 1-Metallacyclopenta-2,3,4-trienes

Room-temperature catalytic hydrodefluorination of pentafluoro-pyridine by zirconocene fluoro complexes and diisobutylaluminumhydride

Combination of Spectroscopic Methods: In Situ NMR and UV/Vis Measurements To Understand the Formation of Group 4 Metallacyclopentanes from the Corresponding Metallacyclopropenes

Formation of a 1-Zircona-2,5-disilacyclopent-3-yne: Coordination of 1,4-Disilabutatriene to Zirconocene

Si−H Bond Activation of Alkynylsilanes by Group 4 Metallocene Complexes

Crystal structure of bis-{μ2-[(2-imino-cyclo-pentyl-idene)methyl-idene]aza-nido-κ(2) N:N'}bis-[(η(5)-penta-methyl-cyclo-penta-dien-yl)zirconium(IV)] hexane monosolvate

(Cyanido-κ C )(2,2-diphenylacetamido-κ 2 N , O )bis(η 5 -pentamethylcyclopentadienyl)zirconium(IV)

Crystal structure of bis(η5-cyclopentadienyl)(1,4-di-tert-butylbuta-1-en-3-yn-1-yl)zirconium(IV) μ2-hydroxido-bis[tris(pentafluorophenyl)borate]

Synthesis and crystallographic characterization of [2,2-bis(η 5 -pentamethylcyclopentadienyl)-3,4-bis(trimethylsilyl)-2-zirconafuran-5-one-κ O 5 ]triisobutylaluminium

Crystal structure of di- n -butylbis( η 5 -pentamethylcyclopentadienyl)hafnium(IV)

Crystal structure of bis(η 5 -cyclopentadienyl)(2,3-diethylbutane-1,4-diyl)hafnium(IV)

Complexation of Bis(trimethylsilyl)acetylene by Decamethylhafnocene To Give the Hafnacyclopropene Cp2Hf(η2-Me3SiC2SiMe3): An Unusually Strong Metal−Alkyne Interaction

Nitrile-Nitrile CC Coupling at Group 4 Metallocenes to Form 1-Metalla-2,5-diaza-cyclopenta-2,4-dienes: Synthesis and Reactivity

Reduction of 1,4-dichlorobut-2-yne by titanocene to a 1,2,3-butatriene. Formation of a 1-titanacyclopent-3-yne and a 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene

Ring-Opening Reactions of Tetrahydrofuran versus Alkyne Complexation by Group 4 Metallocene Complexes Leading to General Consequences for Synthesis and Reactions of Metallocene Complexes

1-Titanacyclobuta-2,3-diene - an elusive four-membered cyclic allene

Group 4 Metallocene Mediated Homo- and Heterocoupling of Heteroaromatic Nitriles

Reactions of Group 4 Metallocenes with Monosubstituted Acetonitriles: Keteniminate Formation versus CC Coupling

Formation of Tri- and Tetranuclear Titanacycles through Decamethyltitanocene-Mediated Intermolecular C-C Coupling of Dinitriles

Visiting the Limits between a Highly Strained 1‐Zirconacyclobuta‐2,3‐diene and Chemically Robust Dizirconacyclooctatetraene

Reactions of rac-(ebthi)M(η2-Me3SiC2SiMe3) (M=Ti, Zr) with Aryl Nitriles

A general benzylic C–H activation and C–C coupling reaction of zirconocenes mediated by C–N bond cleavage in tert -butylisocyanide – unusual formation of iminoacyl complexes

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