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Catalytic Enantioselective Synthesis of Acyclic Quaternary Centers: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Acyclic Enol Carbonates

Journal of the American Chemical Society, 2018-08, Vol.140 (32), p.10109-10112

2018

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Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N -acyl indole-derived enol carbonates

Chemical science (Cambridge), 2019-06, Vol.10 (23), p.5996-6000

2019

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Tailoring Panchromatic Absorption and Excited-State Dynamics of Tetrapyrrole–Chromophore (Bodipy, Rylene) ArraysInterplay of Orbital Mixing and Configuration Interaction

Journal of the American Chemical Society, 2017-12, Vol.139 (48), p.17547-17564

2017

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Panchromatic chromophore–tetrapyrrole light-harvesting arrays constructed from Bodipy, perylene, terrylene, porphyrin, chlorin, and bacteriochlorin building blocks

New journal of chemistry, 2016-01, Vol.40 (9), p.8032-8052

2016

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Panchromatic absorbers for solar light-harvesting

Chemical communications (Cambridge, England), 2014-12, Vol.50 (93), p.14512-14515

2014

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Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Acyclic α- N -Pyrrolyl/Indolyl Ketones

Organic letters, 2020-06, Vol.22 (11), p.4272-4275

2020

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Enantioselective γ‑Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement

Journal of the American Chemical Society, 2016-04, Vol.138 (16), p.5234-5237

2016

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Asymmetric Total Synthesis of Havellockate

Journal of the American Chemical Society, 2022-11, Vol.144 (44), p.20232-20236

2022

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Palladium‐Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Protected Benzoin‐Derived Enol Carbonates

Advanced synthesis & catalysis, 2020-01, Vol.362 (2), p.344-347

2020

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Global Diastereoconvergence in the Ireland–Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α‑Amino Acids

Journal of the American Chemical Society, 2020-12, Vol.142 (52), p.21938-21947

2020

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Enantioselective Pd-Catalyzed Decarboxylative Allylic Alkylation of Thiopyranones. Access to Acyclic, Stereogenic α‑Quaternary Ketones

Organic letters, 2017-10, Vol.19 (19), p.5007-5009

2017

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Palladium-catalyzed α,β-dehydrogenation of acyclic ester equivalents promoted by a novel electron deficient phosphinooxazoline ligand

Tetrahedron, 2019-08, Vol.75 (31), p.4104-4109

2019

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Stereospecific Overman Rearrangement of Substituted Cyclic Vinyl Bromides: Access to Fully Substituted α‑Amino Ketones

Organic letters, 2019-11, Vol.21 (22), p.8962-8965

2019

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Origin of Panchromaticity in Multichromophore–Tetrapyrrole Arrays

The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 2018-09, Vol.122 (36), p.7181-7201

2018

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Paley's watchmaker analogy and prebiotic synthetic chemistry in surfactant assemblies. Formaldehyde scavenging by pyrroles leading to porphyrins as a case study

Organic & biomolecular chemistry, 2015-10, Vol.13 (39), p.10025-10031

2015

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Tuning the Electronic Structure and Properties of Perylene–Porphyrin–Perylene Panchromatic Absorbers

The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 2016-09, Vol.120 (38), p.7434-7450

2016

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Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates† †Electronic supplementary information (ESI) available: Experimental procedures, NMR and IR spectra, SFC traces, X-ray crystallographic data. CCDC 1908785. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc01726g

Chemical science (Cambridge), 2019-05, Vol.10 (23), p.5996-6000

2019

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Paley's watchmaker analogy and prebiotic synthetic chemistry in surfactant assemblies. Formaldehyde scavenging by pyrroles leading to porphyrins as a case studyElectronic supplementary information (ESI) available: Further experimental information and data. See DOI: 10.1039/c5ob01409c

2015-09

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Development of Enantioselective Transition-Metal Catalyzed Allylic Alkylation Methodologies

Alexy, Eric J

2020

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Panchromatic chromophore-tetrapyrrole light-harvesting arrays constructed from Bodipy, perylene, terrylene, porphyrin, chlorin, and bacteriochlorin building blocksElectronic supplementary information (ESI) available: NMR spectra for all new compounds; MALDI-MS data and analytical SEC traces for all arrays and benchmarks. See DOI: 10.1039/c6nj01782g

2016-08

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Panchromatic absorbers for solar light-harvestingElectronic supplementary information (ESI) available: Complete synthesis and characterization of all arrays; spectroscopic methods for determination of excited-state lifetimes. See DOI: 10.1039/c4cc06853j

2014-10

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Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted -acyl indole-derived enol carbonates

Chemical science (Cambridge), 2019-06, Vol.1 (23), p.5996-6

2019

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ChemInform Abstract: Enantioselective [gamma]-Alkylation of [alpha],[beta]-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement

ChemInform, 2016-10, Vol.47 (43)

2016

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ChemInform Abstract: Enantioselective γ‐Alkylation of α,β‐Unsaturated Malonates and Ketoesters by a Sequential Ir‐Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement

ChemInform, 2016-10, Vol.47 (43), p.no-no

2016

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Effect of Torsemide vs Furosemide After Discharge on All-Cause Mortality in Patients Hospitalized With Heart Failure: The TRANSFORM-HF Randomized Clinical Trial

JAMA : the journal of the American Medical Association, 2023-01, Vol.329 (3), p.214

2023

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Catalytic Enantioselective Synthesis of Acyclic Quaternary Centers: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Acyclic Enol Carbonates

Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N -acyl indole-derived enol carbonates

Tailoring Panchromatic Absorption and Excited-State Dynamics of Tetrapyrrole–Chromophore (Bodipy, Rylene) ArraysInterplay of Orbital Mixing and Configuration Interaction

Panchromatic chromophore–tetrapyrrole light-harvesting arrays constructed from Bodipy, perylene, terrylene, porphyrin, chlorin, and bacteriochlorin building blocks

Panchromatic absorbers for solar light-harvesting

Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Acyclic α- N -Pyrrolyl/Indolyl Ketones

Enantioselective γ‑Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement

Asymmetric Total Synthesis of Havellockate

Palladium‐Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Protected Benzoin‐Derived Enol Carbonates

Global Diastereoconvergence in the Ireland–Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α‑Amino Acids

Enantioselective Pd-Catalyzed Decarboxylative Allylic Alkylation of Thiopyranones. Access to Acyclic, Stereogenic α‑Quaternary Ketones

Palladium-catalyzed α,β-dehydrogenation of acyclic ester equivalents promoted by a novel electron deficient phosphinooxazoline ligand

Stereospecific Overman Rearrangement of Substituted Cyclic Vinyl Bromides: Access to Fully Substituted α‑Amino Ketones

Origin of Panchromaticity in Multichromophore–Tetrapyrrole Arrays

Paley's watchmaker analogy and prebiotic synthetic chemistry in surfactant assemblies. Formaldehyde scavenging by pyrroles leading to porphyrins as a case study

Tuning the Electronic Structure and Properties of Perylene–Porphyrin–Perylene Panchromatic Absorbers

Paley's watchmaker analogy and prebiotic synthetic chemistry in surfactant assemblies. Formaldehyde scavenging by pyrroles leading to porphyrins as a case studyElectronic supplementary information (ESI) available: Further experimental information and data. See DOI: 10.1039/c5ob01409c

Development of Enantioselective Transition-Metal Catalyzed Allylic Alkylation Methodologies

Panchromatic absorbers for solar light-harvestingElectronic supplementary information (ESI) available: Complete synthesis and characterization of all arrays; spectroscopic methods for determination of excited-state lifetimes. See DOI: 10.1039/c4cc06853j

Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted -acyl indole-derived enol carbonates

ChemInform Abstract: Enantioselective [gamma]-Alkylation of [alpha],[beta]-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement

ChemInform Abstract: Enantioselective γ‐Alkylation of α,β‐Unsaturated Malonates and Ketoesters by a Sequential Ir‐Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement

Effect of Torsemide vs Furosemide After Discharge on All-Cause Mortality in Patients Hospitalized With Heart Failure: The TRANSFORM-HF Randomized Clinical Trial

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