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Copper-Catalyzed Asymmetric Synthesis

Alexandre Alexakis, Norbert Krause, Simon Woodward, Alexandre Alexakis, Norbert Krause, Simon Woodward

1, 2013

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Enantioselective Organocatalytic Fluorination-Induced Wagner-Meerwein Rearrangement

Angewandte Chemie International Edition, 2013-08, Vol.52 (35), p.9266-9270

International ed. in English, 2013

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Copper-Catalyzed Asymmetric Allylic Alkylation

European Journal of Organic Chemistry, 2008-08, Vol.2008 (22), p.3765-3780

2008

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Chiral amines as organocatalysts for asymmetric conjugate addition to nitroolefins and vinyl sulfones via enamine activation

Chemical communications (Cambridge, England), 2007-01 (30), p.3123-3135

2007

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Access to High Levels of Molecular Complexity by One-Pot Iridium/Enamine Asymmetric Catalysis

Angewandte Chemie (International ed.), 2011-03, Vol.50 (10), p.2354-2358

International ed. in English, 2011

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Formation of Contiguous Quaternary and Tertiary Stereocenters by Sequential Asymmetric Conjugate Addition of Grignard Reagents to 2-Substituted Enones and Mg-Enolate Trapping

Chemistry : a European journal, 2015-06, Vol.21 (23), p.8597-8606

2015

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Regiodivergent 1,4 versus 1,6 Asymmetric Copper-Catalyzed Conjugate Addition

Angewandte Chemie (International ed.), 2008-01, Vol.47 (47), p.9122-9124

2008

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Enantioselective Organocatalytic Iodination-Initiated Wagner–Meerwein Rearrangement

Organic letters, 2013-11, Vol.15 (22), p.5890-5893

2013

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Enantioselective Halogenative Semi-Pinacol Rearrangement: Extension of Substrate Scope and Mechanistic Investigations

Chemistry : a European journal, 2015-03, Vol.21 (14), p.5561-5583

2015

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Enantio- and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated Nitroolefins

Chemistry : a European journal, 2013-08, Vol.19 (34), p.11352-11363

2013

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Copper-Free Asymmetric Allylic Alkylation of Trisubstituted Cyclic Allyl Bromides Using Grignard Reagents

Angewandte Chemie International Edition, 2013-12, Vol.52 (51), p.13642-13646

International ed. in English, 2013

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Copper-Catalyzed Asymmetric Conjugate Addition of Aryl Aluminum Reagents to Trisubstituted Enones: Construction of Aryl-Substituted Quaternary Centers

Angewandte Chemie International Edition, 2008-10, Vol.47 (43), p.8211-8214

2008

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Diamine-Catalyzed Asymmetric Michael Additions of Aldehydes and Ketones to Nitrostyrene

Organic letters, 2002-10, Vol.4 (21), p.3611-3614

2002

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First Organocatalyzed Asymmetric Michael Addition of Aldehydes to Vinyl Sulfones

Organic letters, 2005-09, Vol.7 (20), p.4361-4364

2005

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Copper-Catalyzed Asymmetric Conjugate Addition of Trialkylaluminium Reagents to Trisubstituted Enones: Construction of Chiral Quaternary Centers

Chemistry : a European journal, 2007-01, Vol.13 (34), p.9647-9662

2007

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Enantioselective Copper-Catalyzed Conjugate Addition to Trisubstituted Cyclohexenones: Construction of Stereogenic Quaternary Centers

Angewandte Chemie International Edition, 2005-02, Vol.44 (9), p.1376-1378

2005

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Transition metal-free asymmetric and diastereoselective allylic alkylation using Grignard reagents: construction of vicinal stereogenic centers via kinetic resolution

Chemical science (Cambridge), 2014, Vol.5 (10), p.3803-3807

2014

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Copper-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents to Trisubstituted Enones. Construction of All-Carbon Quaternary Chiral Centers

Journal of the American Chemical Society, 2006-07, Vol.128 (26), p.8416-8417

2006

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Copper-Catalyzed Enantioselective Synthesis of Axially Chiral Allenes

Organic letters, 2012-12, Vol.14 (23), p.5880-5883

2012

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Formation of Quaternary Stereogenic Centers by Copper-Catalyzed Asymmetric Conjugate Addition Reactions of Alkenylaluminums to Trisubstituted Enones

Chemistry : a European journal, 2013-11, Vol.19 (45), p.15226-15239

2013

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Copper-Catalyzed Asymmetric 1,4-Addition of Alkenyl Alanes to N-Substituted-2-3-dehydro-4-piperidones

Organic letters, 2012-04, Vol.14 (7), p.1842-1845

2012

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Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters

Chemical communications (Cambridge, England), 2010-10, Vol.46 (39), p.7295-736

2010

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Catalytic Asymmetric Bromine-Lithium Exchange: A New Tool to Build Axial Chirality

Advanced synthesis & catalysis, 2010-10, Vol.352 (14-15), p.2611-2620

2010

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Organocatalytic Addition on 1,2-Bis(sulfone)vinylenes Leading to an Unprecedented Rearrangement

Chemistry : a European journal, 2009-10, Vol.15 (42), p.11109-11113

2009

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A Highly Effective Phosphoramidite Ligand for Asymmetric Allylic Substitution

Angewandte Chemie International Edition, 2004-04, Vol.43 (18), p.2426-2428

2004

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Copper-Catalyzed Asymmetric Synthesis

Enantioselective Organocatalytic Fluorination-Induced Wagner-Meerwein Rearrangement

Copper-Catalyzed Asymmetric Allylic Alkylation

Chiral amines as organocatalysts for asymmetric conjugate addition to nitroolefins and vinyl sulfones via enamine activation

Access to High Levels of Molecular Complexity by One-Pot Iridium/Enamine Asymmetric Catalysis

Formation of Contiguous Quaternary and Tertiary Stereocenters by Sequential Asymmetric Conjugate Addition of Grignard Reagents to 2-Substituted Enones and Mg-Enolate Trapping

Regiodivergent 1,4 versus 1,6 Asymmetric Copper-Catalyzed Conjugate Addition

Enantioselective Organocatalytic Iodination-Initiated Wagner–Meerwein Rearrangement

Enantioselective Halogenative Semi-Pinacol Rearrangement: Extension of Substrate Scope and Mechanistic Investigations

Enantio- and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated Nitroolefins

Copper-Free Asymmetric Allylic Alkylation of Trisubstituted Cyclic Allyl Bromides Using Grignard Reagents

Copper-Catalyzed Asymmetric Conjugate Addition of Aryl Aluminum Reagents to Trisubstituted Enones: Construction of Aryl-Substituted Quaternary Centers

Diamine-Catalyzed Asymmetric Michael Additions of Aldehydes and Ketones to Nitrostyrene

First Organocatalyzed Asymmetric Michael Addition of Aldehydes to Vinyl Sulfones

Copper-Catalyzed Asymmetric Conjugate Addition of Trialkylaluminium Reagents to Trisubstituted Enones: Construction of Chiral Quaternary Centers

Enantioselective Copper-Catalyzed Conjugate Addition to Trisubstituted Cyclohexenones: Construction of Stereogenic Quaternary Centers

Transition metal-free asymmetric and diastereoselective allylic alkylation using Grignard reagents: construction of vicinal stereogenic centers via kinetic resolution

Copper-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents to Trisubstituted Enones. Construction of All-Carbon Quaternary Chiral Centers

Copper-Catalyzed Enantioselective Synthesis of Axially Chiral Allenes

Formation of Quaternary Stereogenic Centers by Copper-Catalyzed Asymmetric Conjugate Addition Reactions of Alkenylaluminums to Trisubstituted Enones

Copper-Catalyzed Asymmetric 1,4-Addition of Alkenyl Alanes to N-Substituted-2-3-dehydro-4-piperidones

Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters

Catalytic Asymmetric Bromine-Lithium Exchange: A New Tool to Build Axial Chirality

Organocatalytic Addition on 1,2-Bis(sulfone)vinylenes Leading to an Unprecedented Rearrangement

A Highly Effective Phosphoramidite Ligand for Asymmetric Allylic Substitution

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