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Cyclizations of Alkynes: Revisiting Baldwin’s Rules for Ring Closure

Chemical reviews, 2011-11, Vol.111 (11), p.6513-6556

2011

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Anomeric effect, hyperconjugation and electrostatics: lessons from complexity in a classic stereoelectronic phenomenon

Chemical Society reviews, 2021-09, Vol.5 (18), p.1212-1252

2021

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Alkyne Origami: Folding Oligoalkynes into Polyaromatics

Accounts of chemical research, 2018-05, Vol.51 (5), p.1206-1219

2018

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Isonitriles as Stereoelectronic Chameleons: The Donor–Acceptor Dichotomy in Radical Additions

Journal of the American Chemical Society, 2018-10, Vol.140 (43), p.14272-14288

2018

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Finding the right path: Baldwin "Rules for Ring Closure" and stereoelectronic control of cyclizations

Chemical communications (Cambridge, England), 2013-01, Vol.49 (96), p.11246-1125

2013

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Stereoelectronic power of oxygen in control of chemical reactivity: the anomeric effect is not alone

Chemical Society reviews, 2021-09, Vol.5 (18), p.1253-1345

2021

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AIBN as an Electrophilic Reagent for Cyano Group Transfer

Journal of organic chemistry, 2023-02, Vol.88 (4), p.2648-2654

2023

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“Two Functional Groups in One Package”: Using Both Alkyne π‑Bonds in Cascade Transformations

Journal of organic chemistry, 2013-08, Vol.78 (16), p.7777-7784

2013

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Design principles of the use of alkynes in radical cascades

Nature reviews. Chemistry, 2023-06, Vol.7 (6), p.405-423

2023

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Antiaromaticity Gain Activates Tropone and Nonbenzenoid Aromatics as Normal-Electron-Demand Diels–Alder Dienes

Organic letters, 2020-09, Vol.22 (18), p.7083-7087

2020

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Stereoelectronic Chameleons: The Donor–Acceptor Dichotomy of Functional Groups

Chemistry : a European journal, 2017-03, Vol.23 (14), p.3225-3245

2017

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Hybridization Trends for Main Group Elements and Expanding the Bent’s Rule Beyond Carbon: More than Electronegativity

The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 2014-05, Vol.118 (20), p.3663-3677

2014

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Expanding Stereoelectronic Limits of endo-tet Cyclizations: Synthesis of Benz[b]azepines from Donor–Acceptor Cyclopropanes

Journal of the American Chemical Society, 2021-09, Vol.143 (34), p.13952-13961

2021

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Rules for Anionic and Radical Ring Closure of Alkynes

Journal of the American Chemical Society, 2011-08, Vol.133 (32), p.12608-12623

2011

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The Baldwin rules: revised and extended

Wiley interdisciplinary reviews. Computational molecular science, 2016-09, Vol.6 (5), p.487-514

2016

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Oxidative Photocyclization of Aromatic Schiff Bases in Synthesis of Phenanthridines and Other Aza-PAHs

International journal of molecular sciences, 2020-08, Vol.21 (16), p.5868

2020

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Alkynes as Synthetic Equivalents of Ketones and Aldehydes: A Hidden Entry into Carbonyl Chemistry

Molecules (Basel, Switzerland), 2019-03, Vol.24 (6), p.1036

2019

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Drawing Catalytic Power from Charge Separation: Stereoelectronic and Zwitterionic Assistance in the Au(I)-Catalyzed Bergman Cyclization

Journal of the American Chemical Society, 2017-03, Vol.139 (9), p.3406-3416

2017

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Concerted Reactions That Produce Diradicals and Zwitterions: Electronic, Steric, Conformational, and Kinetic Control of Cycloaromatization Processes

Chemical reviews, 2013-09, Vol.113 (9), p.7089-7129

2013

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Upconversion of Reductants

Angewandte Chemie International Edition, 2019-04, Vol.58 (17), p.5532-5550

International ed. in English, 2019

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Hole Catalysis of Cycloaddition Reactions: How to Activate and Control Oxidant Upconversion in Radical-Cationic Diels–Alder Reactions

Journal of the American Chemical Society, 2023-09, Vol.145 (35), p.19354-19367

2023

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Moderating Strain without Sacrificing Reactivity: Design of Fast and Tunable Noncatalyzed Alkyne–Azide Cycloadditions via Stereoelectronically Controlled Transition State Stabilization

Journal of the American Chemical Society, 2013-01, Vol.135 (4), p.1558-1569

2013

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Twofold π‑Extension of Polyarenes via Double and Triple Radical Alkyne peri-Annulations: Radical Cascades Converging on the Same Aromatic Core

Journal of the American Chemical Society, 2020-05, Vol.142 (18), p.8352-8366

2020

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Hyperconjugation

Wiley interdisciplinary reviews. Computational molecular science, 2019-03, Vol.9 (2), p.e1389-n/a

2019

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Chemistry: A Place to Publish Your Creative Multidisciplinary Research

Chemistry an international journal, 2023-12, Vol.5 (4), p.2677-2681

Alabugin, Igor V.

2023

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Cyclizations of Alkynes: Revisiting Baldwin’s Rules for Ring Closure

Anomeric effect, hyperconjugation and electrostatics: lessons from complexity in a classic stereoelectronic phenomenon

Alkyne Origami: Folding Oligoalkynes into Polyaromatics

Isonitriles as Stereoelectronic Chameleons: The Donor–Acceptor Dichotomy in Radical Additions

Finding the right path: Baldwin "Rules for Ring Closure" and stereoelectronic control of cyclizations

Stereoelectronic power of oxygen in control of chemical reactivity: the anomeric effect is not alone

AIBN as an Electrophilic Reagent for Cyano Group Transfer

“Two Functional Groups in One Package”: Using Both Alkyne π‑Bonds in Cascade Transformations

Design principles of the use of alkynes in radical cascades

Antiaromaticity Gain Activates Tropone and Nonbenzenoid Aromatics as Normal-Electron-Demand Diels–Alder Dienes

Stereoelectronic Chameleons: The Donor–Acceptor Dichotomy of Functional Groups

Hybridization Trends for Main Group Elements and Expanding the Bent’s Rule Beyond Carbon: More than Electronegativity

Expanding Stereoelectronic Limits of endo-tet Cyclizations: Synthesis of Benz[b]azepines from Donor–Acceptor Cyclopropanes

Rules for Anionic and Radical Ring Closure of Alkynes

The Baldwin rules: revised and extended

Oxidative Photocyclization of Aromatic Schiff Bases in Synthesis of Phenanthridines and Other Aza-PAHs

Alkynes as Synthetic Equivalents of Ketones and Aldehydes: A Hidden Entry into Carbonyl Chemistry

Drawing Catalytic Power from Charge Separation: Stereoelectronic and Zwitterionic Assistance in the Au(I)-Catalyzed Bergman Cyclization

Concerted Reactions That Produce Diradicals and Zwitterions: Electronic, Steric, Conformational, and Kinetic Control of Cycloaromatization Processes

Upconversion of Reductants

Hole Catalysis of Cycloaddition Reactions: How to Activate and Control Oxidant Upconversion in Radical-Cationic Diels–Alder Reactions

Moderating Strain without Sacrificing Reactivity: Design of Fast and Tunable Noncatalyzed Alkyne–Azide Cycloadditions via Stereoelectronically Controlled Transition State Stabilization

Twofold π‑Extension of Polyarenes via Double and Triple Radical Alkyne peri-Annulations: Radical Cascades Converging on the Same Aromatic Core

Hyperconjugation

Chemistry: A Place to Publish Your Creative Multidisciplinary Research

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