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Development of (Trifluoromethyl)zinc Reagent as Trifluoromethyl Anion and Difluorocarbene Sources

Organic letters, 2015-10, Vol.17 (20), p.4996-4999

2015

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Bench‐Stable Electrophilic Fluorinating Reagents for Highly Selective Mono‐ and Difluorination of Silyl Enol Ethers

Chemistry : a European journal, 2021-08, Vol.27 (46), p.11919-11925

2021

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Siladifluoromethylation and Difluoromethylation onto C(sp3), C(sp2), and C(sp) Centers Using Ruppert–Prakash Reagent and Fluoroform

Organic letters, 2016-07, Vol.18 (14), p.3354-3357

2016

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Stable but Reactive Perfluoroalkylzinc Reagents: Application in Ligand-Free Copper-Catalyzed Perfluoroalkylation of Aryl Iodides

Chemistry : a European journal, 2015-01, Vol.21 (1), p.96-100

2015

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Catalytic Asymmetric Synthesis of Tertiary Alcohols and Oxetenes Bearing a Difluoromethyl Group

Organic letters, 2015-10, Vol.17 (20), p.5108-5111

2015

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Direct Synthesis of a Trifluoromethyl Copper Reagent from Trifluoromethyl Ketones: Application to Trifluoromethylation

Chemistry : a European journal, 2013-12, Vol.19 (52), p.17692-17697

2013

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Umpolung of Fluoroform by CF Bond Activation: Direct Difluoromethylation of Lithium Enolates

Angewandte Chemie (International ed.), 2012-09, Vol.51 (38), p.9535-9538

2012

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Copper(I)-Catalyzed Asymmetric Desymmetrization: Synthesis of Five-Membered-Ring Compounds Containing All-Carbon Quaternary Stereocenters

Journal of the American Chemical Society, 2012-06, Vol.134 (25), p.10329-10332

2012

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Direct Synthesis of Pentafluoroethyl Copper from Pentafluoropropionate as an Economical C2F5 Source: Application to Pentafluoroethylation of Arylboronic Acids and Aryl Bromides

Organic letters, 2014-07, Vol.16 (13), p.3456-3459

2014

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Axial Chirality Control of Gold(biphep) Complexes by Chiral Anions: Application to Asymmetric Catalysis

Angewandte Chemie (International ed.), 2009-01, Vol.48 (33), p.6073-6077

2009

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Carbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations

Beilstein journal of organic chemistry, 2015-12, Vol.11 (1), p.2661-2670

2015

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Cyclic-Protected Hexafluoroacetone as an Air-Stable Liquid Reagent for Trifluoromethylations

European journal of organic chemistry, 2016-08, Vol.2016 (23), p.4099-4104

2016

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Catalytic Asymmetric Synthesis of Stable Oxetenes via Lewis Acid-Promoted [2 + 2] Cycloaddition

Journal of the American Chemical Society, 2011-12, Vol.133 (50), p.20092-20095

2011

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Synergistic Effect: Hydroalkoxylation of Allenes through Combination of Enantiopure BIPHEP-Gold Complexes and Chiral Anions

Advanced synthesis & catalysis, 2010-12, Vol.352 (18), p.3131-3135

2010

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Copper-catalyzed asymmetric methylation of fluoroalkylated pyruvates with dimethylzinc

Beilstein journal of organic chemistry, 2018-03, Vol.14 (1), p.576-582

2018

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Enantioselective Catalysis of Ketoester-ene Reaction of Silyl Enol Ether to Construct Quaternary Carbons by Chiral Dicationic Palladium(II) Complexes

Journal of the American Chemical Society, 2007-10, Vol.129 (43), p.12950-12951

2007

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Stable Axial Chirality in Metal Complexes Bearing 4,4′-Substituted BIPHEPs: Application to Catalytic Asymmetric Carbon–Carbon Bond-Forming Reactions

Bulletin of the Chemical Society of Japan, 2012-02, Vol.85 (2), p.201-208

2012

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Fragment-Based Reaction Discovery of Non-Ene-Type Carbon-Carbon Bond-Forming Reactions: Catalytic Asymmetric Oxetane Synthesis by Screening Olefinic Reactants without Allylic Hydrogen

Synlett, 2011-11, Vol.2011 (18), p.2719-2724

2011

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Rhodium-Catalyzed Hydrocarboxylation of Olefins with Carbon Dioxide

European journal of organic chemistry, 2016-07, Vol.2016 (19), p.3166-3170

2016

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Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide

Beilstein journal of organic chemistry, 2013-11, Vol.9 (1), p.2404-2409

2013

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Dynamic Chirality Control of tropos DPCB-digold Skeleton by Chiral Binaphthyldicarboxylate

Chemistry, an Asian journal, 2016-03, Vol.11 (6), p.823-827

2016

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Axial chirality control of tropos BIPHEP-Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation

Chemical communications (Cambridge, England), 2008-01 (41), p.5095-5097

2008

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Copper-Catalyzed Difluoromethylation of Aryl Iodides with (Difluoromethyl)zinc Reagent

Organic letters, 2016-08, Vol.18 (15), p.3686-3689

2016

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Palladium-Catalyzed Negishi Cross-Coupling Reaction of Aryl Halides with (Difluoromethyl)zinc Reagent

Organic letters, 2016-08, Vol.18 (15), p.3690-3693

2016

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Catalyst Self-Adaptation in Conjugate Addition to Nitroalkenes and Nitroacrylates: Instant Chirality Control in Diphenylmethane-Based Phosphoramidite Ligands

Journal of the American Chemical Society, 2008-04, Vol.130 (15), p.5012-5013

2008

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Development of (Trifluoromethyl)zinc Reagent as Trifluoromethyl Anion and Difluorocarbene Sources

Bench‐Stable Electrophilic Fluorinating Reagents for Highly Selective Mono‐ and Difluorination of Silyl Enol Ethers

Siladifluoromethylation and Difluoromethylation onto C(sp3), C(sp2), and C(sp) Centers Using Ruppert–Prakash Reagent and Fluoroform

Stable but Reactive Perfluoroalkylzinc Reagents: Application in Ligand-Free Copper-Catalyzed Perfluoroalkylation of Aryl Iodides

Catalytic Asymmetric Synthesis of Tertiary Alcohols and Oxetenes Bearing a Difluoromethyl Group

Direct Synthesis of a Trifluoromethyl Copper Reagent from Trifluoromethyl Ketones: Application to Trifluoromethylation

Umpolung of Fluoroform by CF Bond Activation: Direct Difluoromethylation of Lithium Enolates

Copper(I)-Catalyzed Asymmetric Desymmetrization: Synthesis of Five-Membered-Ring Compounds Containing All-Carbon Quaternary Stereocenters

Direct Synthesis of Pentafluoroethyl Copper from Pentafluoropropionate as an Economical C2F5 Source: Application to Pentafluoroethylation of Arylboronic Acids and Aryl Bromides

Axial Chirality Control of Gold(biphep) Complexes by Chiral Anions: Application to Asymmetric Catalysis

Carbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations

Cyclic-Protected Hexafluoroacetone as an Air-Stable Liquid Reagent for Trifluoromethylations

Catalytic Asymmetric Synthesis of Stable Oxetenes via Lewis Acid-Promoted [2 + 2] Cycloaddition

Synergistic Effect: Hydroalkoxylation of Allenes through Combination of Enantiopure BIPHEP-Gold Complexes and Chiral Anions

Copper-catalyzed asymmetric methylation of fluoroalkylated pyruvates with dimethylzinc

Enantioselective Catalysis of Ketoester-ene Reaction of Silyl Enol Ether to Construct Quaternary Carbons by Chiral Dicationic Palladium(II) Complexes

Stable Axial Chirality in Metal Complexes Bearing 4,4′-Substituted BIPHEPs: Application to Catalytic Asymmetric Carbon–Carbon Bond-Forming Reactions

Fragment-Based Reaction Discovery of Non-Ene-Type Carbon-Carbon Bond-Forming Reactions: Catalytic Asymmetric Oxetane Synthesis by Screening Olefinic Reactants without Allylic Hydrogen

Rhodium-Catalyzed Hydrocarboxylation of Olefins with Carbon Dioxide

Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide

Dynamic Chirality Control of tropos DPCB-digold Skeleton by Chiral Binaphthyldicarboxylate

Axial chirality control of tropos BIPHEP-Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation

Copper-Catalyzed Difluoromethylation of Aryl Iodides with (Difluoromethyl)zinc Reagent

Palladium-Catalyzed Negishi Cross-Coupling Reaction of Aryl Halides with (Difluoromethyl)zinc Reagent

Catalyst Self-Adaptation in Conjugate Addition to Nitroalkenes and Nitroacrylates: Instant Chirality Control in Diphenylmethane-Based Phosphoramidite Ligands

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