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Models of the iron-only hydrogenase: a comparison of chelate and bridge isomers of Fe2(CO)4{Ph2PN(R)PPh2}(μ-pdt) as proton-reduction catalysts

Dalton transactions : an international journal of inorganic chemistry, 2013-01, Vol.42 (19), p.6775-6792

2013

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Reactions of [Os3(CO)10(μ-H)2] and [Os3(CO)8{µ3-Ph2PCH2P(Ph)C6H4}(μ-H)] with pymS‒SnPh3 (pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand

Journal of chemical crystallography, 2021-06, Vol.51 (2), p.257-264

2021

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New Tetraruthenium Cluster from the Thermolysis of [Ru3(CO)10(μ-dppm)]: Crystal Structure of [HRu4(CO)9(μ3-PhPCH2PPh2) (μ3,η2:η1:η1-C6H4)]

Journal of chemical crystallography, 2024-03, Vol.54 (1), p.54-63

2024

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Synthesis, Structure, and Reactivity of Triosmium Clusters Bearing a Metalated Dialkyl-substituted Pyrazine Ligand

Journal of chemical crystallography, 2023-06, Vol.53 (2), p.197-208

2023

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Fluorinated models of the iron-only hydrogenase: An electrochemical study of the influence of an electron-withdrawing bridge on the proton reduction overpotential and catalyst stability

Journal of electroanalytical chemistry (Lausanne, Switzerland), 2013-08, Vol.703, p.14-22

2013

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Thermal transformations of tris(2-thienyl)phosphine (PTh3) at low-valent ruthenium cluster centers: Part I. Carbon–hydrogen, carbon–phosphorus and carbon–sulfur bond activation yielding Ru3(CO)8L{μ-Th2P(C4H2S)}(μ-H) (L = CO, PTh3), Ru3(CO)7(μ-PTh2)2(μ3-η2-C4H2S), Ru4(CO)9(μ-CO)2(μ4-η2-C4H2S)(μ4-PTh) and Ru5(CO)11(μ-PTh2)(μ4-η4-C4H3)(μ4-S)

Journal of organometallic chemistry, 2016-06, Vol.812, p.197-206

2016

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Trinuclear clusters containing 2-aminopyridinate/pyrimidinate ligands as electrocatalysts for proton reduction

Journal of organometallic chemistry, 2017-11, Vol.851, p.57-67

2017

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Hydrogenase Biomimetics with Redox-Active Ligands: Synthesis, Structure, and Electrocatalytic Studies on [Fe2(CO)4(κ2-dppn)(µ-edt)] (edt = Ethanedithiolate; dppn = 1,8-bis(Diphenylphosphino)Naphthalene)

Inorganics, 2018-12, Vol.6 (4), p.122

2018

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Synthesis of [Ru3(CO)9(μ-dppf){P(C4H3E)3}] (E = O, S) and thermally induced cyclometalation to form [(μ-H)Ru3(CO)7(μ-dppf){μ3-(C4H3E)2P(C4H2E)}] (dppf = 1,1′-bis(diphenylphosphino)ferrocene)

Journal of organometallic chemistry, 2014-06, Vol.760, p.231-239

2014

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Carbon−Phosphorus Bond Activation of Tri(2-thienyl)phosphine at Dirhenium and Dimanganese Centers

Organometallics, 2009-03, Vol.28 (5), p.1514-1523

2009

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Reactions of [HOs3(CO)10(µ-L)] (L = saccharinate, thiosaccharinate) with Ph3SnH and Ph3GeH

Journal of organometallic chemistry, 2021-06, Vol.942, p.121819, Article 121819

2021

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Reactivity of [Os3(CO)9(μ3-η1,κ1-C9H6N)(μ-H)] towards Ph3EH (E = Si, Ge, Sn): Synthesis and structure of triosmium clusters bearing a Ph3E ligand

Polyhedron, 2023-11, Vol.244, p.116591, Article 116591

2023

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Tri and hexaosmium clusters bearing saccharinate and diphosphine ligands: Synthesis, structure and fluxionality

Journal of organometallic chemistry, 2024-07, Vol.1015, p.123212, Article 123212

2024

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Hydrogenase biomimics containing redox-active ligands: Fe2(CO)4(μ-edt)(κ2-bpcd) with electron-acceptor 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) as a potential [Fe4–S4]H surrogate

Dalton transactions : an international journal of inorganic chemistry, 2019, Vol.48 (18), p.6051-6060

2019

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A comparative study of the electrochemical and proton-reduction behaviour of diphosphine-dithiolate complexes [M2(CO)4(μ-dppm){μ-S(CH2)nS}] (M = Fe, Ru; n = 2, 3)

Transition metal chemistry (Weinheim), 2017-10, Vol.42 (7), p.597-603

2017

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Biomimetics of the [FeFe]-hydrogenase enzyme: Identification of kinetically favoured apical-basal [Fe2(CO)4(μ-H){κ2-Ph2PC(Me2)PPh2}(μ-pdt)]+ as a proton-reduction catalyst

Journal of organometallic chemistry, 2016-06, Vol.812, p.247-258

2016

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New iron-sulphur clusters containing thiocarboxamide, amino-carbyne and amino-carbene ligands

Journal of organometallic chemistry, 2021-05, Vol.940, p.121772, Article 121772

2021

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Models of the iron-only hydrogenase enzyme: structure, electrochemistry and catalytic activity of Fe2(CO)3(μ-dithiolate)(μ,κ1,κ2-triphos)

Dalton transactions : an international journal of inorganic chemistry, 2019, Vol.48 (18), p.6174-6190

2019

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Triosmium cluster bearing a metalated dibenzylideneacetone ligand: Synthesis, structure, redox and electronic properties

Journal of organometallic chemistry, 2024-05, Vol.1011, p.123141, Article 123141

2024

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Biomimics of [FeFe]-hydrogenases incorporating redox-active ligands: synthesis, redox properties and spectroelectrochemistry of diiron-dithiolate complexes with ferrocenyl-diphosphines as Fe4S4 surrogates

Dalton transactions : an international journal of inorganic chemistry, 2022-06, Vol.51 (25), p.9748-9769

2022

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Ligand coordination in [Re2(CO)9(NCMe)] and [H3Re3(CO)11(NCMe)] by triphenylantimony: Reactivity studies and Sb–Ph bond cleavage to give new antimony-containing di- and trirhenium complexes

Journal of organometallic chemistry, 2021-11, Vol.953, p.122034, Article 122034

2021

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Facile Os-Os bond cleavage in the reactions of [Os3(CO)10(NCMe)2] and [Os3(CO)10(μ-H)2] with tetramethylthiuram disulfide (tmtd): Syntheses and crystal structures of new polynuclear osmium carbonyl complexes containing a dimethyldithiocarbamate ligand(s)

Journal of organometallic chemistry, 2020-04, Vol.911, p.121133, Article 121133

2020

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Synthesis, Molecular Structures and Electrochemical Investigations of [FeFe]‐Hydrogenase Biomimics [Fe2(CO)6‐n(EPh3)n(µ‐edt)] (E = P, As, Sb; n = 1, 2)

European journal of inorganic chemistry, 2019-11, Vol.2019 (42), p.4506-4515

2019

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Stereochemical control of the diphosphine and alkyne ligands in triruthenium clusters: The effect of reversible CO loss/addition on the ligand distribution in [Ru3(µ3,η2-PhCCPh){µ-Ph2PCH(Me)PPh2}(CO)7,8]

Journal of organometallic chemistry, 2022-06, Vol.968-969, p.122337, Article 122337

2022

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Electrocatalytic proton reduction by thiolate-capped triiron clusters [Fe3(CO)9(μ3-SR)(μ-H)] (R = iPr, tBu)

Inorganica Chimica Acta, 2018-08, Vol.480, p.47-53

2018

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Models of the iron-only hydrogenase: a comparison of chelate and bridge isomers of Fe2(CO)4{Ph2PN(R)PPh2}(μ-pdt) as proton-reduction catalysts

Reactions of [Os3(CO)10(μ-H)2] and [Os3(CO)8{µ3-Ph2PCH2P(Ph)C6H4}(μ-H)] with pymS‒SnPh3 (pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand

New Tetraruthenium Cluster from the Thermolysis of [Ru3(CO)10(μ-dppm)]: Crystal Structure of [HRu4(CO)9(μ3-PhPCH2PPh2) (μ3,η2:η1:η1-C6H4)]

Synthesis, Structure, and Reactivity of Triosmium Clusters Bearing a Metalated Dialkyl-substituted Pyrazine Ligand

Fluorinated models of the iron-only hydrogenase: An electrochemical study of the influence of an electron-withdrawing bridge on the proton reduction overpotential and catalyst stability

Trinuclear clusters containing 2-aminopyridinate/pyrimidinate ligands as electrocatalysts for proton reduction

Hydrogenase Biomimetics with Redox-Active Ligands: Synthesis, Structure, and Electrocatalytic Studies on [Fe2(CO)4(κ2-dppn)(µ-edt)] (edt = Ethanedithiolate; dppn = 1,8-bis(Diphenylphosphino)Naphthalene)

Synthesis of [Ru3(CO)9(μ-dppf){P(C4H3E)3}] (E = O, S) and thermally induced cyclometalation to form [(μ-H)Ru3(CO)7(μ-dppf){μ3-(C4H3E)2P(C4H2E)}] (dppf = 1,1′-bis(diphenylphosphino)ferrocene)

Carbon−Phosphorus Bond Activation of Tri(2-thienyl)phosphine at Dirhenium and Dimanganese Centers

Reactions of [HOs3(CO)10(µ-L)] (L = saccharinate, thiosaccharinate) with Ph3SnH and Ph3GeH

Reactivity of [Os3(CO)9(μ3-η1,κ1-C9H6N)(μ-H)] towards Ph3EH (E = Si, Ge, Sn): Synthesis and structure of triosmium clusters bearing a Ph3E ligand

Tri and hexaosmium clusters bearing saccharinate and diphosphine ligands: Synthesis, structure and fluxionality

Hydrogenase biomimics containing redox-active ligands: Fe2(CO)4(μ-edt)(κ2-bpcd) with electron-acceptor 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) as a potential [Fe4–S4]H surrogate

A comparative study of the electrochemical and proton-reduction behaviour of diphosphine-dithiolate complexes [M2(CO)4(μ-dppm){μ-S(CH2)nS}] (M = Fe, Ru; n = 2, 3)

Biomimetics of the [FeFe]-hydrogenase enzyme: Identification of kinetically favoured apical-basal [Fe2(CO)4(μ-H){κ2-Ph2PC(Me2)PPh2}(μ-pdt)]+ as a proton-reduction catalyst

New iron-sulphur clusters containing thiocarboxamide, amino-carbyne and amino-carbene ligands

Models of the iron-only hydrogenase enzyme: structure, electrochemistry and catalytic activity of Fe2(CO)3(μ-dithiolate)(μ,κ1,κ2-triphos)

Triosmium cluster bearing a metalated dibenzylideneacetone ligand: Synthesis, structure, redox and electronic properties

Biomimics of [FeFe]-hydrogenases incorporating redox-active ligands: synthesis, redox properties and spectroelectrochemistry of diiron-dithiolate complexes with ferrocenyl-diphosphines as Fe4S4 surrogates

Ligand coordination in [Re2(CO)9(NCMe)] and [H3Re3(CO)11(NCMe)] by triphenylantimony: Reactivity studies and Sb–Ph bond cleavage to give new antimony-containing di- and trirhenium complexes

Facile Os-Os bond cleavage in the reactions of [Os3(CO)10(NCMe)2] and [Os3(CO)10(μ-H)2] with tetramethylthiuram disulfide (tmtd): Syntheses and crystal structures of new polynuclear osmium carbonyl complexes containing a dimethyldithiocarbamate ligand(s)

Synthesis, Molecular Structures and Electrochemical Investigations of [FeFe]‐Hydrogenase Biomimics [Fe2(CO)6‐n(EPh3)n(µ‐edt)] (E = P, As, Sb; n = 1, 2)

Stereochemical control of the diphosphine and alkyne ligands in triruthenium clusters: The effect of reversible CO loss/addition on the ligand distribution in [Ru3(µ3,η2-PhCCPh){µ-Ph2PCH(Me)PPh2}(CO)7,8]

Electrocatalytic proton reduction by thiolate-capped triiron clusters [Fe3(CO)9(μ3-SR)(μ-H)] (R = iPr, tBu)

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