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Unsymmetrically Bridged Methyl Groups as Intermediates in the Transformation of Bridging Methylene to Bridging Acetyl Groups: Ligand Migrations and Migratory Insertions in Mixed Iridium/Ruthenium Complexes

Organometallics, 2009-06, Vol.28 (12), p.3407-3420

2009

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Alkyne/Methylene Coupling Reactions at Adjacent Rh/Os Centers: Stepwise Transformations from C 1 - through C 4 -Bridged Species

Organometallics, 2005-12, Vol.24 (26), p.6398-6410

2005

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Bridging Methylene and Methyl Complexes of Rhodium/Osmium: Influence of the Ancillary Ligands on the Methyl Binding Mode

Organometallics, 2005-12, Vol.24 (25), p.6194-6211

2005

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Dialkyl and Trialkyl Heterobinuclear Complexes of Rhodium and Iridium: Models for Adjacent-Metal Involvement in Bimetallic Catalysts

Organometallics, 2005-08, Vol.24 (18), p.4393-4405

2005

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Binuclear Activation of Cumulenes: Roles of the Adjacent Metals and the Cumulene Binding Mode in the Activation Process

Organometallics, 2005-07, Vol.24 (15), p.3711-3724

2005

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Bridging Methylene to Bridging Acyl Conversion in Heterobinuclear Rh/Ru Complexes: Models for Adjacent-Metal Involvement in Bimetallic Catalysts

Organometallics, 2004-08, Vol.23 (16), p.3873-3883

2004

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Olefin Binding in a Binuclear Iridium Complex as a Function of Fluorine Substitution: Ethylene to Tetrafluoroethylene

Organometallics, 2003-11, Vol.22 (23), p.4647-4657

2003

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Methylene-to-Acetyl Conversion in Heterobinuclear Rh/Os Complexes: Models for Oxygenate Formation by Bimetallic Fischer−Tropsch Catalysts

Organometallics, 2003-06, Vol.22 (13), p.2638-2651

2003

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Binuclear Fluorovinyl Complexes of Iridium: Transformation of an Iridium-Bound Trifluorovinyl Group into a trans-[Ir−C(F)C(F)CH3] Moiety

Organometallics, 2002-11, Vol.21 (24), p.5172-5181

2002

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Methylene-Bridged Complexes of Rhodium/Ruthenium as Models for Bimetallic Fischer−Tropsch Catalysts: Comparisons with the Rh/Os and Ir/Ru Analogues

Organometallics, 2002-07, Vol.21 (15), p.3228-3237

2002

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Methylene-Bridged Heterobinuclear Complexes of Iridium and Ruthenium: Models for Bimetallic Fischer−Tropsch Catalysts

Organometallics, 2001-01, Vol.20 (1), p.88-99

2001

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Double Activation of the Geminal Carbon−Hydrogen Bonds in 1,3-Butadiene by a Diiridium Complex

Organometallics, 2000-10, Vol.19 (22), p.4432-4434

2000

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Reactions of the Binuclear Complexes [MIr(CO)3(Ph2PCH2PPh2)2] (M = Rh, Ir) with Alkyl Halides: Dramatic Reactivity Differences as a Function of Metal Combination and Alkyl Halide

Organometallics, 2000-03, Vol.19 (5), p.854-864

2000

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An Unusual Example of Allyl-to-Alkynyl Migration in a Phenylacetylide-Bridged Heterobinuclear Complex of Rhodium and Iridium

Organometallics, 1999-12, Vol.18 (25), p.5330-5343

1999

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((Diaryl- and Dialkylphosphino)alkyl)cyclopentadienyl Ligands and Their Use in the Preparation of Heterobinuclear Ti/Mo and Zr/Mo Complexes

Organometallics, 1999-08, Vol.18 (17), p.3490-3501

1999

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Tetranuclear, Early−Late Heterobimetallic Complexes Bridged by the Bifunctional Phosphinoalkylcyclopentadienyl Ligands [Ph2P(CH2) n C5H4]- (n = 1, 2)

Organometallics, 1999-08, Vol.18 (17), p.3502-3510

1999

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Mixed-Metal Hydrocarbyl Complexes Involving the Rh/Mo and Rh/W Metal Combinations

Organometallics, 1999-05, Vol.18 (11), p.2177-2188

1999

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Heterobinuclear Methyl Complexes of Rhodium/Iridium: Reactivity with Nucleophiles and Subsequent Ligand Rearrangements

Organometallics, 1999-04, Vol.18 (9), p.1629-1640

1999

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Reactivity of the Heterobinuclear Phenylacetylide-Bridged A-Frame [RhIr(CO)2(μ-CCPh)(Ph2PCH2PPh2)2][O3SCF3] with Small Molecules

Organometallics, 1998-06, Vol.17 (12), p.2553-2566

1998

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Heterobinuclear Vinyl, Allyl, and Related Complexes of Rhodium/Osmium from Terminal Alkynes and Allenes, Vinyl to Carbene Transformations, and the Structures of [RhOs(C(CH3)CH2)(CO)3(Ph2PCH2PPh2)2] and [RhOs(C(CH3)C(CH3)2)(CH3)(CO)3(Ph2PCH2PPh2)2][CF3SO3]

Organometallics, 1997-05, Vol.16 (11), p.2297-2312

1997

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Binding of π-acid ligands and diiridium and rhodium-iridium iodo complexes, including rare examples of ethylene coordination in a frame compounds. Structure of [Ir2I2(CO)(μ-CO)(Ph2PCH2PPh2)2].CH2Cl2

Organometallics, 1991-08, Vol.10 (8), p.2708-2717

1991

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Diphosphine-bridged, heterobimetallic complexes containing iridium and osmium. Reversible ortho metalation of a bridging bis(diphenylphosphino)methane group at the iridium center promoted by the adjacent osmium center

Organometallics, 1991-05, Vol.10 (5), p.1297-1304

1991

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Low-valent, heterobinuclear complexes of rhodium and osmium. Influence of the coordinatively unsaturated rhodium center on the reactivity

Organometallics, 1991-01, Vol.10 (1), p.304-316

1991

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Binuclear oxidative additions of silanes to [Ir2(CO)3(Ph2PCH2PPh2)2] to yield silylene-bridged dihydride complexes

Organometallics, 1990-09, Vol.9 (9), p.2468-2478

1990

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Chemistry of (.mu.-dithio)bis(tricarbonyliron), an inorganic mimic of organic disulfides. 3. Reaction with low-valent metal compounds and some interesting isolobal analogies involving the products

Organometallics, 1989-01, Vol.8 (1), p.119-132

1989

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Unsymmetrically Bridged Methyl Groups as Intermediates in the Transformation of Bridging Methylene to Bridging Acetyl Groups: Ligand Migrations and Migratory Insertions in Mixed Iridium/Ruthenium Complexes

Alkyne/Methylene Coupling Reactions at Adjacent Rh/Os Centers: Stepwise Transformations from C 1 - through C 4 -Bridged Species

Bridging Methylene and Methyl Complexes of Rhodium/Osmium: Influence of the Ancillary Ligands on the Methyl Binding Mode

Dialkyl and Trialkyl Heterobinuclear Complexes of Rhodium and Iridium: Models for Adjacent-Metal Involvement in Bimetallic Catalysts

Binuclear Activation of Cumulenes: Roles of the Adjacent Metals and the Cumulene Binding Mode in the Activation Process

Bridging Methylene to Bridging Acyl Conversion in Heterobinuclear Rh/Ru Complexes: Models for Adjacent-Metal Involvement in Bimetallic Catalysts

Olefin Binding in a Binuclear Iridium Complex as a Function of Fluorine Substitution: Ethylene to Tetrafluoroethylene

Methylene-to-Acetyl Conversion in Heterobinuclear Rh/Os Complexes: Models for Oxygenate Formation by Bimetallic Fischer−Tropsch Catalysts

Binuclear Fluorovinyl Complexes of Iridium: Transformation of an Iridium-Bound Trifluorovinyl Group into a trans-[Ir−C(F)C(F)CH3] Moiety

Methylene-Bridged Complexes of Rhodium/Ruthenium as Models for Bimetallic Fischer−Tropsch Catalysts: Comparisons with the Rh/Os and Ir/Ru Analogues

Methylene-Bridged Heterobinuclear Complexes of Iridium and Ruthenium: Models for Bimetallic Fischer−Tropsch Catalysts

Double Activation of the Geminal Carbon−Hydrogen Bonds in 1,3-Butadiene by a Diiridium Complex

Reactions of the Binuclear Complexes [MIr(CO)3(Ph2PCH2PPh2)2] (M = Rh, Ir) with Alkyl Halides: Dramatic Reactivity Differences as a Function of Metal Combination and Alkyl Halide

An Unusual Example of Allyl-to-Alkynyl Migration in a Phenylacetylide-Bridged Heterobinuclear Complex of Rhodium and Iridium

((Diaryl- and Dialkylphosphino)alkyl)cyclopentadienyl Ligands and Their Use in the Preparation of Heterobinuclear Ti/Mo and Zr/Mo Complexes

Tetranuclear, Early−Late Heterobimetallic Complexes Bridged by the Bifunctional Phosphinoalkylcyclopentadienyl Ligands [Ph2P(CH2) n C5H4]- (n = 1, 2)

Mixed-Metal Hydrocarbyl Complexes Involving the Rh/Mo and Rh/W Metal Combinations

Heterobinuclear Methyl Complexes of Rhodium/Iridium: Reactivity with Nucleophiles and Subsequent Ligand Rearrangements

Reactivity of the Heterobinuclear Phenylacetylide-Bridged A-Frame [RhIr(CO)2(μ-CCPh)(Ph2PCH2PPh2)2][O3SCF3] with Small Molecules

Heterobinuclear Vinyl, Allyl, and Related Complexes of Rhodium/Osmium from Terminal Alkynes and Allenes, Vinyl to Carbene Transformations, and the Structures of [RhOs(C(CH3)CH2)(CO)3(Ph2PCH2PPh2)2] and [RhOs(C(CH3)C(CH3)2)(CH3)(CO)3(Ph2PCH2PPh2)2][CF3SO3]

Binding of π-acid ligands and diiridium and rhodium-iridium iodo complexes, including rare examples of ethylene coordination in a frame compounds. Structure of [Ir2I2(CO)(μ-CO)(Ph2PCH2PPh2)2].CH2Cl2

Diphosphine-bridged, heterobimetallic complexes containing iridium and osmium. Reversible ortho metalation of a bridging bis(diphenylphosphino)methane group at the iridium center promoted by the adjacent osmium center

Low-valent, heterobinuclear complexes of rhodium and osmium. Influence of the coordinatively unsaturated rhodium center on the reactivity

Binuclear oxidative additions of silanes to [Ir2(CO)3(Ph2PCH2PPh2)2] to yield silylene-bridged dihydride complexes

Chemistry of (.mu.-dithio)bis(tricarbonyliron), an inorganic mimic of organic disulfides. 3. Reaction with low-valent metal compounds and some interesting isolobal analogies involving the products

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