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Stable Two-Coordinate, Open-Shell (d1–d9) Transition Metal Complexes

Chemical reviews, 2012-06, Vol.112 (6), p.3482-3507

Power, Philip P

2012

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Main-group elements as transition metals

Nature (London), 2010-01, Vol.463 (7278), p.171-177

Power, Philip P

2010

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Addition of Hydrogen or Ammonia to a Low-Valent Group 13 Metal Species at 25 °C and 1 Atmosphere

Angewandte Chemie (International ed.), 2009-03, Vol.48 (11), p.2031-2034

2009

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Counterintuitive Interligand Angles in the Diaryls E{C6H3‑2,6-(C6H2‑2,4,6‑ i Pr3)2}2 (E = Ge, Sn, or Pb) and Related Species: The Role of London Dispersion Forces

Organometallics, 2018-07, Vol.37 (13), p.2075-2085

2018

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Structural Characterization, Infrared Spectroscopy, and Theoretical Calculations for B(C6F5)3-Stabilized Benzene-Ammonia and Benzene-Water Complexes

Angewandte Chemie (International ed.), 2011-11, Vol.50 (46), p.10965-10968

International ed. in English, 2011

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The Instability of Ni{N(SiMe3)2}2: A Fifty Year Old Transition Metal Silylamide Mystery

Angewandte Chemie (International ed.), 2015-10, Vol.54 (44), p.12914-12917

International ed. in English, 2015

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Addition of H2 to distannynes under ambient conditions

Chemical communications (Cambridge, England), 2008 (45), p.6042-6044

2008

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Synthesis and Characterization of the Homologous M−M Bonded Series Ar‘MMAr‘ (M = Zn, Cd, or Hg; Ar‘ = C6H3-2,6-(C6H3-2,6-Pr i 2)2) and Related Arylmetal Halides and Hydride Species

Journal of the American Chemical Society, 2007-09, Vol.129 (35), p.10847-10857

2007

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Synthesis and Characterization of the Non-Kekulé, Singlet Biradicaloid Ar‘Ge(μ-NSiMe3)2GeAr‘ (Ar‘ = 2,6-Dipp2C6H3, Dipp = 2,6-i-Pr2C6H3)

Journal of the American Chemical Society, 2004-06, Vol.126 (21), p.6510-6511

2004

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Beyond Steric Crowding: Dispersion Energy Donor Effects in Large Hydrocarbon Ligands

Accounts of chemical research, 2022-05, Vol.55 (9), p.1337-1348

2022

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Tl2[Aryl2P4]: A Thallium Complexed Diaryltetraphosphabutadienediide and its Two-Electron Oxidation to a Diaryltetraphosphabicyclobutane, Aryl2P4

Angewandte Chemie (International ed.), 2005-12, Vol.44 (47), p.7729-7733

2005

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Structures, Bonding, and Reaction Chemistry of the Neutral Organogallium(I) Compounds (GaAr) n (n = 1 or 2) (Ar = Terphenyl or Related Ligand): An Experimental Investigation of Ga−Ga Multiple Bonding

Journal of the American Chemical Society, 2003-03, Vol.125 (9), p.2667-2679

2003

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Synthesis and Characterization of [Ar′GaC(Ph)CH]2 and K2[Ar′GaC(Ph)CH]2⋅OEt2: From Digallene to Digallacyclohexadiene to Digallatabenzene

Angewandte Chemie International Edition, 2009-03, Vol.48 (11), p.2027-2030

2009

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π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements

Chemical reviews, 1999-12, Vol.99 (12), p.3463-3504

Power, Philip P

1999

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Solution Synthesis of Alkyl- and Alkyl/Alkoxy-Capped Silicon Nanoparticles via Oxidation of Mg2Si

Chemistry of materials, 2003-10, Vol.15 (21), p.4005-4011

2003

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Reactivity of Ar‘GeGeAr‘ (Ar‘ = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-iPr2) toward Alkynes: Isolation of a Stable Digermacyclobutadiene

Journal of the American Chemical Society, 2004-04, Vol.126 (16), p.5062-5063

2004

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Synthesis, Structure, and Spectroscopy of the Biscarboranyl Stannylenes (bc)Sn·THF and K2[(bc)Sn]2 (bc = 1,1′(ortho-Biscarborane)) and Dibiscarboranyl Ethene (bc)CHCH(bc)

Organometallics, 2023-07, Vol.42 (13), p.1649-1657

2023

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Hydrides, Halides, and Polymers: Some Unexpected Intermediates on the Routes to First-Row Transition Metal M{N(SiMe3)2} n (n = 2, 3) Complexes

Inorganic chemistry, 2021-12, Vol.60 (23), p.18503-18511

2021

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Correction to "Synthesis, Structure, and Spectroscopy of the Biscarboranyl Stannylenes (bc)Sn·THF and K2[(bc)Sn]2 (bc = 1,1'(ortho-Biscarborane)) and Dibiscarboranyl Ethene (bc)CH=CH(bc)"

Organometallics, 2023-08, Vol.42 (16), p.2319-2320

2023

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Synthesis, Structure, and Spectroscopy of the Biscarboranyl Stannylenes ( bc )Sn·THF and K 2 [( bc )Sn] 2 ( bc = 1,1'( ortho -Biscarborane)) and Dibiscarboranyl Ethene ( bc )CH=CH( bc )

Organometallics, 2023-07, Vol.42 (13), p.1649-1657

2023

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Designing a Solution-Stable Distannene: The Decisive Role of London Dispersion Effects in the Structure and Properties of {Sn(C6H2‑2,4,6-Cy3)2}2 (Cy = Cyclohexyl)

Journal of the American Chemical Society, 2021-12, Vol.143 (51), p.21478-21483

2021

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Isomeric Forms of Heavier Main Group Hydrides: Experimental and Theoretical Studies of the [Sn(Ar)H]2 (Ar = Terphenyl) System

Journal of the American Chemical Society, 2007-12, Vol.129 (51), p.16197-16208

2007

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Synthesis and Characterization of Quasi-Two-Coordinate Transition Metal Dithiolates M(SAr)2 (M = Cr, Mn, Fe, Co, Ni, Zn; Ar = C6H3-2,6(C6H2-2,4,6-Pri 3)2

Journal of the American Chemical Society, 2005-06, Vol.127 (23), p.8545-8552

2005

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Rearrangement of a Ge(II) aryloxide to yield a new Ge(II) oxo-cluster [Ge 6 (μ 3 -O) 4 (μ 2 -OC 6 H 2 -2,4,6-Cy 3 ) 4 ](NH 3 ) 0.5 : main group aryloxides of Ge(II), Sn(II), and Pb(II) [M(OC 6 H 2 -2,4,6-Cy 3 ) 2 ] 2 (Cy = cyclohexyl)

Dalton transactions : an international journal of inorganic chemistry, 2023-07, Vol.52 (28), p.9582-9589

2023

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Disproportionation of Sn(II){CH(SiMe 3 ) 2 } 2 to ˙Sn(III){CH(SiMe 3 ) 2 } 3 and ˙Sn(I){CH(SiMe 3 ) 2 }: characterization of the Sn(I) product

Chemical communications (Cambridge, England), 2023-05, Vol.59 (42), p.6399-6402

2023

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Stable Two-Coordinate, Open-Shell (d1–d9) Transition Metal Complexes

Main-group elements as transition metals

Addition of Hydrogen or Ammonia to a Low-Valent Group 13 Metal Species at 25 °C and 1 Atmosphere

Counterintuitive Interligand Angles in the Diaryls E{C6H3‑2,6-(C6H2‑2,4,6‑ i Pr3)2}2 (E = Ge, Sn, or Pb) and Related Species: The Role of London Dispersion Forces

Structural Characterization, Infrared Spectroscopy, and Theoretical Calculations for B(C6F5)3-Stabilized Benzene-Ammonia and Benzene-Water Complexes

The Instability of Ni{N(SiMe3)2}2: A Fifty Year Old Transition Metal Silylamide Mystery

Addition of H2 to distannynes under ambient conditions

Synthesis and Characterization of the Homologous M−M Bonded Series Ar‘MMAr‘ (M = Zn, Cd, or Hg; Ar‘ = C6H3-2,6-(C6H3-2,6-Pr i 2)2) and Related Arylmetal Halides and Hydride Species

Synthesis and Characterization of the Non-Kekulé, Singlet Biradicaloid Ar‘Ge(μ-NSiMe3)2GeAr‘ (Ar‘ = 2,6-Dipp2C6H3, Dipp = 2,6-i-Pr2C6H3)

Beyond Steric Crowding: Dispersion Energy Donor Effects in Large Hydrocarbon Ligands

Tl2[Aryl2P4]: A Thallium Complexed Diaryltetraphosphabutadienediide and its Two-Electron Oxidation to a Diaryltetraphosphabicyclobutane, Aryl2P4

Structures, Bonding, and Reaction Chemistry of the Neutral Organogallium(I) Compounds (GaAr) n (n = 1 or 2) (Ar = Terphenyl or Related Ligand): An Experimental Investigation of Ga−Ga Multiple Bonding

Synthesis and Characterization of [Ar′GaC(Ph)CH]2 and K2[Ar′GaC(Ph)CH]2⋅OEt2: From Digallene to Digallacyclohexadiene to Digallatabenzene

π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements

Solution Synthesis of Alkyl- and Alkyl/Alkoxy-Capped Silicon Nanoparticles via Oxidation of Mg2Si

Reactivity of Ar‘GeGeAr‘ (Ar‘ = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-iPr2) toward Alkynes: Isolation of a Stable Digermacyclobutadiene

Synthesis, Structure, and Spectroscopy of the Biscarboranyl Stannylenes (bc)Sn·THF and K2[(bc)Sn]2 (bc = 1,1′(ortho-Biscarborane)) and Dibiscarboranyl Ethene (bc)CHCH(bc)

Hydrides, Halides, and Polymers: Some Unexpected Intermediates on the Routes to First-Row Transition Metal M{N(SiMe3)2} n (n = 2, 3) Complexes

Correction to "Synthesis, Structure, and Spectroscopy of the Biscarboranyl Stannylenes (bc)Sn·THF and K2[(bc)Sn]2 (bc = 1,1'(ortho-Biscarborane)) and Dibiscarboranyl Ethene (bc)CH=CH(bc)"

Synthesis, Structure, and Spectroscopy of the Biscarboranyl Stannylenes ( bc )Sn·THF and K 2 [( bc )Sn] 2 ( bc = 1,1'( ortho -Biscarborane)) and Dibiscarboranyl Ethene ( bc )CH=CH( bc )

Designing a Solution-Stable Distannene: The Decisive Role of London Dispersion Effects in the Structure and Properties of {Sn(C6H2‑2,4,6-Cy3)2}2 (Cy = Cyclohexyl)

Isomeric Forms of Heavier Main Group Hydrides: Experimental and Theoretical Studies of the [Sn(Ar)H]2 (Ar = Terphenyl) System

Synthesis and Characterization of Quasi-Two-Coordinate Transition Metal Dithiolates M(SAr)2 (M = Cr, Mn, Fe, Co, Ni, Zn; Ar = C6H3-2,6(C6H2-2,4,6-Pri 3)2

Rearrangement of a Ge(II) aryloxide to yield a new Ge(II) oxo-cluster [Ge 6 (μ 3 -O) 4 (μ 2 -OC 6 H 2 -2,4,6-Cy 3 ) 4 ](NH 3 ) 0.5 : main group aryloxides of Ge(II), Sn(II), and Pb(II) [M(OC 6 H 2 -2,4,6-Cy 3 ) 2 ] 2 (Cy = cyclohexyl)

Disproportionation of Sn(II){CH(SiMe 3 ) 2 } 2 to ˙Sn(III){CH(SiMe 3 ) 2 } 3 and ˙Sn(I){CH(SiMe 3 ) 2 }: characterization of the Sn(I) product

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