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Trimethylsilyl‐Protected Alkynes as Selective Cross‐Coupling Partners in Titanium‐Catalyzed [2+2+1] Pyrrole Synthesis

Angewandte Chemie International Edition, 2018-05, Vol.57 (21), p.6090-6094

International ed. in English, 2018

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Mechanism of Ti-Catalyzed Oxidative Nitrene Transfer in [2 + 2 + 1] Pyrrole Synthesis from Alkynes and Azobenzene

Journal of the American Chemical Society, 2018-06, Vol.140 (23), p.7267-7281

2018

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Dative Directing Group Effects in Ti-Catalyzed [2+2+1] Pyrrole Synthesis: Chemo- and Regioselective Alkyne Heterocoupling

ACS catalysis, 2019-01, Vol.9 (1), p.216-223

2019

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Multicomponent Pyrazole Synthesis from Alkynes, Nitriles, and Titanium Imido Complexes via Oxidatively Induced N–N Bond Coupling

Journal of the American Chemical Society, 2020-03, Vol.142 (9), p.4390-4399

2020

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Modern applications of low-valent early transition metals in synthesis and catalysis

Nature reviews. Chemistry, 2019-01, Vol.3 (1), p.15-34

2019

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Oxidative nitrene transfer from azides to alkynes via Ti(ii)/Ti(iv) redox catalysis: formal [2+2+1] synthesis of pyrroles

Chemical communications (Cambridge, England), 2018, Vol.54 (50), p.6891-6894

2018

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Titanium redox catalysis: insights and applications of an earth-abundant base metal

Dalton transactions : an international journal of inorganic chemistry, 2017-09, Vol.46 (35), p.11522-11528

2017

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Synthesis of pentasubstituted 2-aryl pyrroles from boryl and stannyl alkynes via one-pot sequential Ti-catalyzed [2 + 2 + 1] pyrrole synthesis/cross coupling reactions

Chemical science (Cambridge), 2020-09, Vol.11 (37), p.10236-10242

2020

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Synthesis of Pyridylimido Complexes of Tantalum and Niobium by Reductive Cleavage of the NN Bond of 2,2′-Azopyridine: Precursors for Early–Late Heterobimetallic Complexes

Inorganic chemistry, 2019-11, Vol.58 (22), p.15155-15165

2019

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Ti-Catalyzed and -Mediated Oxidative Amination Reactions

Accounts of chemical research, 2021-09, Vol.54 (17), p.3476-3490

Tonks, Ian A

2021

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Reassessment of N 2 activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N 2 adduct is actually an arene adduct

Chemical science (Cambridge), 2022-11, Vol.13 (45), p.13330-13337

2022

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Ethylene polymerization catalyzed by bridging Ni/Zn heterobimetallics

Dalton transactions : an international journal of inorganic chemistry, 2017, Vol.46 (17), p.5513-5517

2017

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Structure and bonding of group 4-nickel heterobimetallics supported by 2-(diphenylphosphino)pyrrolide ligands

Dalton transactions : an international journal of inorganic chemistry, 2016-01, Vol.45 (24), p.9892-9901

2016

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Bis(imido)vanadium(V)-Catalyzed [2+2+1] Coupling of Alkynes and Azobenzenes Giving Multisubstituted Pyrroles

Journal of the American Chemical Society, 2019-03, Vol.141 (10), p.4194-4198

2019

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Catalytic formal [2+2+1] synthesis of pyrroles from alkynes and diazenes via Ti(II)/Ti(IV) redox catalysis

Nature chemistry, 2016-01, Vol.8 (1), p.63

2016

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Catalytic formal [2+2+1] synthesis of pyrroles from alkynes and diazenes via TiII/TiIV redox catalysis

Nature chemistry, 2016, Vol.8 (1), p.63-68

2016

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Tunable and recyclable polyesters from CO2 and butadiene

Nature chemistry, 2022-08, Vol.14 (8), p.877-883

2022

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3-Ethyl-6-vinyltetrahydro-2H-pyran-2-one (EVP): a versatile CO2-derived lactone platform for polymer synthesis

Chemical communications (Cambridge, England), 2022-08, Vol.58 (69), p.9586-9593

2022

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In Situ Catalyst Generation and Benchtop-Compatible Entry Points for TiII/TiIV Redox Catalytic Reactions

Organometallics, 2018-01, Vol.37 (23), p.4439-4445

2018

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Bonding and Reactivity of d 0 Transition Metal Imido Complexes Encoded in Their 15 N NMR Signatures

Journal of the American Chemical Society, 2024-04, Vol.146 (14), p.9860-9870

2024

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Mechanistic study of pyrazole synthesis via oxidation-induced N-N coupling of diazatitanacycles

Dalton transactions : an international journal of inorganic chemistry, 2024-06, Vol.53 (22), p.9510-9515

2024

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Ti-Catalyzed Multicomponent Synthesis of Pyrroles Using Allene Coupling Partners

Organometallics, 2023-07, Vol.42 (13), p.1459-1464

2023

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Reactivity of terminal imido complexes of group 4–6 metals: Stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules

Coordination chemistry reviews, 2020-03, Vol.407, p.213118, Article 213118

2020

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Trimethylsilyl‐Protected Alkynes as Selective Cross‐Coupling Partners in Titanium‐Catalyzed [2+2+1] Pyrrole Synthesis

Angewandte Chemie, 2018-05, Vol.130 (21), p.6198-6202

2018

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Evaluation of Tungsten Catalysis among Early Transition Metals for N‑Aryl-2,3,4,5-tetraarylpyrrole Synthesis: Modular Access to N‑Doped π‑Conjugated Material Precursors

Inorganic chemistry, 2024-02, Vol.63 (6), p.3037-3046

2024

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Trimethylsilyl‐Protected Alkynes as Selective Cross‐Coupling Partners in Titanium‐Catalyzed [2+2+1] Pyrrole Synthesis

Mechanism of Ti-Catalyzed Oxidative Nitrene Transfer in [2 + 2 + 1] Pyrrole Synthesis from Alkynes and Azobenzene

Dative Directing Group Effects in Ti-Catalyzed [2+2+1] Pyrrole Synthesis: Chemo- and Regioselective Alkyne Heterocoupling

Multicomponent Pyrazole Synthesis from Alkynes, Nitriles, and Titanium Imido Complexes via Oxidatively Induced N–N Bond Coupling

Modern applications of low-valent early transition metals in synthesis and catalysis

Oxidative nitrene transfer from azides to alkynes via Ti(ii)/Ti(iv) redox catalysis: formal [2+2+1] synthesis of pyrroles

Titanium redox catalysis: insights and applications of an earth-abundant base metal

Synthesis of pentasubstituted 2-aryl pyrroles from boryl and stannyl alkynes via one-pot sequential Ti-catalyzed [2 + 2 + 1] pyrrole synthesis/cross coupling reactions

Synthesis of Pyridylimido Complexes of Tantalum and Niobium by Reductive Cleavage of the NN Bond of 2,2′-Azopyridine: Precursors for Early–Late Heterobimetallic Complexes

Ti-Catalyzed and -Mediated Oxidative Amination Reactions

Reassessment of N 2 activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N 2 adduct is actually an arene adduct

Ethylene polymerization catalyzed by bridging Ni/Zn heterobimetallics

Structure and bonding of group 4-nickel heterobimetallics supported by 2-(diphenylphosphino)pyrrolide ligands

Bis(imido)vanadium(V)-Catalyzed [2+2+1] Coupling of Alkynes and Azobenzenes Giving Multisubstituted Pyrroles

Catalytic formal [2+2+1] synthesis of pyrroles from alkynes and diazenes via Ti(II)/Ti(IV) redox catalysis

Catalytic formal [2+2+1] synthesis of pyrroles from alkynes and diazenes via TiII/TiIV redox catalysis

Tunable and recyclable polyesters from CO2 and butadiene

3-Ethyl-6-vinyltetrahydro-2H-pyran-2-one (EVP): a versatile CO2-derived lactone platform for polymer synthesis

In Situ Catalyst Generation and Benchtop-Compatible Entry Points for TiII/TiIV Redox Catalytic Reactions

Bonding and Reactivity of d 0 Transition Metal Imido Complexes Encoded in Their 15 N NMR Signatures

Mechanistic study of pyrazole synthesis via oxidation-induced N-N coupling of diazatitanacycles

Ti-Catalyzed Multicomponent Synthesis of Pyrroles Using Allene Coupling Partners

Reactivity of terminal imido complexes of group 4–6 metals: Stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules

Trimethylsilyl‐Protected Alkynes as Selective Cross‐Coupling Partners in Titanium‐Catalyzed [2+2+1] Pyrrole Synthesis

Evaluation of Tungsten Catalysis among Early Transition Metals for N‑Aryl-2,3,4,5-tetraarylpyrrole Synthesis: Modular Access to N‑Doped π‑Conjugated Material Precursors

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