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Metathetical Exchange between Metal–Metal Triple Bonds

Journal of the American Chemical Society, 2020-02, Vol.142 (5), p.2233-2237

2020

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Isolation of a Stable, Acyclic, Two-Coordinate Silylene

Journal of the American Chemical Society, 2012-04, Vol.134 (15), p.6504-6507

2012

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Facile Activation of Dihydrogen by an Unsaturated Heavier Main Group Compound

Journal of the American Chemical Society, 2005-09, Vol.127 (35), p.12232-12233

2005

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Reversible Complexation of Ethylene by a Silylene under Ambient Conditions

Journal of the American Chemical Society, 2014-01, Vol.136 (2), p.634-637

2014

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C–H Activation of Cycloalkenes by Dimetallynes (M = Ge, Sn) under Ambient Conditions

Journal of the American Chemical Society, 2011-08, Vol.133 (31), p.11960-11963

2011

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A Germanium Isocyanide Complex Featuring (n → π) Back-Bonding and Its Conversion to a Hydride/Cyanide Product via C–H Bond Activation under Mild Conditions

Journal of the American Chemical Society, 2012-03, Vol.134 (9), p.4045-4048

2012

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Terphenyl Complexes of Molybdenum and Tungsten with Quadruple Metal–Metal Bonds and Bridging Carboxylate Ligands

Journal of the American Chemical Society, 2014-06, Vol.136 (25), p.9173-9180

2014

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Large Differences in Secondary Metal−Arene Interactions in the Transition-Metal Dimers ArMMAr (Ar = Terphenyl; M = Cr, Fe, or Co): Implications for Cr−Cr Quintuple Bonding

Journal of the American Chemical Society, 2008-04, Vol.130 (15), p.5104-5114

2008

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An Unsymmetric Oxo/Imido-Bridged Germanium-Centered Singlet Diradicaloid

Journal of the American Chemical Society, 2009-10, Vol.131 (40), p.14164-14165

2009

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Synthesis and Characterization of the Homologous M−M Bonded Series Ar‘MMAr‘ (M = Zn, Cd, or Hg; Ar‘ = C6H3-2,6-(C6H3-2,6-Pr i 2)2) and Related Arylmetal Halides and Hydride Species

Journal of the American Chemical Society, 2007-09, Vol.129 (35), p.10847-10857

2007

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Ab Initio Quantum Chemistry Calculations on the Electronic Structure of Heavier Alkyne Congeners: Diradical Character and Reactivity

Journal of the American Chemical Society, 2006-06, Vol.128 (22), p.7185-7192

2006

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Synthesis and Characterization of the Non-Kekulé, Singlet Biradicaloid Ar‘Ge(μ-NSiMe3)2GeAr‘ (Ar‘ = 2,6-Dipp2C6H3, Dipp = 2,6-i-Pr2C6H3)

Journal of the American Chemical Society, 2004-06, Vol.126 (21), p.6510-6511

2004

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Mechanistic Study of Stepwise Methylisocyanide Coupling and C–H Activation Mediated by a Low-Valent Main Group Molecule

Journal of the American Chemical Society, 2013-04, Vol.135 (16), p.6257-6261

2013

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Linear and Nonlinear Two-Coordinate Vanadium Complexes: Synthesis, Characterization, and Magnetic Properties of V(II) Amides

Journal of the American Chemical Society, 2013-07, Vol.135 (29), p.10720-10728

2013

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Structures, Bonding, and Reaction Chemistry of the Neutral Organogallium(I) Compounds (GaAr) n (n = 1 or 2) (Ar = Terphenyl or Related Ligand): An Experimental Investigation of Ga−Ga Multiple Bonding

Journal of the American Chemical Society, 2003-03, Vol.125 (9), p.2667-2679

2003

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Reversible Sn–Sn Triple Bond Dissociation in a Distannyne: Support for Charge-Shift Bonding Character

Journal of the American Chemical Society, 2019-08, Vol.141 (32), p.12527-12530

2019

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A Monomeric Aluminum Imide (Iminoalane) with Al–N Triple-Bonding: Bonding Analysis and Dispersion Energy Stabilization

Journal of the American Chemical Society, 2021-05, Vol.143 (17), p.6351-6356

2021

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Facile C–H Bond Metathesis Mediated by a Stannylene

Journal of the American Chemical Society, 2018-05, Vol.140 (17), p.5674-5677

2018

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Reversible Coordination of H 2 by a Distannyne

Journal of the American Chemical Society, 2018-01, Vol.140 (2), p.590-593

2018

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Diarylstannylene Activation of Hydrogen or Ammonia with Arene Elimination

Journal of the American Chemical Society, 2008-09, Vol.130 (37), p.12268-12269

2008

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Reactivity of Ar‘GeGeAr‘ (Ar‘ = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-iPr2) toward Alkynes: Isolation of a Stable Digermacyclobutadiene

Journal of the American Chemical Society, 2004-04, Vol.126 (16), p.5062-5063

2004

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Monomeric, Two-Coordinate, Univalent Chromium(I) Compounds: Steric Prevention of Metal−Metal Bond Formation

Journal of the American Chemical Society, 2007-05, Vol.129 (19), p.6076-6077

2007

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Designing a Solution-Stable Distannene: The Decisive Role of London Dispersion Effects in the Structure and Properties of {Sn(C6H2‑2,4,6-Cy3)2}2 (Cy = Cyclohexyl)

Journal of the American Chemical Society, 2021-12, Vol.143 (51), p.21478-21483

2021

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Isomeric Forms of Heavier Main Group Hydrides: Experimental and Theoretical Studies of the [Sn(Ar)H]2 (Ar = Terphenyl) System

Journal of the American Chemical Society, 2007-12, Vol.129 (51), p.16197-16208

2007

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Synthesis and Characterization of Quasi-Two-Coordinate Transition Metal Dithiolates M(SAr)2 (M = Cr, Mn, Fe, Co, Ni, Zn; Ar = C6H3-2,6(C6H2-2,4,6-Pri 3)2

Journal of the American Chemical Society, 2005-06, Vol.127 (23), p.8545-8552

2005

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Metathetical Exchange between Metal–Metal Triple Bonds

Isolation of a Stable, Acyclic, Two-Coordinate Silylene

Facile Activation of Dihydrogen by an Unsaturated Heavier Main Group Compound

Reversible Complexation of Ethylene by a Silylene under Ambient Conditions

C–H Activation of Cycloalkenes by Dimetallynes (M = Ge, Sn) under Ambient Conditions

A Germanium Isocyanide Complex Featuring (n → π) Back-Bonding and Its Conversion to a Hydride/Cyanide Product via C–H Bond Activation under Mild Conditions

Terphenyl Complexes of Molybdenum and Tungsten with Quadruple Metal–Metal Bonds and Bridging Carboxylate Ligands

Large Differences in Secondary Metal−Arene Interactions in the Transition-Metal Dimers ArMMAr (Ar = Terphenyl; M = Cr, Fe, or Co): Implications for Cr−Cr Quintuple Bonding

An Unsymmetric Oxo/Imido-Bridged Germanium-Centered Singlet Diradicaloid

Synthesis and Characterization of the Homologous M−M Bonded Series Ar‘MMAr‘ (M = Zn, Cd, or Hg; Ar‘ = C6H3-2,6-(C6H3-2,6-Pr i 2)2) and Related Arylmetal Halides and Hydride Species

Ab Initio Quantum Chemistry Calculations on the Electronic Structure of Heavier Alkyne Congeners: Diradical Character and Reactivity

Synthesis and Characterization of the Non-Kekulé, Singlet Biradicaloid Ar‘Ge(μ-NSiMe3)2GeAr‘ (Ar‘ = 2,6-Dipp2C6H3, Dipp = 2,6-i-Pr2C6H3)

Mechanistic Study of Stepwise Methylisocyanide Coupling and C–H Activation Mediated by a Low-Valent Main Group Molecule

Linear and Nonlinear Two-Coordinate Vanadium Complexes: Synthesis, Characterization, and Magnetic Properties of V(II) Amides

Structures, Bonding, and Reaction Chemistry of the Neutral Organogallium(I) Compounds (GaAr) n (n = 1 or 2) (Ar = Terphenyl or Related Ligand): An Experimental Investigation of Ga−Ga Multiple Bonding

Reversible Sn–Sn Triple Bond Dissociation in a Distannyne: Support for Charge-Shift Bonding Character

A Monomeric Aluminum Imide (Iminoalane) with Al–N Triple-Bonding: Bonding Analysis and Dispersion Energy Stabilization

Facile C–H Bond Metathesis Mediated by a Stannylene

Reversible Coordination of H 2 by a Distannyne

Diarylstannylene Activation of Hydrogen or Ammonia with Arene Elimination

Reactivity of Ar‘GeGeAr‘ (Ar‘ = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-iPr2) toward Alkynes: Isolation of a Stable Digermacyclobutadiene

Monomeric, Two-Coordinate, Univalent Chromium(I) Compounds: Steric Prevention of Metal−Metal Bond Formation

Designing a Solution-Stable Distannene: The Decisive Role of London Dispersion Effects in the Structure and Properties of {Sn(C6H2‑2,4,6-Cy3)2}2 (Cy = Cyclohexyl)

Isomeric Forms of Heavier Main Group Hydrides: Experimental and Theoretical Studies of the [Sn(Ar)H]2 (Ar = Terphenyl) System

Synthesis and Characterization of Quasi-Two-Coordinate Transition Metal Dithiolates M(SAr)2 (M = Cr, Mn, Fe, Co, Ni, Zn; Ar = C6H3-2,6(C6H2-2,4,6-Pri 3)2

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