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Radical aryl migration reactions and synthetic applications

Chemical Society reviews, 2015-08, Vol.44 (15), p.522-5245

2015

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Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols

Angewandte Chemie International Edition, 2013-09, Vol.52 (37), p.9781-9785

International ed. in English, 2013

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Semipinacol rearrangement in natural product synthesis

Chemical reviews, 2011-11, Vol.111 (11), p.7523-7556

2011

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Copper‐Complex‐Catalyzed Asymmetric Aerobic Oxidative Cross‐Coupling of 2‐Naphthols: Enantioselective Synthesis of 3,3′‐Substituted C1‐Symmetric BINOLs

Angewandte Chemie International Edition, 2019-08, Vol.58 (32), p.11023-11027

International ed. in English, 2019

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Enantioselective Synthesis of 3,3′‐Disubstituted 2‐Amino‐2′‐hydroxy‐1,1′‐binaphthyls by Copper‐Catalyzed Aerobic Oxidative Cross‐Coupling

Angewandte Chemie International Edition, 2021-03, Vol.60 (13), p.7061-7065

International ed. in English, 2021

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Enantioselective synthesis of cis-hydrobenzofurans bearing all-carbon quaternary stereocenters and application to total synthesis of (‒)-morphine

Nature communications, 2019-06, Vol.10 (1), p.2507-2507, Article 2507

2019

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Recent applications of the 1,2-carbon atom migration strategy in complex natural product total synthesis

Chemical Society reviews, 2017-04, Vol.46 (8), p.2272-235

2017

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Lewis Base/Brønsted Acid Co‐catalyzed Enantioselective Sulfenylation/Semipinacol Rearrangement of Di‐ and Trisubstituted Allylic Alcohols

Angewandte Chemie International Edition, 2019-09, Vol.58 (36), p.12491-12496

International ed. in English, 2019

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Catalytic asymmetric semipinacol rearrangements

Chemical communications (Cambridge, England), 2014-01, Vol.5 (19), p.2393-248

2014

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Asymmetric Intramolecular Hydroalkylation of Internal Olefin with Cycloalkanone to Directly Access Polycyclic Systems

Angewandte Chemie International Edition, 2023-09, Vol.62 (39), p.e202308858-n/a

International ed. in English, 2023

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Organo-Cation Catalyzed Asymmetric Homo/Heterodialkylation of Bisoxindoles: Construction of Vicinal All-Carbon Quaternary Stereocenters and Total Synthesis of (−)-Chimonanthidine

Journal of the American Chemical Society, 2018-08, Vol.140 (32), p.10099-10103

2018

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An efficient approach to angular tricyclic molecular architecture via Nazarov-like cyclization and double ring-expansion cascade

Nature communications, 2022-04, Vol.13 (1), p.2335-2335, Article 2335

2022

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Enantioselective Catalytic Aldehyde α‐Alkylation/Semipinacol Rearrangement: Construction of α‐Quaternary‐δ‐Carbonyl Cycloketones and Total Synthesis of (+)‐Cerapicol

Angewandte Chemie International Edition, 2020-05, Vol.59 (22), p.8471-8475

International ed. in English, 2020

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Collective Total Synthesis of Aspidofractinine Alkaloids through the Development of a Bischler–Napieralski/Semipinacol Rearrangement Reaction

Angewandte Chemie International Edition, 2020-12, Vol.59 (49), p.21954-21958

International ed. in English, 2020

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Recent development and applications of semipinacol rearrangement reactions

Chemical science (Cambridge), 2021-07, Vol.12 (27), p.9262-9274

2021

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Electrochemical Semipinacol Rearrangements of Allylic Alcohols: Construction of All-Carbon Quaternary Stereocenters

Organic letters, 2019-04, Vol.21 (8), p.2536-2540

2019

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Chiral 1,2,3‐Triazolium Salt Catalyzed Asymmetric Mono‐ and Dialkylation of 2,5‐Diketopiperazines with the Construction of Tetrasubstituted Carbon Centers

Angewandte Chemie International Edition, 2022-02, Vol.61 (9), p.e202114129-n/a

International ed. in English, 2022

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Enantioselective Construction of 2‑Aryl-2,3-dihydrobenzofuran Scaffolds Using Cu/SPDO-Catalyzed [3 + 2] Cycloaddition

Organic letters, 2021-02, Vol.23 (4), p.1258-1262

2021

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A Facile Approach to Oximes and Ethers by a Tandem NO+‐Initiated Semipinacol Rearrangement and H‐Elimination

Angewandte Chemie International Edition, 2018-10, Vol.57 (40), p.13192-13196

International ed. in English, 2018

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Copper‐Nitrene‐Catalyzed Desymmetric Oxaziridination/1,2‐Alkyl Rearrangement of 1,3‐Diketones toward Bicyclic Lactams

Angewandte Chemie International Edition, 2021-10, Vol.60 (42), p.22688-22692

International ed. in English, 2021

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Electrochemical halogenation/semi-pinacol rearrangement of allylic alcohols using inorganic halide salt: an eco-friendly route to the synthesis of β-halocarbonyls

Green chemistry : an international journal and green chemistry resource : GC, 2019-07, Vol.21 (15), p.414-419

2019

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Brønsted Acid Catalyzed Enantioselective Semipinacol Rearrangement for the Synthesis of Chiral Spiroethers

Angewandte Chemie (International ed.), 2009-10, Vol.48 (45), p.8572-8574

2009

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Divergent and Efficient Syntheses of the Lycopodium Alkaloids (−)-Lycojaponicumin C, (−)-8-Deoxyserratinine, (+)-Fawcettimine, and (+)-Fawcettidine

Angewandte Chemie International Edition, 2013-10, Vol.52 (43), p.11373-11376

2013

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Photoinduced reductive Reformatsky reaction of α-haloesters and aldehydes or ketones by cooperative dual-metal catalysis

Chemical communications (Cambridge, England), 2023-12, Vol.59 (97), p.14427-1443

2023

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Recent progress in the isolation, bioactivity, biosynthesis, and total synthesis of natural spiroketals

Natural product reports, 2018-01, Vol.35 (1), p.75-14

2018

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Radical aryl migration reactions and synthetic applications

Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols

Semipinacol rearrangement in natural product synthesis

Copper‐Complex‐Catalyzed Asymmetric Aerobic Oxidative Cross‐Coupling of 2‐Naphthols: Enantioselective Synthesis of 3,3′‐Substituted C1‐Symmetric BINOLs

Enantioselective Synthesis of 3,3′‐Disubstituted 2‐Amino‐2′‐hydroxy‐1,1′‐binaphthyls by Copper‐Catalyzed Aerobic Oxidative Cross‐Coupling

Enantioselective synthesis of cis-hydrobenzofurans bearing all-carbon quaternary stereocenters and application to total synthesis of (‒)-morphine

Recent applications of the 1,2-carbon atom migration strategy in complex natural product total synthesis

Lewis Base/Brønsted Acid Co‐catalyzed Enantioselective Sulfenylation/Semipinacol Rearrangement of Di‐ and Trisubstituted Allylic Alcohols

Catalytic asymmetric semipinacol rearrangements

Asymmetric Intramolecular Hydroalkylation of Internal Olefin with Cycloalkanone to Directly Access Polycyclic Systems

Organo-Cation Catalyzed Asymmetric Homo/Heterodialkylation of Bisoxindoles: Construction of Vicinal All-Carbon Quaternary Stereocenters and Total Synthesis of (−)-Chimonanthidine

An efficient approach to angular tricyclic molecular architecture via Nazarov-like cyclization and double ring-expansion cascade

Enantioselective Catalytic Aldehyde α‐Alkylation/Semipinacol Rearrangement: Construction of α‐Quaternary‐δ‐Carbonyl Cycloketones and Total Synthesis of (+)‐Cerapicol

Collective Total Synthesis of Aspidofractinine Alkaloids through the Development of a Bischler–Napieralski/Semipinacol Rearrangement Reaction

Recent development and applications of semipinacol rearrangement reactions

Electrochemical Semipinacol Rearrangements of Allylic Alcohols: Construction of All-Carbon Quaternary Stereocenters

Chiral 1,2,3‐Triazolium Salt Catalyzed Asymmetric Mono‐ and Dialkylation of 2,5‐Diketopiperazines with the Construction of Tetrasubstituted Carbon Centers

Enantioselective Construction of 2‑Aryl-2,3-dihydrobenzofuran Scaffolds Using Cu/SPDO-Catalyzed [3 + 2] Cycloaddition

A Facile Approach to Oximes and Ethers by a Tandem NO+‐Initiated Semipinacol Rearrangement and H‐Elimination

Copper‐Nitrene‐Catalyzed Desymmetric Oxaziridination/1,2‐Alkyl Rearrangement of 1,3‐Diketones toward Bicyclic Lactams

Electrochemical halogenation/semi-pinacol rearrangement of allylic alcohols using inorganic halide salt: an eco-friendly route to the synthesis of β-halocarbonyls

Brønsted Acid Catalyzed Enantioselective Semipinacol Rearrangement for the Synthesis of Chiral Spiroethers

Divergent and Efficient Syntheses of the Lycopodium Alkaloids (−)-Lycojaponicumin C, (−)-8-Deoxyserratinine, (+)-Fawcettimine, and (+)-Fawcettidine

Photoinduced reductive Reformatsky reaction of α-haloesters and aldehydes or ketones by cooperative dual-metal catalysis

Recent progress in the isolation, bioactivity, biosynthesis, and total synthesis of natural spiroketals

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