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ansa-Zirconocene Ester Enolates: Synthesis, Structure, Reaction with Organo-Lewis Acids, and Application to Polymerization of Methacrylates

Journal of the American Chemical Society, 2004-04, Vol.126 (15), p.4897-4906

2004

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Single-Site Anionic Polymerization. Monomeric Ester Enolaluminate Propagator Synthesis, Molecular Structure, and Polymerization Mechanism

Journal of the American Chemical Society, 2005-01, Vol.127 (3), p.961-974

2005

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Reversal of Polymerization Stereoregulation in Anionic Polymerization of MMA by Chiral Metallocene and Non-metallocene Initiators: A New Reaction Pathway for Metallocene-Initiated MMA Polymerization

Journal of the American Chemical Society, 2001-08, Vol.123 (32), p.7943-7944

2001

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Stereochemically Controlled PMMA-Exfoliated Silicate Nanocomposites Using Intergallery-Anchored Metallocenium Cations

Journal of the American Chemical Society, 2003-12, Vol.125 (51), p.15726-15727

2003

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Amphicatalytic Polymerization: Synthesis of Stereomultiblock Poly(methyl methacrylate) with Diastereospecific Ion Pairs

Journal of the American Chemical Society, 2003-06, Vol.125 (24), p.7150-7151

2003

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“Double Activation” of Constrained Geometry and ansa-Metallocene Group 4 Metal Dialkyls: Synthesis, Structure, and Olefin Polymerization Study of Mono- and Dicationic Aluminate Complexes

Journal of the American Chemical Society, 2001-01, Vol.123 (4), p.745-746

2001

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Divalent ansa-Zirconocenes: Stereoselective Synthesis and High Activity for Propylene Polymerization

Journal of the American Chemical Society, 2004-01, Vol.126 (1), p.42-43

2004

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Probing Site Cooperativity of Frustrated Phosphine/Borane Lewis Pairs by a Polymerization Study

Journal of the American Chemical Society, 2014-02, Vol.136 (5), p.1774-1777

2014

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Unmasking the Catalytic Activity of a Platinum Complex with a Lewis Acidic, Non-innocent Antimony Ligand

Journal of the American Chemical Society, 2017-05, Vol.139 (20), p.6843-6846

2017

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Frustrated Lewis Pairs

Journal of the American Chemical Society, 2015-08, Vol.137 (32), p.10018-10032

Stephan, Douglas W

2015

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A Robust Ni(II) α‑Diimine Catalyst for High Temperature Ethylene Polymerization

Journal of the American Chemical Society, 2013-11, Vol.135 (44), p.16316-16319

2013

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Selective Reduction of CO2 to CH4 by Tandem Hydrosilylation with Mixed Al/B Catalysts

Journal of the American Chemical Society, 2016-04, Vol.138 (16), p.5321-5333

2016

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The Quest for Converting Biorenewable Bifunctional α‑Methylene-γ-butyrolactone into Degradable and Recyclable Polyester: Controlling Vinyl-Addition/Ring-Opening/Cross-Linking Pathways

Journal of the American Chemical Society, 2016-11, Vol.138 (43), p.14326-14337

2016

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Mechanism of Single-Site Molecule-Like Catalytic Ethylene Dimerization in Ni-MFU‑4l

Journal of the American Chemical Society, 2017-01, Vol.139 (2), p.757-762

2017

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Reversed Controlled Polymerization (RCP): Depolymerization from Well-Defined Polymers to Monomers

Journal of the American Chemical Society, 2023-05, Vol.145 (18), p.9898-9915

2023

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Synthesis, Characterization, and Heterobimetallic Cooperation in a Titanium–Chromium Catalyst for Highly Branched Polyethylenes

Journal of the American Chemical Society, 2013-06, Vol.135 (24), p.8830-8833

2013

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Chemoselective, Stereospecific, and Living Polymerization of Polar Divinyl Monomers by Chiral Zirconocenium Catalysts

Journal of the American Chemical Society, 2015-07, Vol.137 (29), p.9469-9480

2015

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Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization

Journal of the American Chemical Society, 2017-05, Vol.139 (20), p.6823-6826

2017

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Electron-Rich Metal Cations Enable Synthesis of High Molecular Weight, Linear Functional Polyethylenes

Journal of the American Chemical Society, 2018-07, Vol.140 (28), p.8841-8850

2018

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Robust Cross-Linked Stereocomplexes and C 60 Inclusion Complexes of Vinyl-Functionalized Stereoregular Polymers Derived from Chemo/Stereoselective Coordination Polymerization

Journal of the American Chemical Society, 2016-08, Vol.138 (30), p.9533-9547

2016

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A Supported Ziegler-Type Organohafnium Site Metabolizes Polypropylene

Journal of the American Chemical Society, 2023-11, Vol.145 (45), p.24447-24451

2023

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Compounded Sequence Control in Polymerization of One-Pot Mixtures of Highly Reactive Acrylates by Differentiating Lewis Pairs

Journal of the American Chemical Society, 2020-04, Vol.142 (13), p.5969-5973

2020

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Photoinduced Initiation of Olefin Polymerization: Enabling Spatial Control with Light

Journal of the American Chemical Society, 2022-11, Vol.144 (46), p.21206-21212

2022

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π‑Bond Character in Metal–Alkyl Compounds for C–H Activation: How, When, and Why?

Journal of the American Chemical Society, 2019-01, Vol.141 (1), p.648-656

2019

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Catalyst-Site-Controlled Coordination Polymerization of Polar Vinyl Monomers to Highly Syndiotactic Polymers

Journal of the American Chemical Society, 2010-03, Vol.132 (8), p.2695-2709

2010

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ansa-Zirconocene Ester Enolates: Synthesis, Structure, Reaction with Organo-Lewis Acids, and Application to Polymerization of Methacrylates

Single-Site Anionic Polymerization. Monomeric Ester Enolaluminate Propagator Synthesis, Molecular Structure, and Polymerization Mechanism

Reversal of Polymerization Stereoregulation in Anionic Polymerization of MMA by Chiral Metallocene and Non-metallocene Initiators: A New Reaction Pathway for Metallocene-Initiated MMA Polymerization

Stereochemically Controlled PMMA-Exfoliated Silicate Nanocomposites Using Intergallery-Anchored Metallocenium Cations

Amphicatalytic Polymerization: Synthesis of Stereomultiblock Poly(methyl methacrylate) with Diastereospecific Ion Pairs

“Double Activation” of Constrained Geometry and ansa-Metallocene Group 4 Metal Dialkyls: Synthesis, Structure, and Olefin Polymerization Study of Mono- and Dicationic Aluminate Complexes

Divalent ansa-Zirconocenes: Stereoselective Synthesis and High Activity for Propylene Polymerization

Probing Site Cooperativity of Frustrated Phosphine/Borane Lewis Pairs by a Polymerization Study

Unmasking the Catalytic Activity of a Platinum Complex with a Lewis Acidic, Non-innocent Antimony Ligand

Frustrated Lewis Pairs

A Robust Ni(II) α‑Diimine Catalyst for High Temperature Ethylene Polymerization

Selective Reduction of CO2 to CH4 by Tandem Hydrosilylation with Mixed Al/B Catalysts

The Quest for Converting Biorenewable Bifunctional α‑Methylene-γ-butyrolactone into Degradable and Recyclable Polyester: Controlling Vinyl-Addition/Ring-Opening/Cross-Linking Pathways

Mechanism of Single-Site Molecule-Like Catalytic Ethylene Dimerization in Ni-MFU‑4l

Reversed Controlled Polymerization (RCP): Depolymerization from Well-Defined Polymers to Monomers

Synthesis, Characterization, and Heterobimetallic Cooperation in a Titanium–Chromium Catalyst for Highly Branched Polyethylenes

Chemoselective, Stereospecific, and Living Polymerization of Polar Divinyl Monomers by Chiral Zirconocenium Catalysts

Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization

Electron-Rich Metal Cations Enable Synthesis of High Molecular Weight, Linear Functional Polyethylenes

Robust Cross-Linked Stereocomplexes and C 60 Inclusion Complexes of Vinyl-Functionalized Stereoregular Polymers Derived from Chemo/Stereoselective Coordination Polymerization

A Supported Ziegler-Type Organohafnium Site Metabolizes Polypropylene

Compounded Sequence Control in Polymerization of One-Pot Mixtures of Highly Reactive Acrylates by Differentiating Lewis Pairs

Photoinduced Initiation of Olefin Polymerization: Enabling Spatial Control with Light

π‑Bond Character in Metal–Alkyl Compounds for C–H Activation: How, When, and Why?

Catalyst-Site-Controlled Coordination Polymerization of Polar Vinyl Monomers to Highly Syndiotactic Polymers

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