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Catalyst/Cocatalyst Nuclearity Effects in Single-Site Polymerization. Enhanced Polyethylene Branching and α-Olefin Comonomer Enchainment in Polymerizations Mediated by Binuclear Catalysts and Cocatalysts via a New Enchainment Pathway

Journal of the American Chemical Society, 2002-10, Vol.124 (43), p.12725-12741

2002

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Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene: Enhanced Enchainment Mediated by Binuclear Catalysts and Cocatalysts

Journal of the American Chemical Society, 2005-10, Vol.127 (42), p.14756-14768

2005

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Catalyst/Cocatalyst Nuclearity Effects in Single-Site Olefin Polymerization. Significantly Enhanced 1-Octene and Isobutene Comonomer Enchainment in Ethylene Polymerizations Mediated by Binuclear Catalysts and Cocatalysts

Journal of the American Chemical Society, 2003-09, Vol.125 (36), p.10788-10789

2003

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Polynuclear Catalysis: Enhancement of Enchainment Cooperativity between Different Single-Site Olefin Polymerization Catalysts by Ion Pairing with a Binuclear Cocatalyst

Journal of the American Chemical Society, 2002-11, Vol.124 (47), p.13966-13967

2002

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Bimetallic Catalysis for Styrene Homopolymerization and Ethylene−Styrene Copolymerization. Exceptional Comonomer Selectivity and Insertion Regiochemistry

Journal of the American Chemical Society, 2004-06, Vol.126 (21), p.6542-6543

2004

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Diverse Stereocontrol Effects Induced by Weakly Coordinating Anions. Stereospecific Olefin Polymerization Pathways at Archetypal Cs- and C1-Symmetric Metallocenium Catalysts Using Mono- and Polynuclear Halo-perfluoroarylmetalates as Cocatalysts

Journal of the American Chemical Society, 2007-10, Vol.129 (42), p.12713-12733

2007

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Sterically Encumbered (Perfluoroaryl) Borane and Aluminate Cocatalysts for Tuning Cation−Anion Ion Pair Structure and Reactivity in Metallocene Polymerization Processes. A Synthetic, Structural, and Polymerization Study

Journal of the American Chemical Society, 1998-07, Vol.120 (25), p.6287-6305

1998

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Diverse Stereocontrol Effects Induced by Weakly Coordinating Anions. Stereospecific Olefin Polymerization Pathways at Archetypal C s - and C 1-Symmetric Metallocenium Catalysts Using Mono- and Polynuclear Halo-perfluoroarylmetalates as Cocatalysts

Journal of the American Chemical Society, 2007-10, Vol.129 (42), p.12713-12733

2007

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Preparation and Use of Ta(CD 2 Bu t ) 5 To Probe the Formation of (Bu t CD 2 ) 3 Ta═CDBu t . Kinetic and Mechanistic Studies of the Conversion of Pentaneopentyltantalum to the Archetypical Alkylidene Complex

Journal of the American Chemical Society, 2009-06, Vol.131 (23), p.8246-8251

2009

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Preparation and Use of Ta(CD2But)5 To Probe the Formation of (ButCD2)3TaCDBut. Kinetic and Mechanistic Studies of the Conversion of Pentaneopentyltantalum to the Archetypical Alkylidene Complex

Journal of the American Chemical Society, 2009-06, Vol.131 (23), p.8246-8251

2009

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Diverse stereocontrol effects induced by weakly coordinating anions. Stereospecific olefin polymerization pathways at archetypal C(s)- and C(1)-symmetric metallocenium catalysts using mono- and polynuclear halo-perfluoroarylmetalates as cocatalysts

Journal of the American Chemical Society, 2007-10, Vol.129 (42), p.12713-12733

2007

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Early-Transition-Metal Silyl Complexes Free from Anionic .pi.-Ligands. A New Family of Alkyl, Alkylidene, and Alkylidyne Compounds

Journal of the American Chemical Society, 1994-03, Vol.116 (5), p.2169-2170

1994

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Preparation and use of Ta(CD2Bu(t))5 to probe the formation of (Bu(t)CD2)3Ta=CDBu(t). Kinetic and mechanistic studies of the conversion of pentaneopentyltantalum to the archetypical alkylidene complex

Journal of the American Chemical Society, 2009-06, Vol.131 (23), p.8246-8251

2009

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Direct Observation of an Equilibrium between (ButCH2)2W(⋮CBut)(SiButPh2) and (ButCH2)W(CHBut)2(SiButPh2) and an Unusual Silyl Migration

Journal of the American Chemical Society, 1998-12, Vol.120 (51), p.13519-13520

1998

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Energetics of Metal−Ligand Multiple Bonds. Thermochemistry of Tantalum(V) Alkylidene Formation

Journal of the American Chemical Society, 1997-09, Vol.119 (36), p.8574-8575

1997

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Direct Observation of an Equilibrium between (Bu t CH 2 ) 2 W(⋮CBu t )(SiBu t Ph 2 ) and (Bu t CH 2 )W(CHBu t ) 2 (SiBu t Ph 2 ) and an Unusual Silyl Migration

Journal of the American Chemical Society, 1998-12, Vol.120 (51), p.13519-13520

1998

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Direct Observation of (Me3ECH2)5Ta (E = C, Si) as the Precursors to (Me3ECH2)3Ta:CHEMe3 and (Me3SiCH2)2Ta(.mu.-CSiMe3)2Ta(CH2SiMe3)2. Kinetic and Mechanistic Studies of the Formation of Alkylidene and Alkylidyne Ligands

Journal of the American Chemical Society, 1995-12, Vol.117 (51), p.12746-12750

1995

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Early-transition-metal silyl complexes free from anionic [pi]-ligands. A new family of alkyl, alkylidene, and alkylidyne compounds

Journal of the American Chemical Society, 1994-03, Vol.116:5

1994

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Atomically Precise Alkynyl-Protected Metal Nanoclusters as a Model Catalyst: Observation of Promoting Effect of Surface Ligands on Catalysis by Metal Nanoparticles

Journal of the American Chemical Society, 2016-03, Vol.138 (10), p.3278-3281

2016

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Biomimetic Nanofibrillar Hydrogel with Cell-Adaptable Network for Enhancing Cellular Mechanotransduction, Metabolic Energetics, and Bone Regeneration

Journal of the American Chemical Society, 2023-07, Vol.145 (28), p.15218-15229

2023

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Catalyst/Cocatalyst Nuclearity Effects in Single-Site Polymerization. Enhanced Polyethylene Branching and α-Olefin Comonomer Enchainment in Polymerizations Mediated by Binuclear Catalysts and Cocatalysts via a New Enchainment Pathway

Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene: Enhanced Enchainment Mediated by Binuclear Catalysts and Cocatalysts

Catalyst/Cocatalyst Nuclearity Effects in Single-Site Olefin Polymerization. Significantly Enhanced 1-Octene and Isobutene Comonomer Enchainment in Ethylene Polymerizations Mediated by Binuclear Catalysts and Cocatalysts

Polynuclear Catalysis: Enhancement of Enchainment Cooperativity between Different Single-Site Olefin Polymerization Catalysts by Ion Pairing with a Binuclear Cocatalyst

Bimetallic Catalysis for Styrene Homopolymerization and Ethylene−Styrene Copolymerization. Exceptional Comonomer Selectivity and Insertion Regiochemistry

Diverse Stereocontrol Effects Induced by Weakly Coordinating Anions. Stereospecific Olefin Polymerization Pathways at Archetypal Cs- and C1-Symmetric Metallocenium Catalysts Using Mono- and Polynuclear Halo-perfluoroarylmetalates as Cocatalysts

Sterically Encumbered (Perfluoroaryl) Borane and Aluminate Cocatalysts for Tuning Cation−Anion Ion Pair Structure and Reactivity in Metallocene Polymerization Processes. A Synthetic, Structural, and Polymerization Study

Diverse Stereocontrol Effects Induced by Weakly Coordinating Anions. Stereospecific Olefin Polymerization Pathways at Archetypal C s - and C 1-Symmetric Metallocenium Catalysts Using Mono- and Polynuclear Halo-perfluoroarylmetalates as Cocatalysts

Preparation and Use of Ta(CD 2 Bu t ) 5 To Probe the Formation of (Bu t CD 2 ) 3 Ta═CDBu t . Kinetic and Mechanistic Studies of the Conversion of Pentaneopentyltantalum to the Archetypical Alkylidene Complex

Preparation and Use of Ta(CD2But)5 To Probe the Formation of (ButCD2)3TaCDBut. Kinetic and Mechanistic Studies of the Conversion of Pentaneopentyltantalum to the Archetypical Alkylidene Complex

Diverse stereocontrol effects induced by weakly coordinating anions. Stereospecific olefin polymerization pathways at archetypal C(s)- and C(1)-symmetric metallocenium catalysts using mono- and polynuclear halo-perfluoroarylmetalates as cocatalysts

Early-Transition-Metal Silyl Complexes Free from Anionic .pi.-Ligands. A New Family of Alkyl, Alkylidene, and Alkylidyne Compounds

Preparation and use of Ta(CD2Bu(t))5 to probe the formation of (Bu(t)CD2)3Ta=CDBu(t). Kinetic and mechanistic studies of the conversion of pentaneopentyltantalum to the archetypical alkylidene complex

Direct Observation of an Equilibrium between (ButCH2)2W(⋮CBut)(SiButPh2) and (ButCH2)W(CHBut)2(SiButPh2) and an Unusual Silyl Migration

Energetics of Metal−Ligand Multiple Bonds. Thermochemistry of Tantalum(V) Alkylidene Formation

Direct Observation of an Equilibrium between (Bu t CH 2 ) 2 W(⋮CBu t )(SiBu t Ph 2 ) and (Bu t CH 2 )W(CHBu t ) 2 (SiBu t Ph 2 ) and an Unusual Silyl Migration

Direct Observation of (Me3ECH2)5Ta (E = C, Si) as the Precursors to (Me3ECH2)3Ta:CHEMe3 and (Me3SiCH2)2Ta(.mu.-CSiMe3)2Ta(CH2SiMe3)2. Kinetic and Mechanistic Studies of the Formation of Alkylidene and Alkylidyne Ligands

Early-transition-metal silyl complexes free from anionic [pi]-ligands. A new family of alkyl, alkylidene, and alkylidyne compounds

Atomically Precise Alkynyl-Protected Metal Nanoclusters as a Model Catalyst: Observation of Promoting Effect of Surface Ligands on Catalysis by Metal Nanoparticles

Biomimetic Nanofibrillar Hydrogel with Cell-Adaptable Network for Enhancing Cellular Mechanotransduction, Metabolic Energetics, and Bone Regeneration

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