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Synthesis and Structure of Ruthenium−Silylene Complexes: Activation of Si−Cl Bonds in N-Heterocyclic Silanes

Journal of the American Chemical Society, 2006-05, Vol.128 (18), p.6038-6039

2006

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Synthesis and Reactivity of Silyl Ruthenium Complexes: The Importance of Trans Effects in C−H Activation, Si−C Bond Formation, and Dehydrogenative Coupling of Silanes

Journal of the American Chemical Society, 2003-07, Vol.125 (26), p.8043-8058

2003

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Evidence for Ligand Non-innocence in a Formally Ruthenium(I) Hydride Complex

Journal of the American Chemical Society, 2010-03, Vol.132 (12), p.4107-4109

2010

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Structure and Reactivity of Bis(silyl) Dihydride Complexes (PMe3)3Ru(SiR3)2(H)2: Model Compounds and Real Intermediates in a Dehydrogenative C−Si Bond Forming Reaction

Journal of the American Chemical Society, 2003-07, Vol.125 (29), p.8936-8948

2003

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Formation and Interconversion of Ruthenium−Silene and 16-Electron Ruthenium Silyl Complexes

Journal of the American Chemical Society, 1999-09, Vol.121 (36), p.8391-8392

1999

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Catalytic Synthesis of Poly(arylmethylgermanes) by Demethanative Coupling: A Mild Route to σ-Conjugated Polymers

Journal of the American Chemical Society, 1998-09, Vol.120 (38), p.9844-9849

1998

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Ruthenium-Catalyzed Demethanative Coupling of HGeMe3: A High Yield Route to Polygermanes

Journal of the American Chemical Society, 1996-10, Vol.118 (39), p.9430-9431

1996

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Agostic β-Si-H interactions in silylamido complexes of zirconocene

Journal of the American Chemical Society, 1994-01, Vol.116 (1), p.177-185

1994

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Structure and reactivity of Cp2W(.eta.2-Me2Si:CH2), a tungsten silene complex

Journal of the American Chemical Society, 1990-08, Vol.112 (17), p.6405-6406

1990

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Disilene complexes of molybdenum and tungsten

Journal of the American Chemical Society, 1990, Vol.112 (1), p.452-453

1990

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Structure and reactivity of bis(silyl) dihydride complexes (PMe(3))(3)Ru(SiR(3))(2)(H)(2): model compounds and real intermediates in a dehydrogenative C-Si bond forming reaction

Journal of the American Chemical Society, 2003-07, Vol.125 (29), p.8936-8948

2003

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Selective H/D exchange in alkylsilanes catalyzed by osmium phosphine complexes: the first evidence for β-hydrogen elimination from a metal silyl

Journal of the American Chemical Society, 1989-05, Vol.111 (11), p.4099-4100

1989

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Formation of molybdenum silyl complexes from hydrides by net silylene transfer: evidence for a radical-chain mechanism

Journal of the American Chemical Society, 1987-06, Vol.109 (12), p.3777-3778

1987

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Facile arene C-H bond activation by tantalum silyl complexes

Journal of the American Chemical Society, 1989-09, Vol.111 (20), p.8049-8051

1989

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Dimethylsilylene insertion into tantalum-hydride bonds

Journal of the American Chemical Society, 1987-09, Vol.109 (20), p.6210-6212

1987

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Metal-centered radical-pair mechanism for alkyne hydrogenation with a binuclear rhodium hydride complex. CIDNP without organic radicals

Journal of the American Chemical Society, 1986-08, Vol.108 (17), p.5345-5347

1986

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Dehydrogenative coupling of trialkylsilanes mediated by ruthenium phosphine complexes: catalytic synthesis of carbosilanes

Journal of the American Chemical Society, 1991-05, Vol.113 (10), p.4039-4040

1991

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Competitive C―H activation and C≡C coordination in the reactions of acetylenes with a binuclear rhodium complex

Journal of the American Chemical Society, 1985, Vol.107 (24), p.7181-7183

1985

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eta.2-Silanimine complexes of zirconocene: synthesis, structure, and reactivity of Cp2Zr(.eta.2-SiMe2:N-tert-Bu)(PMe3)

Journal of the American Chemical Society, 1991-02, Vol.113 (5), p.1870-1872

1991

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Selective hydrogen-deuterium exchange in alkylsilanes catalyzed by osmium phosphine complexes: the first evidence for .beta.-hydrogen elimination from a metal silyl

Journal of the American Chemical Society, 1989-05, Vol.111 (11), p.4099-4100

1989

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Agostic .beta.-silicon-hydrogen interactions in silylamido complexes of zirconocene

Journal of the American Chemical Society, 1994-01, Vol.116 (1), p.177-185

1994

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Facile arene carbon-hydrogen bond activation by tantalum silyl complexes

Journal of the American Chemical Society, 1989-09, Vol.111 (20), p.8049-8051

1989

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Carbon-carbon bond formation by reductive coupling of two carbonyl ligands of binuclear transition metal complexes

Journal of the American Chemical Society, 1982-08, Vol.104 (17), p.4712-4715

1982

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Structure and Reactivity of Bis(silyl) Dihydride Complexes (PMe 3 ) 3 Ru(SiR 3 ) 2 (H) 2 : Model Compounds and Real Intermediates in a Dehydrogenative C−Si Bond Forming Reaction

Journal of the American Chemical Society, 2003-07, Vol.125 (29), p.8936-8948

2003

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Competitive carbon-hydrogen activation and C.tplbond.C coordination in the reactions of acetylenes with a binuclear rhodium complex

Journal of the American Chemical Society, 1985-11, Vol.107 (24), p.7181-7183

1985

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Synthesis and Structure of Ruthenium−Silylene Complexes: Activation of Si−Cl Bonds in N-Heterocyclic Silanes

Synthesis and Reactivity of Silyl Ruthenium Complexes: The Importance of Trans Effects in C−H Activation, Si−C Bond Formation, and Dehydrogenative Coupling of Silanes

Evidence for Ligand Non-innocence in a Formally Ruthenium(I) Hydride Complex

Structure and Reactivity of Bis(silyl) Dihydride Complexes (PMe3)3Ru(SiR3)2(H)2: Model Compounds and Real Intermediates in a Dehydrogenative C−Si Bond Forming Reaction

Formation and Interconversion of Ruthenium−Silene and 16-Electron Ruthenium Silyl Complexes

Catalytic Synthesis of Poly(arylmethylgermanes) by Demethanative Coupling: A Mild Route to σ-Conjugated Polymers

Ruthenium-Catalyzed Demethanative Coupling of HGeMe3: A High Yield Route to Polygermanes

Agostic β-Si-H interactions in silylamido complexes of zirconocene

Structure and reactivity of Cp2W(.eta.2-Me2Si:CH2), a tungsten silene complex

Disilene complexes of molybdenum and tungsten

Structure and reactivity of bis(silyl) dihydride complexes (PMe(3))(3)Ru(SiR(3))(2)(H)(2): model compounds and real intermediates in a dehydrogenative C-Si bond forming reaction

Selective H/D exchange in alkylsilanes catalyzed by osmium phosphine complexes: the first evidence for β-hydrogen elimination from a metal silyl

Formation of molybdenum silyl complexes from hydrides by net silylene transfer: evidence for a radical-chain mechanism

Facile arene C-H bond activation by tantalum silyl complexes

Dimethylsilylene insertion into tantalum-hydride bonds

Metal-centered radical-pair mechanism for alkyne hydrogenation with a binuclear rhodium hydride complex. CIDNP without organic radicals

Dehydrogenative coupling of trialkylsilanes mediated by ruthenium phosphine complexes: catalytic synthesis of carbosilanes

Competitive C―H activation and C≡C coordination in the reactions of acetylenes with a binuclear rhodium complex

eta.2-Silanimine complexes of zirconocene: synthesis, structure, and reactivity of Cp2Zr(.eta.2-SiMe2:N-tert-Bu)(PMe3)

Selective hydrogen-deuterium exchange in alkylsilanes catalyzed by osmium phosphine complexes: the first evidence for .beta.-hydrogen elimination from a metal silyl

Agostic .beta.-silicon-hydrogen interactions in silylamido complexes of zirconocene

Facile arene carbon-hydrogen bond activation by tantalum silyl complexes

Carbon-carbon bond formation by reductive coupling of two carbonyl ligands of binuclear transition metal complexes

Structure and Reactivity of Bis(silyl) Dihydride Complexes (PMe 3 ) 3 Ru(SiR 3 ) 2 (H) 2 : Model Compounds and Real Intermediates in a Dehydrogenative C−Si Bond Forming Reaction

Competitive carbon-hydrogen activation and C.tplbond.C coordination in the reactions of acetylenes with a binuclear rhodium complex

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