Details

Autor(en) / Beteiligte

• Zhang, Kou-Lin
• Lin, Jian-Guo
• Wang, Ya-Qiong
• Xu, Wen-Lin
• Chen, Jiu-Tong

Titel

Aqua­bis(2-nitro­benzoato-κO)(1,10-phenanthroline-κ2N,N′)­zinc(II)

Ist Teil von

• Acta crystallographica. Section C, Crystal structure communications, 2004-09, Vol.60 (9), p.m454-m456

Ort / Verlag

5 Abbey Square, Chester, Cheshire CH1 2HU, England: Munksgaard International Publishers

Erscheinungsjahr

2004

Quelle

Wiley Online Library

Beschreibungen/Notizen

• The title compound, [Zn(C7H4NO4)2(C12H8N2)(H2O)], has been synthesized. X‐Ray analysis reveals that it is a neutral zinc(II) mononuclear carboxyl­ate complex based on mixed N‐ and O‐donor ligands. The Zn atom is five‐coordinate in a distorted trigonal–bipyramidal coordination environment involving two O atoms of two monodentate 2‐nitro­benzoate mol­ecules, two N atoms of a 1,10‐phenanthroline mol­ecule and one O atom of a water mol­ecule. The axial positions are occupied by a carboxyl­ate O atom from the 2‐nitro­benzoate ligand and an N atom from the 1,10‐phenanthroline ligand [N—Zn—O = 167.66 (9)°].