Details

Autor(en) / Beteiligte

• Liebeskind, Lanny S
• Garnier‐Amblard, Ethel C
• Pombeiro, Armando J. L

Titel

Toward Chemoselective Bioconjugative Desulfitative Catalysis

Ist Teil von

• Advances in Organometallic Chemistry and Catalysis, 2013, p.295-303

Ort / Verlag

Hoboken, NJ, USA: John Wiley & Sons, Inc

Erscheinungsjahr

2013

Quelle

Wiley Online Library All Obooks

Beschreibungen/Notizen

• This contribution provides an overview of the author's explorations of pH‐neutral desulfitative catalytic coupling of thioorganics with boronic acids. It begins with an explanation of the palladium‐catalyzed, copper(I) carboxylate mediated reaction systems and transitions to the newer pH‐neutral reaction methods that require only copper in catalytic quantities. The discussion ends with a look forward at the application of pH‐neutral desulfitative catalysis to biological molecules in water.