Chinese chemical letters, 2013-08, Vol.24 (8), p.707-709
2013
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Details
- Autor(en) / Beteiligte
- Titel
- Selective binding of unsaturated aliphatic hydrocarbons by a pillar[5]arene
- Ist Teil von
- Chinese chemical letters, 2013-08, Vol.24 (8), p.707-709
- Ort / Verlag
- Elsevier B.V
- Erscheinungsjahr
- 2013
- Quelle
- Alma/SFX Local Collection
- Beschreibungen/Notizen
- The complexation behavior of unsaturated fatty hydrocarbons,i.e.,1,7-octadiyne and 1,7-octadiene,by a perethylated pillar[5]arene has been investigated,which was compared with that for saturated n-octane. It was found that the host-guest binding strength increased in accordance with the electron-negativity of the terminal carbon atom on the guests：alkyne〉alkene〉alkane.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1001-8417eISSN: 1878-5964DOI: 10.1016/j.cclet.2013.05.008Titel-ID: cdi_wanfang_journals_zghxkb201308012
- Format
- –
- Schlagworte
- Molecular recognition, Pillararenes, Supramolecular chemistry, Unsaturated hydrocarbons, 不饱和, 主客体, 支柱, 正辛烷, 碳原子, 结合强度, 脂肪烃, 芳烃