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Electrocatalytic activity of non-precious metal catalyst Co-N/C toward oxygen reduction reaction
Ist Teil von
Chinese chemical letters, 2010-08, Vol.21 (8), p.983-986
Ort / Verlag
Elsevier B.V
Erscheinungsjahr
2010
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Metallic cobalt was deposited on acetylene black to synthesize a composite Co/C by chemical reduction method.A platinumfree electrocatalyst Co-N/C(800) for oxygen reduction reaction(ORR) was synthesized by mixing the composite Co/C with urea and heat-treating at 800℃.The results from linear sweep voltammograms indicated that the Co-N/C(800) is active to ORR.Theβ-Co and cobalt oxides are not the active site of the catalyst Co-N/C.However,the existence of cobalt facilitated the modification of nitrogen to carbon black and led to the formation of active site of catalyst Co-N/C(800).